• Title/Summary/Keyword: $LiNbO_3$ crystal

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이층구조의 전반로를 갖는 단성표면파의 온도특성 (Temperature Characteristics of Elastic Layer Mode Propagating on Piezoelectric Crystal)

  • 김완상
    • 대한전자공학회논문지
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    • 제10권6호
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    • pp.56-61
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    • 1973
  • 압전 결정 LiNbO3에서 탄성표면파(Rayleigh 표면파)의 온도계수가 가장 작은 131° 로테이트 Y캇트의 전반로에 Ag와 Pd를 증착하여 증착막의 두께에 따른 위상속도의 변화와 위상속도의 온도계수의 변화를 수치해석방법에 의하여 계산하였다. 계산한 결과 Ag의 경우는 증착막의 두께가 증가함에 따라 온도계수가 급격히 증가하나 Pd의 경우는 증가와 감소의 불규칙성을 보이며 wh=9000에서 -36×10 /℃의 위상속도의 온도계수의 최소치를 얻었다.

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광메모리 단결정의 성장과 그 특성 (Crystal Growth and their photorefractive properties for optical memo)

  • 유영문
    • 방송과미디어
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    • 제6권1호
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    • pp.78-87
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    • 2001
  • 광메모리 시스템의 실용화에 기여할 수 있을 것으로 기대되고 있는 가장 대표적인 포토리프렉티브 결정 7종에 대해 개관하였다. 각 결정에 대한 고균질 광학결정의 성장 조건의 문제점들을 다음의 3가지 결정성장법에 따라 논의 하였다. (1) 용액인상법에 의한 $LiNbO_3$$Bi_{12}SiO_{20}$ (2) TSSG 법에 의한 $Bi_{12}TiO_{20}$, $KNbO_3$, $BaTiO_3$, (3) 소테파노프법에 의한 $(Sr_{1-x} Ba_{x})$$Nb_2O_6$, $(K_{1-y}Na_y)_{2A-2} (Sr_{1-x}Ba_x)_{2-A}Nb_{2}O_{6}$, 또한 결정의 포토리프렉티브의 기능성에 대한 재료적 성능지수 $Q_1$, $Q_2$및 감도에 대하여 논의하였다.

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Li-Mn계 산화물의 치환 및 첨가에 따른 물성 변화 (Properties Changing depends on Substituents or Dopants of Li-Mn oxide material)

  • 이대진;지미정;최병현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.289-289
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    • 2007
  • Spinel structured $LiMn_2O_4$ is more economic and environmental friendly to be used as commercial active material for secondary battery compared to Co-oxide material active material, but spinel structure of $LiMn_2O_4$ is unstable and its capacitance decreases with increase of cycle. Therefore, the purpose of our sturdy is to improve the stability of $LiMn_2O_4$ spinel structure and increase its capacitance by using substituents or dopants. $LiMn_2O_4$ powder was synthesized by charging substituents or dopants mole fractions, and temperatures. Crystal state, structure and specific surface area of the synthesized powder were measured and also characteried electrochemically by measuring its impedance, charge-discharge capacitance and etc.

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광도파로 제작을 위한 단결정 LiNbO3 건식 식각 특성 (Dry Etching Characteristics of LiNbO3 Single Crystal for Optical Waveguide Fabrication)

  • 박우정;양우석;이한영;윤대호
    • 한국세라믹학회지
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    • 제42권4호
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    • pp.232-236
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    • 2005
  • $LiNbO_{3}$ optical waveguide 구조를 neutral loop discharge plasma 방법으로 식각시 As과 $C\_{3}F_{8}$가 혼합된 가스 유량에 따른 식각속도와 표면조도 값의 특성을 관찰하였다. 식각 후 식각속도와 식각단면은 scanning electron microscopy로 비교 분석하였으며, 표면조도는 atomic force microscopy로 측정하였다. Ar과 $C_{3}F_{8}$가 혼합된 가스 유량비를 각각 0.1-0.5로 증가시킴에 따라 식각속도와 표면조도는 0.2에서 가장 높게 나타났으며, bias power를 증가함에 따라 300W에서 가장 우수한 식각속도와 가장 평탄한 표면 형상을 얻을 수 있었다.

