• Title/Summary/Keyword: $LiAlH_4$

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A femtosecond Cr:LiSAF laser pumped by semiconductor lasers (반도체 레이저 여기 펨토초 Cr:LiSAF 레이저)

  • 박종대
    • Korean Journal of Optics and Photonics
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    • v.11 no.5
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    • pp.360-364
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    • 2000
  • We demonstrate self-starting passIve mode locking of a Cr:LiSAF laser, using a SCIDlconduclor Saturable Absorber Mirror (SESAM), Two high-power red semiconductor lasers (Coherent S-67-500C-100-H) of wavelength 667 nm and maximum power of 500 mW were used as pump lasers, The cavity has 10 cm radius-ai-curvature folding minors, two SF 10 prisms, a 99% reflectivity output coupler and a SESAM at dIe focus of a 10 cm radIus-at-curvature mirror. We used the laser crystal in BrewsterBrewster shape with 1 5% $Cr^{+3}$ ion concentration and the length of 6 mm, An X-shaped resonator was used to compensate the astigmatism induced by tile crystal. The structure of the SESAM cOllSists of 30 pmr of $AlAs/Al_{0.15}Ga_{0.85}As$ layer, wi1l1 a 10 nm GaAs quantum well situated in the topmost layer Output spectra were centeled at 833 nm, with 4 nm spectral bandwidth and pulse width was measured to be 220 fs, Output power of 3 mW is obtained at a pump power of 800 mW. 00 mW.

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Optimization of Rod-shaped γ-LiAlO2 Particle Reinforced MCFC Matrices by Aqueous Tape Casting (수계 테이프 케스팅 법에 의한 봉상 γ-LiAlO2 입자 강화 MCFC 매트릭스 제조 공정의 최적화)

  • Choi, Hyun-Jong;Shin, Mi-Young;Hyun, Sang-Hoon;Lim, Hee-Chun
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.282-287
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    • 2009
  • Rod-shaped particle reinforced $LiAlO_2$ matrices for MCFC were fabricated by an aqueous tape-casting technique. The hydrolysis reaction and agglomeration of $\gamma-LiAlO_2$ particles in aqueous slurries were inhibited by additions of $LiOH{\cdot}H_2O$ and glycerin to the aqueous $\gamma-LiAlO_2$ slurry. The tape-casting, performed using the aqueous slurry containing protein albumin, was fast and led to an effective drying at casting temperature range of $60{\sim}65^{\circ}C$. The strength of the particle reinforced matrix was improved about 4 times compared to that of matrix without reinforcement. Pore size distribution ($0.1{\sim}0.4{\mu}m$) and porosity ($50{\sim}60%$) of the reinforced matrices were determined to be appropriate for the MCFC matrix. The aqueous tape casting process is not only environmental-friendly but also efficient for fabricating MCFC matrices compared to non-aqueous tape casting.

The Effect of Low Melting Point Phase on Mechanical Properties of Al-Cu-Li-X(In, Be) Alloys (Al-Cu-Li-X(In, Be) 합금의 기계적 성질에 미치는 저융점상의 영향)

  • Lee, J.S.;Lee, S.H.;Kim, S.W.;Woo, K.D.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.4
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    • pp.245-254
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    • 1995
  • The purpose of this study was to examine the effects of low melting point phase(LMPP) on mechanical properties in the Al-Cu-Li-X(In, Be) alloys. This study was performed by the differential scanning calorimetry(DSC), the transmission electron microscope(TEM), hardness test, tensile test and notch tensile test. The shape of LMPP in the specimens homogenized at $570^{\circ}C$ was film type due to remelting at grain boundary during homogenization. Low melting point phases had no effects on mechanical properties in the aging treated materials, because the density of LMPPs was low. Mechanical properties of the aging treated materials were affected by the density of matrix precipitation phases and grain sizes. For the In or In, Be added Al-Cu-Li alloys, the optimum solution treatment temperature was $550^{\circ}C$. The strength of Al-Cu-Li-In-Be $T_6$ treated alloy was higher than that of 2090-$T_8$ alloy.

