• Title/Summary/Keyword: $M/H_2/1$ model

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Sorption of Se(-II) on illite, MX-80 bentonite, shale, and limestone in Na-Ca-Cl solutions

  • Walker, Andrew;Racette, Joshua;Saito, Takumi;Yang, Tammy (Tianxiao);Nagasaki, Shinya
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1616-1622
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    • 2022
  • Selenium has been identified as an element of interest for the safety assessment of a deep geological repository (DGR) for used nuclear fuel. In Canada, groundwaters at DGR depths in sedimentary rocks have been observed to have a high ionic strength. This paper examines the sorption behavior of Se(-II) onto illite, MX-80 bentonite, Queenston shale, and argillaceous limestone in Na-Ca-Cl solutions of varying ionic strength (0.1-6 mol/kgw (m)) and across a pH range of 4-9. Little ionic strength dependence for Se(-II) sorption onto all solids was observed except that sorption at high ionic strength (6 m) was generally slightly lower than sorption at low ionic strength (0.1 m). Illite and MX-80 exhibited the expected results for anion sorption, while shale and limestone exhibited more constant sorption across the pH range tested. A non-electrostatic surface complexation model successfully predicted sorption of Se(-II) onto illite and MX-80 using the formation of an inner-sphere surface complex and an outer-sphere surface complex. Optimized values for the formation reactions of these surface species were proposed.

Biodegradation Kinetics of Phenol and pcresol by Micrococcus sp. M1 (Micrococcus sp. M1에 의한 Phenol과 p-Creso의 생분해 Kinetics)

  • Son, Hong-Joo;Jang, Woong-Seok;Lee, Geon;Lee, Sang-Joon
    • Journal of Environmental Science International
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    • v.6 no.2
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    • pp.153-163
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    • 1997
  • In order to fad the most fitted biodegradation model, biodegradation kinetics model to the initial phenol and p-cresot concentrations were investigated and had been fitted by the linear regression. Bacteria capable of degrading p-cresol were isolated from soil by enrichment culture technique. Among them, strain Ml capable of degradillg p.rcresol has also degraded phenal and was identified as the genus Micrococcus from the results from of taxonomical studies. The optimal tonditlons for the biodegradation of phenal and p-cresol by Micrococcus sp. Ml were $NH_4NO_3$ 0.05%, pH 7.0, 3$0^{\circ}C$, respectively, and medium volume 100m1/250m1 shaking flask. iwicrococcus sp. Ml was able to grow on phenal concentration up to 14mM and p-cresol concelltration up to 0.8mM. With increasing substrate concentraction, the lag period increased, but the maximum specific growth rates decreased. The yield coefficient decreased with increasing substrate concentation. The biodegradation kinetics of phenol and p-cresol were best described by Monod with growth model for every experimented concentration. In cultivation of mixed substrate, p-cresol was degraded first and phenol was second. This result implies that p-cresol and phenol was not degraded simultaneously.

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Long-term simultaneous monitoring observations of SiO and H2O masers toward Mira variable WX Serpentis

  • Lim, Jang Ho;Kim, Jaeheon;Son, Seong Min;Suh, Kyung-Won;Cho, Se-Hyung;Yang, Haneul;Yoon, Dong-Hwan
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.49.1-49.1
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    • 2021
  • We carried out simultaneous monitoring observations of five maser lines, H2O (22 GHz), SiO 𝝊 =1, 2, J =1-0 (43.1, 42.8 GHz), and SiO 𝝊 =1, J=2-1, J =3-2 (86.2, 129.3 GHz), toward the Mira variable star WX Serpentis with the 21-m antennas of the Korean VLBI Network (KVN) in 2009-2021 (~12 years). Most spectra of the H2O maser are well separated into two parts of two blue- and one redshifted features within ± 10 km s-1 of the stellar velocity. All detected SiO masers are generally concentrated within ± 5 km s-1 of the stellar velocity, and sometimes appear split into two components. Overall, the profiles of SiO and H2O masers detected in WX Serpentis illustrate typical characteristics of the Mira variable. In addition, flux variations of both SiO and H2O masers are well correlated with the optical light curve of the central star, showing a phase lag of ~ 0.1 for SiO masers and ~ 0.2 for H2O maser. This phenomenon is considered to be the direct effect of propagating shock waves generated by the stellar pulsation, because SiO and H2O masers are sequentially distributed at different positions with respect to the central star. In addition, we analyzed long-term trends and characteristics of maser velocities, maser ratio, and the velocity extents (the full width at zero power; FWZP). We also investigated a spectral energy distribution (SED) ranging from 1.2 to 240 ㎛ obtained using several infrared data: 2MASS, WISE, IRAS, ISO, COBE DIBRE, RAFGL, and AKARI (IRC and FIS). From the IRAS LRS and ISO SWS spectra of this star, we identified 9.7 and 12 ㎛ silicate emission features consistent with the SE6 spectrum model, corresponding to the typical AGB phase.

