• Title/Summary/Keyword: $Hg^{+2}$

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Production Techniques for Goryeo Wooden Lacquerware (고려시대 목심칠기 木芯漆器의 제작기법 연구)

  • Yi, Yonghee;Park, Suzin;Yun, Eunyoung;Jung, Hyejin
    • Conservation Science in Museum
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    • v.15
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    • pp.78-95
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    • 2014
  • To examine the materials, production techniques, and key features of Goryeo wooden lacquerwares, scientific analysis was conducted on six relevant lacquerware items. All of the items, except for a lacquered bowl duksu 4123, were found to have been made by first covering the surface of the wood with cloth and then varnishing with lacquer. The wooden frames of flower-shaped lacquered case and pine leaves shape lacquered case were made by wrapping thin wood around either the lid or bottom panel. In most cases, microscopic analysis revealed a lower layer of lacquer mixed with bone ash and bone dust, followed by an upper varnish layer of lacquer. SEM-EDS analysis and μ-XRF Micro-X-ray Fluorescence analysis showed that vermilion lacquer mixed with cinnabar was used on the surface. A lid decorated with a dot pattern was made by first varnishing the surface with yellow lacquer mixed with orpiment, and then irregular dot pattern with a mixture of black lacquer and soot. The vermilion lacquer used to varnish the side of the lacquered bowls was composed of lacquer mixed with cinnabar and minium Red Lead.

Study of the Antinociception Induced by Opioids and the Proenkephalin Gene Expression in Spontaneously Hypertensive Rats (선천성 고혈압쥐에서의 Opioid에 의한 진통작용과 Proenkephalin유전자 발현에 대한 연구)

  • Suh Hong-Won;Lee Tae-Hee;Song Dong-Keun;Choi Seong-Ran;Jung Jun-Sub;Kim Yung-Hi
    • The Korean Journal of Pharmacology
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    • v.31 no.1 s.57
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    • pp.17-26
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    • 1995
  • The present studies were carried out to determine if antinociceptive action of morphine and ${\beta}-endorphin$ administered intraventricularly was changed in. pentobarbital anesthetized spontaneously hypertensive rats (SHR) and Wistar-Kyoto (WKY) rats. Antinociception was assessed by the tail-flick test. The $ED_{50}$ values of antinociception for morphine administered intraventricularly were 1.9 and 1.2 nmol for WKY and SHR rats, respectively. The $ED_{50}$ values of antinociception for ${\beta}-endorphin$ administered intraventricularly were 0.40 and 0.12 nmol for WKY and SHR rats, respectively. The $[Met^5]-enkephalin$ (ME) and proenkephalin mRNA levels in midbrain, pons and medulla, or lumbar section of the spinal cord in WKY and SHR rats were measured by the radioimmunoassay and Northern blot assay, respectively. There were no differences of ME and proenkephalin mRNA levels in these tissues between WKY and SHR rats. The results suggest that ${\beta}-endorphin$ but not morphine administered intraventricularly produces a greater antinociception in SHR rats. This increased antinociceptive effect of ${\beta}-endorphin$ in SHR rats may be not, at least, due to the alterations of ME And proenkephalin mRNA levels in the midbrain, pons and medulla, or spinal cord.

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Preparation of High Quality Grape Seed Oil by Solvent Extraction and Chemical Refining Process (용매추출 및 화학적 정제법에 의한 고품질의 포도씨유의 제조)

  • Choi Sang-Won;Chung Ui-Seon;Lee Ki-Teak
    • Food Science and Preservation
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    • v.12 no.6
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    • pp.600-607
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    • 2005
  • This study was conducted to prepare high quality grape seed oils by solvent extraction and chemical refining process. Additionally, quantitative analysis of several functional components in grope seed was carried out to compare quality characteristics of grape seeds from grapes grown by conventional and organic agricultural practices. There are no significant differences in several functional constituents of grape seeds between conventionally cultivated- and organically cultivated-grapes, although some functional compositions of grape seeds are different between two cultivation methods. The dried grape seed was pretreated with roasting heating for 5 min, milled and then extracted twice with n-hexane under reflux at $50^{\circ}C$ for overnight, followed by filtration and evaporation. The crude grape seed oil was successively purified by degumming with $0.1\%\;H_3PO_4$, deaciding with $20\%\;NaOH$, and then decoloring and deodorization by a steam distillation, and thereby producing purified grape seed oil(yield: $5.0\%/dried$ grape seed). Physicochemical characteristics of the purified grape seed oil were comparable to those of the imported grape seed oils.