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Synthesis and Conductive Properties of Li1+xAlxTi2-x(PO4)3 (x = 0, 0.3, 0.5) by Sol-Gel Method (Sol-Gel법에 의한 Li1+xAlxTi2-x(PO4)3 (x = 0, 0.3, 0.5)의 합성 및 전도특성)

  • Moon, Jung-In;Cho, Hong-Chan;Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.22 no.7
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    • pp.346-351
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    • 2012
  • $Li_{1+x}Al_xTi_{2-x}(PO_4)_3$(LATP) is a promising solid electrolyte for all-solid-state Li ion batteries. In this study, LATP is prepared through a sol-gel method using relatively the inexpensive reagents $TiCl_4$. The thermal behavior, structural characteristics, fractured surface morphology, ion conductivity, and activation energy of the LATP sintered bodies are investigated by TG-DTA, X-ray diffraction, FE-SEM, and by an impedance method. A gelation powder was calcined at $500^{\circ}C$. A single crystalline phase of the $LiTi_2(PO_4)_3$(LTP) system was obtained at a calcination temperature above $650^{\circ}C$. The obtained powder was pelletized and sintered at $900^{\circ}C$ and $1000^{\circ}C$. The LTP sintered at $900{\sim}1000^{\circ}C$ for 6 h had a relatively low apparent density of 75~80%. The LATP(x = 0.3) pellet sintered at $900^{\circ}C$ for 6 h was denser than those sintered under other conditions and showed the highest ion conductivity of $4.50{\times}10^{-5}$ S/cm at room temperature. However, the ion conductivity of LATP (x = 0.3) sintered at $1000^{\circ}C$ decreased to $1.81{\times}10^{-5}$ S/cm, leading to Li volatilization and abnormal grain growth. For LATP sintered at $900^{\circ}C$ for 6 h, x = 0.3 shows the lowest activation energy of 0.42 eV in the temperature range of room temperature to $300^{\circ}C$.

A Study on the Aging Behavior of a Mg-8.5Li-4.5Al alloy by Differential Scanning Calorimetry (열분석법에 의한 Mg-8.5Li-4.5Al합금의 시효거동 연구)

  • Kim, Y.W.;Hwang, Y.H.;Park, T.W.;Kim, D.H.;Hong, C.P.
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.4
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    • pp.255-265
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    • 1997
  • Precipitation and strengthening mechanisms in squeeze cast Mg-8.5wt%Li-4.5wt%Al have been investigated by differential scanning calorimetry(DSC), scanning electron microscopy(SEM), in-situ and ex-situ X-ray diffraction analysis and hardness measurement. Special emphasis was placed on the investigation of the precipitation behavior by the DSC technique. Microstructural and calorimetric analysis showed that ${\theta}$ and ${\delta}$ precipitates in the b.c.c. ${\beta}$ phase matrix, forming two exothermic peaks at the temperature ranges of $130^{\circ}C{\sim}180^{\circ}C$ and $236^{\circ}C{\sim}280^{\circ}C$. ${\theta}$ and ${\delta}$ dissolve into the matrix forming an endothermic peak at the temperature range of $280^{\circ}C{\sim}352^{\circ}C$. The as-cast microstructure consists of ${\alpha}$, ${\beta}$ and ${\delta}$. Peak strength was obtained after aging for 1 hour at $50^{\circ}C$. The aging time required for the peak strength decreased as the aging temperature increases. The hardness decrease during overaging was due to the coarsening of ${\theta}$ precipitates. Microhardness measurement showed that variation of the hardness of ${\beta}$ matrix was more pronounced than that of the ${\alpha}$ phase, indicating that the ${\beta}$ phase is more responsible for the strengthening of the Mg-8.5wt%Li-4.5wt%Al alloy.

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Synthesis and Electroluminescent Properties of Diphenyl Benzeneamine Derivatives as Dopant Material

  • Seo, H.J.;Park, H.C.;Chung, T.G.;Lee, S.E.;Park, J.W.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.955-958
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    • 2003
  • We report the photo-(PL) and electroluminescence (EL) properties of new conjugated compounds based on diphenyl benzeneamine moiety, 4,4'-(1,4-phenylenedi-(1E)-2,1-ethenediyl]bis(N,N-diphenyl-benzenamine](PEDB) and 4,4'-([1,1 -biphenyl]-4,4'-diyldi-2,1-ethenediyl)bis[N,N-diphenyl-benzenamine)(BPEDB), as emitting materials and dopant materials. The ITO/m-MTDATA/NPB/DPVBi + BPEDB(1%) /Alq3/LiF/Al device shows blue EL spectrum at 458nm and high efficiency(5.3 cd/A). PEDB as dopant shows also blue EL spectrum around ${\lambda}$ max=463nm and 4.1 cd/A high efficiency in ITO/m-MTDATA/NPB/DPVBi + PEDB(1%)/Alq3/LiF/Al device.