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Effects of Activated Carbon Particle Sizes on Caffeine Adsorptions (활성탄 입자 크기가 카페인 흡착에 미치는 영향)

  • Kim, Tae-Yang;Do, Si-Hyun;Hong, Seong-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.3
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    • pp.407-414
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    • 2015
  • The effect of activated carbon particle diameter (i.e. US sieve No. $8{\times}10$ ($d_p{\approx}2.19mm$), $18{\times}20$ ($d_p{\approx}0.92mm$), $50{\times}60$ ($d_p{\approx}0.27mm$) and $170{\times}200$ ($d_p{\approx}0.081mm$) on caffeine adsorption is investigated. BET surface area was increased with decreasing particle diameter ($d_p$), and caffeine adsorption rates increased with decreasing $d_p$. Moreover, pseudo-second order model is predicted the experimental data more accurately than pseudo-first order model, and the fastest rate constant ($k_2$) was $1.7g\;mg^{-1}min^{-1}$ when $d_p$ was 0.081 mm. Surface diffusion coefficient (Ds) was decreased with decreasing $d_p$ based on the minimum sum of square error (SSE). Practically, certain ranges of Ds are acceptable with high reliability ($R^2$) and it is determined that the effect of $d_p$ on Ds is unclear. The effect of pH on caffeine adsorption indicated the dependency of m/L ratio (mass liquid ratio) and $pH_{pzc}$. The $pH_{pzc}$ (i.e. $7.9{\pm}0.2$) was not affected by $d_p$. The higher caffeine adsorption at pH 4 and pH 7 than at pH 10 is due to $pH_{pzc}$, not $pk_a$ of caffeine.

A new bridge-vehicle system part II: Parametric study

  • Chan, Tommy H.T.;Yu, Ling;Yung, T.H.;Chan, Jeffrey H.F.
    • Structural Engineering and Mechanics
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    • v.15 no.1
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    • pp.21-38
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    • 2003
  • The formulation of a new bridge-vehicle system using shell with eccentric beam elements has been introduced in a companion paper (Part I). The new system takes into account of the contribution of the twisting and pitching modes of vehicles to the bridge responses. It can also be used to study the dynamic transverse load distribution of a bridge. This paper presents a parametric study on the impact induced by one vehicle or multi-vehicle running across a bridge using the proposed model. Several parameters were considered as variables including the mass ratio, the speed parameter, the frequency ratio and the axle spacing parameter to investigate their effects on the impact factor. A total number of 189 cases were carried out in this parametric study. Within the realistic range of vehicle considered, the maximum impact factors could be 2.24, 1.78 and 1.49 for bridges with spans 10 m, 20 m and 30 m respectively.

Turning Behavior of Tractor-Trailer System by Computer Simulation (컴퓨터 시뮬레이션에 의한 트랙터와 트레일러의 선회운동)

  • Kim, J.H.;Choi, C.H.
    • Journal of Biosystems Engineering
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    • v.16 no.4
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    • pp.346-354
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    • 1991
  • Turning behavior of tractor-trailer system was studied to guide the tractor and trailer. Based upon kinematic relationship between the tractor and the trailer, a mathematical model was developed and analyzed by computer simulation. A field test was carried out to verify the mathematical model. Following conclusions were drawn from this study. 1. A mathematical model and a simulation program for turning behavior of tractor-trailer system were developed. 2. The results of the field tests showed that the RMS errors were less than 0.33m and the mathematical model based upon kinematic relationship can be used for mapping guidance system for tractor and trailer. 3. As the steering angle was increased, the turning radius was decreased. When the tractor travelled at the low speed, the travel speed of the tractor did not affect turning radius but did affect running time and stability for steering. 4. When the tractor travelled under the critical velocity, the towed trailer followed smoothly. When the the tractor travelled faster than the critical velocity, the towed trailer oscillated. The critical velocity was determined from the specification of the tractor and the trailer.