Hevey Metal Levels in Urine of Residents in Industrial Area (일부 공단지역 주민의 요 중 중금속 농도에 관한 연구)

  • Jou, Hye-Mee;Choi, Su-Hyeon;Chung, Eun-Kyung;Jung, Soon-Won;Yang, Won-Ho;Son, Bu-Soon
    • Journal of Environmental Science International
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    • v.20 no.5
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    • pp.565-574
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    • 2011
  • This study analyzed the concentration of the heavy metals(Cd, Hg, iAs) of urine(n=576) from May, 2007 to Oct 2007. The subject was residents in G, Y, H industrial area, Jeollanam-do, in which exposure due to the adjacency of the industrial complex. As to the heavy metal concentration in the urine of the residents in the whole exposed region and the comparing region, the content of cadmium, mercury, and inorganic arsenic in the exposed region group were 1.23, 1.85, and 8.80 ${\mu}g$/g_ct respectively, and those of the comparing region group were 1.87, 2.00, and 8.93 ${\mu}g$/g_ct respectively, which indicates that the concentration of the comparing group was higher than that of the exposed group. The heavy metal concentration for each age group increased in proportion to age except those under 10 for some substances(p<0.01). As to geometric mean concentration cadmium and inorganic arsenic in urine according to the smoking history of the subject, the concentration of the smoking group and the non-smoking group were 1.65 ${\mu}g$/g_ct and 9.13 ${\mu}g$/g_ct respectively, while those of the non-smoking group were 1.47 ${\mu}g$/g_ct and 8.91 ${\mu}g$/g_ct respectively, which indicates that the former is higher than the latter. As to the inorganic arsenic concentration in urine according to the food preference, in order of vegetable, fish, and meat showed high concentration (p<0.01). To clarify the factors affecting the heavy metal concentration in urine among the subjects, the multiple regression analysis was conducted. As a result, it turned out that as to cadmium content in urine, gender, age, drinking, and smoking have influence on the subjects, with explanatory adequacy of 37.5 %.

Elemental alteration of the surface of dental casting alloys induced by electro discharge machining (치과용 주조 합금의 방전가공에 따른 표면 성분 변화)

  • Jang, Yong-Chul;Lee, Myung-Kon
    • Journal of Technologic Dentistry
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    • v.31 no.1
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    • pp.55-61
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    • 2009
  • Passive fitting of meso-structure and super-structures is a predominant requirement for the longevity and clinical success of osseointegrated dental implants. However, precision and passive fitting has been unpredictable with conventional methods of casting as well as for corrective techniques. Alternative to conventional techniques, electro discharge machining(EDM) is an advanced method introduced to dental technology to improve the passive fitting of implant prosthesis. In this technique material is removed by melting and vaporization in electric sparks. Regarding the efficacy of EDM, the application of this technique induces severe surface morphological and elemental alterations due to the high temperatures developed during machining, which vary between $10,000{\sim}20,000^{\circ}C$. The aim of this study was to investigate the morphological and elemental alterations induced by EDM process of casting dental gold alloy and non-precious alloy used for the production of implant-supported prosthesis. A conventional clinical dental casting alloys were used for experimental specimens patterns, which were divided in three groups, high fineness gold alloy(Au 75%, HG group), low fineness gold alloy(Au 55%, LG group) and nonprecious metal alloy(Ni-Cr, NP group). The UCLA type plastic abutment patterns were invested with conventional investment material and were cast in a centrifugal casting machine. Castings were sandblasted with $50{\mu}m\;Al_2O_3$. One casting specimen of each group was polished by conventional finishing(HGCON, LGCON, NPCON) and one specimen of each group was subjected to EDM in a system using Cu electrodes, kerosene as dielectric fluid in 10 min for gold alloy and 20 min for Ni-Cr alloy(HGEDM. LGEDM, NOEDM). The surface morphology of all specimens was studied under an energy dispersive X-ray spectrometer (EDS). The quantitative results from EDS analysis are presented on the HGEDM and LGEDM specimens a significant increase in C and Cu concentrations was found after EDM finishing. The different result was documented for C on the NPEDM with a significant uptake of O after EDM finishing, whereas Al, Si showed a significant decrease in their concentrations. EDS analysis showed a serious uptake of C and Cu after the EDM procedure in the alloys studied. The C uptake after the EDM process is a common finding and it is attributed to the decomposition of the dielectric fluid in the plasma column, probably due to the development of extremely high temperatures. The Cu uptake is readily explained from the decomposition of Cu electrodes, something which is also a common finding after the EDM procedure. However, all the aforementioned mechanisms require further research. The clinical implication of these findings is related with the biological and corrosion resistance of surfaces prepared by the EDM process.