Frequency Tuning Characteristics of a THz-wave Parametric Oscillator

  • Li, Zhongyang;Bing, Pibin;Xu, Degang;Yao, Jianquan
    • Journal of the Optical Society of Korea
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    • 제17권1호
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    • pp.97-102
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    • 2013
  • Frequency tuning characteristics of a THz-wave by varying phase-matching angle and pump wavelength in a noncollinear phase-matching THz-wave parametric oscillator (TPO) are analyzed. A novel scheme to realize the tuning of a THz-wave by moving the cavity mirror forwards and backwards is proposed in a noncollinear phase-matching TPO. The parametric gain coefficients of the THz-wave in a $LiNbO_3$ crystal are explored under different working temperatures. The relationship between the poling period of periodically poled $LiNbO_3$ (PPLN) and the THz-wave frequency under the condition of a quasi-phase-matching configuration is deduced. Such analyses have an impact on the experiments of the TPO.

GROWTH AND CHARACTERIZATIONS OF $La_3Ga_5SiO_{14}$ SINGLE CRYSTALS AND SINTERED BODY FOR THE APPLICATIONS OF FILER AND RESONATOR

  • Jung, Il-Hyoung;Kyung Joo;Shim, Kwang-Bo;Auh, Keun-Ho
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1998년도 PROCEEDINGS OF THE 15TH KACG TECHNICAL MEETING-PACIFIC RIM 3 SATELLITE SYMPOSIUM SESSION 4, HOTEL HYUNDAI, KYONGJU, SEPTEMBER 20-23, 1998
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    • pp.73-77
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    • 1998
  • Langasite(La3Ga5SiO14) is a new piezoelectric material which is similar to quartz, LN(LiNbO3) and LT(LiTaO3) in its acoustic behavior. In this study, pure Langasite and Langasite family groups were synthesized by the solid state reactions in air. For the synthesis process, diffusion species were investigated and sintered body of synthesized powders were studied on dielectric property according to surface microstructures.

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YCa$_4$O$({BO_3})_3$ 단결정 성장 및 2차고조파 발생 (Crystal Growth and Second Harmonic Generation of YCa$_4$O$({BO_3})_3$)

  • Yu, Young-Moon;A. Ageyev;Jeong, Suk-Jong
    • 한국광학회:학술대회논문집
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    • 한국광학회 2000년도 하계학술발표회
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    • pp.88-89
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    • 2000
  • The properties for self-frequency doubling (SFD) is unique phenomena for a small number of special single crystals. It is known that there are serious limitations to vary the concentration of active ions, for example high doping of active ions from 1 to 50 atomic %, in nonlinear materials. Until now, the Nd:YAl$_3$(BO$_3$)$_4$ (YAB) and Nd:(Ce,Gd)Sc$_3$(BO$_3$)$_4$ (CSB) crystals with high doping rates are well studied for the application of SFD purpose. They have much useful SFD properties, but also have big problems in crystal growth. In case of YAB crystal, it can be grown by solution melt method with very low growth rates and easy occurrence of inclusions. In case of CSB crystal, it has optically heterogeneity problems because of disarrangement of ions in huntite structure [1]. These problems make above crystals not so attractive for optical applications. Some popular nonlinear materials, such as LiNbO$_3$(LN), KTiOPO$_4$(KTP), LiB$_3$O$_{5}$ (LBO) crystals, are impossible to substitute by Rare Earth activators because of their crystallo-chemical problems of structure. When we dope active ions with the requisite concentrations for laser generation, it results in decreasing of optical quality of crystals or destroying of acentrosymmetric structure. (omitted)d)

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Figures of Merit of (K,Na,Li)(Nb,Ta)O3 Ceramics with Various Li Contents for a Piezoelectric Energy Harvester