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Mass inflow history of satellite systems around a dwarf galaxy

  • Chun, Kyungwon;Shin, Jihye;Kim, Sungsoo S.
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.2
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    • pp.63.4-64
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    • 2016
  • We aim to investigate inflow history of matters that fall into the satellite systems around a dwarf galaxy in Lambda-Cold Dark Matter model. Each satellite system has unique properties because all satellite systems have different mass inflow history by environments and/or the events such as cosmic reionization and merging with other halos. To trace mass inflow history of the satellite systems, we perform three different cosmological zoom simulations whose galaxy mass is ${\sim}10^{10}M_{sun}$. Each initial zoom simulation covers a cubic box of $1Mpc/h^3$ with 17 million particles. Particle mass for dark matter (DM) and gas components is $M_{DM}=4.1{\times}10^3M_{sun}$ and $M_{gas}=7.9{\times}10^2M_{sun}$, respectively. Thus, each satellite system is resolved with more than hundreds - thousands of particles. We analyze the influence of the gravitational interaction with host galaxy, baryonic matter inflow by various cooling mechanisms, and merging events with other halos on the mass inflow history of satellite systems.

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Molecular Mechanism of Atopic Dermatitis Induction Following Sensitization and Challenge with 2,4-Dinitrochlorobenzene in Mouse Skin Tissue

  • Kim, JiYoun;Lee, JaeHee;Shin, SoJung;Cho, AhRang;Heo, Yong
    • Toxicological Research
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    • v.34 no.1
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    • pp.7-12
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    • 2018
  • Laboratory animal models have been developed to investigate preventive or therapeutic effect of medicinal products, or occurrence or progression mechanism of atopic dermatitis (AD), a pruritic and persistent inflammatory skin disease. The murine model with immunologic phenomena resembling human AD was introduced, which demonstrated skewedness toward predominance of type-2 helper T cell reactivity and pathophysiological changes similar as human AD following 2,4-dinitrochlorobenzene (DNCB) sensitization and challenge. Molecular mechanism on the DNCB-mediated AD was further evaluated. Skin tissues were collected from mice treated with DNCB, and each tissue was equally divided into two sections; one for protein and the other for mRNA analysis. Expression of filaggrin, an important protein for keratinocyte integrity, was evaluated through SDS-PAGE. Level of mRNA expression for cytokines was determined through semi-quantitative reverse transcriptase polymerase chain reaction. Expression of filaggrin protein was significantly enhanced in the mice treated with DNCB compared with the vehicle (acetone : olive oil = 4 : 1 mixture) treatment group or the normal group without any treatment. Level of tumor necrosis factor-alpha and interleukin-18 mRNA expression, cytokines involved in activity of type-1 helper T ($T_H1$) cell, was significantly downregulated in the AD group compared with other control groups. These results suggest that suppression of $T_H1$ cell-mediated immune response could be reflected into the skin tissue of mice treated with DNCB for AD induction, and disturbance of keratinocyte integrity might evoke a compensatory mechanism.

Long-Range Transported SO2 Inflow fromAsian Continent to Korea Peninsula Using OMI SO2 Data and HYSPLIT Backward Trajectory Calculations (OMI 이산화황자료와 HYSPLIT 역궤적 계산을 이용한 동북아지역의 장거리 수송되는 이산화황 유입량 산출)

  • Park, Junsung;Hong, Hyunkee;Choi, Wonei;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.30 no.6
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    • pp.743-754
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    • 2014
  • In this present paper, we, for the first time, calculated $SO_2$ inflow from China to Korea peninsula based on OMI $SO_2$ products and HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) backward trajectory calculations. The major factors used to estimate $SO_2$ flux are long range transported $SO_2$ concentration, transport speed of air mass, and thickness of transported air mass layer. The mean and maximum $SO_2$ fluxes are estimated to be 0.81 and $2.11g{\cdot}m^{-2}{\cdot}h^{-1}$, respectively based on OMI products while, those of $SO_2$ fluxes are 0.50 and $1.18g{\cdot}m^{-2}{\cdot}h^{-1}$ respectively using insitu data obtained at the surface. For most cases, larger $SO_2$ inflow values were found at the surface than those estimated for the air mass layer which extends from surface up to 1.5 km. However, increased transport speed of air mass leads to the enhanced $SO_2$ flux at the altitude up to 1.5 km at the receptor sites. Additionally, we calculate uncertainties of $SO_2$ flux using error propagation method.

2 GHz Down Conversion MMIC Mixer using SiGe HBT Foundry (SiGe HBT 공정을 이용한 2 GHz Down Conversion MMIC Mixer 개발)

  • S.-M. Heo;J.-H. Joo;S.-Y. Ryu;J.-S. Choi;Y.-H. Nho;B.-S. Kim
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.13 no.8
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    • pp.764-768
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    • 2002
  • In this paper, a double balanced gilbert cell MMIC mixer was realized in Tachyonics SiGe HBT technology. The fabricated mixer has 17 dB conversion gain, 9.8 dB noise figure, -4.2 dBm output 1 dB compression point, -27 dBc RF to IF isolation, and the good input, output matching characteristics. It draws 10 mA from a 3 V supply. The simulation and the measured results are closer to each other, which confirms accuracy of the model library and reliability of the process.