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Impedance spectroscopy analysis of polymer light emitting diodes with the LiF buffer layer at the cathode/organic interface (LiF 음극 버퍼층을 사용한 폴리머의 효율 향상에 관한 임피던스 분석)

  • Kim, H.M.;Jang, K.S.;Yi, J.;Sohn, Sun-Young;Park, Kuen-Hee;Jung, Dong-Geun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.277-278
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    • 2005
  • Admittance Spectroscopic analysis was applied to study the effect of LiF buffer layer and to model the equivalent circuit for poly(2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene) (MEH-PPV)-based polymer light emitting diodes (PLEDs) with the LiF cathode buffer layer. The single layer device with ITO/MEH-PPV/Al structure can be modeled as a simple parallel combination of resistor and capacitor. Insertion of a LiF layer at the Al/MEH-PPV interface shifts the highest occupied molecular orbital level and the vacuum level of the MEH-PPV layer as a result the barrier height for electron injection at the Al/MEH-PPV interface is reduced. The admittance spectroscopy measurement of the devices with the LiF cathode buffer layer shows reduction in contact resistance ($R_c$), parallel resistance ($R_p$) and increment in parallel capacitance ($C_p$).

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The properties of a low expansion glass ceramics of $Li_{2}O-Al_{2}O_{3}-SiO_{2}$ system ($Li_{2}O-Al_{2}O_{3}-SiO_{2}$계 저팽창 결정화 유리의 특성)

  • Kim, Bok-Hee;Ko, Jung-Hoon;Nam, O-Jung;Kang, Woo-Jin;Lee, Chang-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.2
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    • pp.79-83
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    • 2009
  • The glass-ceramic of the $Li_{2}O-Al_{2}O_{3}-SiO_{2}$ system was investigated to develop the low thermal expansion materials. The glass of this system was heat treated at $775^{\circ}C$ for 2 h for nucleation and subsequently at $825{\sim}900^{\circ}C$ for 2 h for crystallization. The crystal structure of the glass-ceramic of this system was a single phase of $\beta$-quartz solid solution($Li_{x}Al_{x}Si_{1-x}O_{2}$). The thermal expansion of the glass-ceramic showed $4.40{\times}10^{-7}{\sim}1.33{\times}10^{-6}K^{-1}$ between $25{\sim}300^{\circ}C$ and $1.56{\times}10^{-6}{\sim}2.53{\times}10^{-6}K^{-1}$ between $25{\sim}800^{\circ}C$, higher than lower temperature range. The mechanical strength remained almost same at around high 110 MPa with heating temperature changes.

Corrosion Behavior of Superalloys in Hot Molten Salt under Oxidation Atmosphere (고온용융염계 산화분위기에서 초합금의 부식거동)

  • 조수행;임종호;정준호;이원경;오승철;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.285-291
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    • 2004
  • As a part of assessment of the structural material for the molten salt handling system, corrosion behavior of Inconel 718, X-750, Haynes 75 and Haynes 263 alloys in the molten salt of LiCl-Li$_2$O-O$_2$was investigated in the range of temperature; $650^{\circ}C$, time; 24~168h, $Li_2O$; 3wt%, mixed gas; Ar~10%$O_2$. In the molten salt of LiCl-$Li_2O-O_2$, the order corrosion rate was Haynes 263 < Haynes 75 < Inconel X-750 < Inconel 718. Haynes 263 alloy showed the highest corrosion resistance among the examined alloys. Corrosion products of alloys were as fellows: Haynes 75: $Cr_2O_4$, $NiFe_2O_4$, $LiNiO_2$, $Li_2NiFe_2O_4$, Inconel 718; $Cr_2O_4$, $NiFe_2O_4$, Haynes 263; $Li(Ni,Co)O_2$, $NiCr_2O_4$, $LiTiO_2$, Inconel X-750; $Cr_2O_3$, $NiFe_2O_4$,$FeNi_3$, (Al,Nb,Ti)$O_2$. Haynes 263 showed local corrosion behavior and Haynes 75, Inconel 718 and Inconel X-750 showed uniform corrosion behavior.

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