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Development of a Functional Mortar for Algae Growth Restraining by Using Soluble Glass (수용성 유리를 이용한 조류 생장 억제형 기능성 모르타르의 개발)

  • Kim, Jun Hwan;Kang, Hojeong;Choi, Se Young;Lim, Yun Mook
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.4
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    • pp.791-799
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    • 2015
  • This study focuses on the algae growth restraining. Many researches on a critical damage from algae growth are published, but it is hard to find how th restrain. Abnormal algae increasing is a problem, because it makes red tides, biodeterioration, etc. Therefore this study aims to decrease the damage from algae growth. Some metal ions have been used microorganism killing materials from old times. Especially, Cu ions are highly effective. Based on these uses of the metal ions, a functional mortar which restrains algae growth is developed. The mortar contains soluble glass which dissolve in water. The soluble glass was made of Cu ions and phosphates. When the soluble glass is dissolved, Cu ions are soaked out stably from the soluble glass. Culture mediums which incubate algae were made to evaluate the developed mortar specimens. Culture mediums were filled with fresh water and sea water. Algae were incubated for fourteen days in culture mediums. The evaluating methods are measuring volume of the dissolved organic carbon and the chlorophyll. Using these two measurements, the mortar specimens are judged that can restrain algae or not. According to the result, the functional mortars of culture medium filled with fresh and sea water shows similar trend. The functional mortar for restraining algae growth performs that's role well.

Hydrogeochemical characteristics of urban groundwater in Seoul

  • Lee, Ju-Hee;Yun, Seong-Taek;Kwon, Jang-Soon;Kim, Dong-Seung;Park, Seong-Sook
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.472-472
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    • 2004
  • Numerous studies on urban groundwater have been carried out in many other countries. Urban groundwater shows a unique hydrologic system because of complex urban characteristics such as road pavement, sewers and public water supply systems. These urban facilities may change the characteristics of groundwater recharge but contaminate its quality as well. There have been several researches on urban groundwater in Seoul. Seoul has been industrialized very rapidly so that the city has large population. The recent population in Seoul amounts to more than ten millions, corresponding to a very high density of about 17, 000 people/km$^2$. Therefore, many factors affect the groundwater quality and quantity in Seoul. Nowadays, groundwater in Seoul is being extracted for construction, industrial use, and drinking and so on. There are 15, 714 wells in Seoul and its annual usage is 41, 425, 977m$^3$(in 2001). Therefore, systematic studies are needed to properly manage and use the groundwater in Seoul. The purposes of this study in progress are to identify geochemical characteristics of groundwater in Seoul and to determine the extent of groundwater contamination and its relationship with urban characteristics. For this study, groundwater was sampled from more than 400 preexisting wells that were randomly selected throughout the Seoul area. For all samples, major cations together with Si, Al, Fe, Pb, Hg For 200 samples among them, TCE, PCE, BTEX were also analyzed by GC. Our study shows that groundwater types of Seoul are distributed broadly from Ca-HCO$_3$ type to Ca-Cl+NO$_3$ type. The latter type indicates anthropogenic contamination. Among cations, Ca is generally high in most samples. In some samples, Na and K are dominant. The dominant anions change widely from HCO$_3$ to Cl+NO$_3$. The anion composition is considered to effectively indicate the contribution of distinct anthropogenic sources. In addition, major ions are positively proportional to total dissolved solid (TDS) except K and NO$_3$. Thus, we consider that TDS may be used as an effective indicator of the extent of pollution. However, the increase of TDS may result from increased water-rock interaction. To determine the extent of groundwater contamination, it is needed to figure out the baseline water quality in Seoul. Furthermore, detailed geochemical studies are required to find out pollution sources and their corresponding hydrochemical parameters.

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Trace Metal Contents in Cultured and Wild fishes from the Coastal Area of Tongyeoung, Korea and their Safely Evaluations (통영연근해역 양식산 및 자연산 어류 중의 미량금속 함량 및 안전성 평가)

  • Choi Jong-Duck;Jeoung In-geon
    • Journal of Food Hygiene and Safety
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    • v.20 no.4
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    • pp.205-210
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    • 2005
  • The content of the trace metals in the cultured and wild fishes were determined. The tested fishes were genuin porgy (Pagrus major) and black porgy (Acanthopogrus schlegeli). The samples of the cultured and wild fishes were collected from slices of raw fish in shops, during 2003 to 2004. The samples were digested with acids, then analyzed by ICP (inductively Coupled plasma Spectrometer) and AAS (Automic Absorption Spectrometer) for the content of lead (Pb), cadmium (Cd), arsenic (As), copper (Cu), manganese (Mn) and zinc (Zn). The content of mercury (Hg) was determined using mercury analyzer. The mean contents of trace metals in cultured and wild fish was 0.031,0.047mg/kg far total-mercury,0.321,0.407 for Pb, 0.048,0.063 for Cd, 1.006, 1.132 for As, 0.467,0.806 for Cu, 0.233, 0.293 for Cr, 9.69, 12.20 for Zn,0.798, 0.624 mg/kg far Mn, respectively. The content of all the trace metals except manganese in wild fish was more than that in cultured fish. The highest level of total-mercury, lead, cadmium, zinc, chromium and arsenic in the samples analyzed were all below the quarantine limit of Korean regulation and guideline established by the U.S. Food and Drug Administration f3r human consumption. The level of the trace metals in the samples was negligible, which could be endogenous. Our data obtained in this study showed that the average weekly intakes of lead, cadmium and mercury from cultured and wild fishes takes about $6\∼13\%$ of Un(Provisional Tolerance Weekley Intakes) that FAO/WHO Joint Food Additive and Contaminants Committee has set to evaluate their safeties.