  • Go, Su Hwan;Kim, Dae Su;Han, Seung Ho;Kang, Hyung-Won;Lee, Hyeung-Gyu;Cheon, Chae Il
    • 한국세라믹학회지
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    • 제54권6호
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    • pp.530-534
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    • 2017
  • The figures of merit in the on-resonance and off-resonance conditions ($FOM_{on}$ and $FOM_{off}$) for the piezoelectric energy harvester (PEH) were measured and compared in $[(K_{0.485}Na_{0.515})_{1-X}Li_X](Nb_{0.99}Ta_{0.01})O_3$ (x = 0.04 ~ 0.09) (KNLNT) ceramics with various Li contents. The crystal structure of CuO-doped KNLNT ceramics changes from orthorhombic to tetragonal around the Li fraction of 0.065. The stable temperature range for the tetragonal phase widens to both higher and lower temperatures as Li is substituted. The piezoelectric charge constant ($d_{33}$), electromechanical coupling factor ($k_p$) and mechanical quality factor ($Q_m$) have maximum values at the Li fraction between 0.055 and 0.065 where the phase boundary lies between the orthorhombic and tetragonal phases. Both $FOM_{on}$ and $FOM_{off}$ have peak values around the phase boundary but the peak compositions are not exactly coincided. The optimal Li fraction in the KNLNT ceramic for a PEH application was found to be between 0.055 and 0.065.

외부전계 인가에 의한 조화용융조성 LiNbO3 결정의 주기적 분극반전 (Congruent LiNbO3 Crystal Periodically Poled by Applying External Field)

  • 권순우;양우석;이형만;김우경;이한영;윤대호;송요승
    • 한국세라믹학회지
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    • 제42권11호
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    • pp.749-752
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    • 2005
  • When an electric field higher than a characteristic coercive field is applied to a ferroelectric such as $LiNbO_3$, the orientation of the spontaneous polarization is reversed, which causes the reversal of the sign of odd-rank tensor properties such as electro-optic and nonlinear optic coefficients. A fabrication process of insulator and periodic external field assisted poling of a z-cut $LiNbO_3$ have been optimized for a periodic $180^{\circ}$ phase inversion along z-axis. The poling jig and the poling control system, fully controlled by a computer, for high quality and reproducible PPLN fabrication have been devised. Periodically polarization reversed PPLN was adjusted based on the fabricated thickness of insulator. The poling structure of PPLN was observed under a microscope after etching PPLN samples by an etching solution ($HF:HNO_3$ = 1 : 2) for about 15 min.

GROWTH AND CHARACTERIZATION OF $La_3Ga_5SiO_{14}$ SINGLE CRYSTALS BY THE FLOATING ZONE METHOD

  • Yoon, Won-Ki;Auh, Keun-Ho
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1999년도 PROCEEDINGS OF 99 INTERNATIONAL CONFERENCE OF THE KACG AND 6TH KOREA·JAPAN EMG SYMPOSIUM (ELECTRONIC MATERIALS GROWTH SYMPOSIUM), HANYANG UNIVERSITY, SEOUL, 06월 09일 JUNE 1999
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    • pp.253-269
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    • 1999
  • The development of telecommunication and information technology requires to develop new piezoelectric materials with small size, low impedance, wide pass band width and high thermal stability of frequency. Langasite (La3Ga5SiO14) single crystal has been researched substitute of quartz and LiNbO3 for the applications of SAW filter, BAW filter and resonator. Its single crystal growth has been carried out by Czochralski Method. So, in order to get single crystal with higher quality, in this study, lnagasite (La3Ga5SiO14) single crystal was grown by using Floating Zone (FZ) method and characterized. For the growth of langasite single crystals, the langasite powder was synthesized at 135$0^{\circ}C$ for 5hrs and the feed rod was sintered at 135$0^{\circ}C$ for 5hrs. The growing rate was 1.5mm/h and the rotation speed was 15 rpm for an upper rotation and 13 rpm for a lower rotation. In order to prevent the evaporation of gallium oxide, Ar and O2 gas mixture was flowed. The growth direction was analyzed by Laue back-scattered analysis. The composition of grown crystal was analyzed suing XRD and WDS. The electrical properties of grown crystal at various frequencies and temperature were discussed.

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