Accumulation of Heavy Metals in Soil Growing for Red Pepper (Capsicum annuum) with using Lime Bordeaux and Lime Sulphur Mixture

  • Lee, Hyun Ho;Kim, Keun Ki;Lee, Yong Bok;Kwak, Youn Sig;Ko, Byong Gu;Lee, Sang Beom;Shim, Chang Ki;Hong, Chang Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.4
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    • pp.318-324
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    • 2017
  • Lime bordeaux mixture (LBM) and lime sulfur mixture (LSM) are representative environmental friendly organic materials for prevention of insect pests in South Korea. Recently, those have been widely used as an alternative for chemical pesticides in eco-friendly farms. However, South Korea has not established even recommendation of LBM and LSM considering the stability of heavy metals in soil. The aim of this study was to evaluate the accumulation of hazardous heavy metals in soil and plant with long-term application of LBM and LSM. Firstly, we investigated the amount of LBM and LSM used per year in several eco-friendly farms to determine a standard application rate of both materials. The pepper plant was grown on the pot in greenhouse for 14 weeks. Both materials were applied at 0, 1, 3, and 9 times of standard application rates (2.56 and $1.28L\;ha^{-1}$ of LBM and LSM per year, respectively). Dry matter yield of pepper and heavy metals (As, Cd, Cu, Hg, Ni, Pb, and Zn) concentration in soil and pepper plant were measured after 14 weeks. Yield of pepper plant did not significantly chang with up to application rate of 1 times, thereafter it markedly decreased with more than 3 times. With increasing LBM and LSM application, the concentration of Cu and Zn in soil significantly increased. Especially, Zn concentration in pepper significantly increased with increasing application rates of both materials. This might resulted in significant decrease in dry matter yield of pepper. The concentrations of those heavy metals in soil did not exceed safety levels ($150mg\;kg^{-1}$ for Cu and $300mg\;kg^{-1}$ for Zn) established by the Korean Soil Environmental Conservation Act as well as concentration of heavy metals in pepper plant by Korean Ministry of Food and Drug Safety. However, particular attention should be paid for heavy metal safety and crop productivity when using LBM and LSM in the organic farm.

Clinical Patterns of Penetrating Torso Injury at Emergency Department (응급실을 통하여 입원한 체간부 관통상 환자에 관한 임상적인 고찰)

  • Yun, Soon Young;Cheon, Young Jin;Won, Tae Hee
    • Journal of Trauma and Injury
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    • v.18 no.1
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    • pp.47-52
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    • 2005
  • Background: This study was undertaken to evaluate the clinical pattern of the patients with penetrating torso injury. We retrospectively analyzed the clinical symptoms, mechanism of injury, injury type including injured organ, and ultimate outcome of treatment. Our purpose of the study was to establish guideline of management in penetrating torso injury. Methods: This study consists of an analysis of a consecutive series of 94 patients with penetrating injury of trunk treated at one general hospital during 7year period (from January 1995 to April 2003) who was admitted through in our emergency department. All data were collected from the medical records and entered in a database for analysis on the following: age, sex, mechanism of injury, vital sign at admission, clinical outcome including hospital mortality, length of hospital stay, length of intensive care unit stay, requirement of crystalloid fluid and blood product. Results: Among 94 patients, there were 68 men and 26 women, with ages ranging from 19 to 82 years (average 38.2 years). The most frequent mechanism of injury was violence by others including rob (n=54, 57.4%) followed by suicidal attempt (n=24, 25.5%) and accidental injury (n=16, 17.0%). No injury was inflicted from gun. In 37 patients, systolic blood pressure at admission was under 90mmHg. The time interval from injury to admission, and from admission to operation was 57.8minutes and 4hour 12minutes each. Laparotomy was required in 70 patients, thoracotomy in 5 patients, and 3 patients required thoracotomy and laparotomy. Among 94 patients, an average of 1.7 organs were injured. The small bowel and colon were the organs most commonly wounded followed by liver, mesentery, pleura. Of the 94 patients, 6 died for an overall mortality rate of 6.4%, and two of them were not related with hemorrhage. The average length of hospital stay was 18.1 days, and 40 patients required ICU care. Conclusion: Of the 94 patients who were admitted from penetrating torso injury, no patient was injured from firearm. Overall mortality rate was 6.4%. In our hospital, firearm injury was relative rare.