• Title/Summary/Keyword: $H_2O$ content

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Hydrogen Permeance of Ce1-xYxO2-δ Membranes According to Yttrium Content

  • Song, Da-Heoi;Jung, Mie-Won
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.451-453
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    • 2013
  • Porous ceramic membranes consisting of $Ce_{1-x}Y_xO_{2-{\delta}}$ were developed for hydrogen permeation tests. Various amounts (x = 0, 0.05, 0.1, 0.2) of yttrium were doped to ceria to study the effect of yttrium doping on ceria membranes on various properties, including hydrogen permeability. $Ce_{1-x}Y_xO_{2-{\delta}}$ powder was synthesized by the sol-gel method. These membranes were fabricated by pressing and sintering at $1300^{\circ}C$ for 6 h. As the amount of yttrium increased, the grain size of the membrane decreased. Hydrogen permeability was improved as the yttrium content increased. Selective permeability of hydrogen compared to CO is explained by electric conductivity. As the temperature rose, both the hydrogen perm-selectivity and electric conductivity on $Ce_{0.8}Y_{0.2}O_{1.9}$ improved.

Mathematical Models of Respiration Rate of Cucumber Plants under Varying Environmental Conditions (환경 변화에 따른 오이의 호흡속도에 관한 수리적 모형)

  • 임준택;정현희;백선영;현규환;권병선;김학진;정순주;이범선
    • Journal of Bio-Environment Control
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    • v.9 no.4
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    • pp.185-192
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    • 2000
  • This study was conducted to develop mathematical model of respiration rate of cucumber plant under varying environmental conditions. 8.55% of gross photosynthesis of individual cucumber plant was used as respiration. Growth respiration coefficient was estimated as 0.0935. Maintenance respiration rate was estimated as 0.00158g CH$_2$g$^{-1}$ .h$^{-1}$ at 24$^{\circ}C$ of air temperature and it increased exponentially as air temperature became higher. Respiration rate decreased poportionally as content of storage carbohydrate became lower. Ion uptake respiration rate of roots was estimated as 0.6648g C$H_2O$.(gN)$^{-1}$ .

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Effect of CH4 Concentration on the Dielectric Properties of SiOC(-H) Film Deposited by PECVD (CH4 농도 변화가 저유전 SiOC(-H) 박막의 유전특성에 미치는 효과)

  • Shin, Dong-Hee;Kim, Jong-Hoon;Lim, Dae-Soon;Kim, Chan-Bae
    • Korean Journal of Materials Research
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    • v.19 no.2
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    • pp.90-94
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    • 2009
  • The development of low-k materials is essential for modern semiconductor processes to reduce the cross-talk, signal delay and capacitance between multiple layers. The effect of the $CH_4$ concentration on the formation of SiOC(-H) films and their dielectric characteristics were investigated. SiOC(-H) thin films were deposited on Si(100)/$SiO_2$/Ti/Pt substrates by plasma-enhanced chemical vapor deposition (PECVD) with $SiH_4$, $CO_2$ and $CH_4$ gas mixtures. After the deposition, the SiOC(-H) thin films were annealed in an Ar atmosphere using rapid thermal annealing (RTA) for 30min. The electrical properties of the SiOC(-H) films were then measured using an impedance analyzer. The dielectric constant decreased as the $CH_4$ concentration of low-k SiOC(-H) thin film increased. The decrease in the dielectric constant was explained in terms of the decrease of the ionic polarization due to the increase of the relative carbon content. The spectrum via Fourier transform infrared (FT-IR) spectroscopy showed a variety of bonding configurations, including Si-O-Si, H-Si-O, Si-$(CH_3)_2$, Si-$CH_3$ and $CH_x$ in the absorbance mode over the range from 650 to $4000\;cm^{-1}$. The results showed that dielectric properties with different $CH_4$ concentrations are closely related to the (Si-$CH_3$)/[(Si-$CH_3$)+(Si-O)] ratio.

Electrical and Mechanical Strength Properties of Epoxy/Micro Silica and Alumina Composites for Power Equipment (전력기기용, 에폭시/마이크로 실리카 및 알루미나 복합제의 전기적·기계적 파괴 강도 특성)

  • Park, Joo-Eon;Park, Jae-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.7
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    • pp.496-501
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    • 2018
  • In this study, we prepared 40, 45, 50, 55, 60, 65, and 70 wt% content composites filled in epoxy matrix for two micro silica and three micro alumina types for use as a GIS heavy electric machine. As a filler type of epoxy composite, micro silica composites showed excellent AC breakdown strength properties compared to micro alumina composites in the case of electrical properties of micro silica and alumina. The electrical breakdown properties of micro silica composites increased with increasing filler content, whereas those of micro alumina decreased with increasing filler content. In the case of mechanical properties, the micro silica composite showed improved tensile strength and flexural strength compared with the micro alumina composite. In addition, mechanical properties such as tensile strength and flexural strength of micro silica and alumina composites decreased with increasing filler content. This is probably because O-H groups are present on the surface of silica in the case of micro silica but are not present on the surface of alumina in the case of micro alumina.

Inhibitory Effects of Ginseng Total Saponins on Hypoxia-induced Dysfunction and Injuries of Cultured Astrocytes

  • Seong, Yeon-Hee;Kim, Hack-Seang
    • Archives of Pharmacal Research
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    • v.20 no.2
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    • pp.103-109
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    • 1997
  • The effects of ginseng total saponins (GTS) on hypoxic damage of primary cultures of astrocytes were studied. Hypoxia was created by placing cultures in an air tight chamber that was flushed with 95% $N_2/5%CO_2$ for 15 min before being sealed. Cultures showed evidence of significant cell injury after 24 h of hypoxia (increased lactate dehydrogenase (LDH) content in the culture medium, cell swelling and decreased glutamate uptake and protein content). Addition of GTS (0.1, 0.3 mg/ml) to the cultures during the exposure to hypoxic conditions produced dose-dependent inhibition of the LDH efflux. GTS (0.1, 0.3 mg/ml) also produced significant inhibition of the increased cell volume of astrocytes measured by $[^3H]$ O-methyl-D-glucose uptake under the hypoxic conditions. Decreased glutamate uptake and protein content was inhibited by GTS. These data suggest that GTS prevents astrocytic cell injury induced by severe hypoxia in vitro.

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MicrostructuraL Characteristics During Hydrogen Desorption of Mechanical Milled TiH2 (기계적 합금화된 TiH2의 수소방출에 따른 미세조직 특성)

  • Jung S.;Jung Hyun-Sung;Ahn Jae-Pyoung;Park Jong-Ku
    • Journal of Powder Materials
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    • v.13 no.3 s.56
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    • pp.199-204
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    • 2006
  • We manufactured the metal hydrides of $(Ti_{0.88}Mg_{0.12})H_2$ using a very easy and cheap way that Ti-12%Mg blending powder was mechanically milled with liquid milling media such as isopropyl alcohol ($C_3H_8O$, containing oxygen) and hexane ($C_6H_{14}$, no oxygen) as hydrogen source. The $(Ti_{0.88}Mg_{0.12})H_2$ synthesized in isopropyl alcohol contained the high oxygen of 11.2%, while one in hexane had the low oxygen content of 0.7%. Such a difference of oxygen content affected the dehydriding behavior, phase transformation, and microstructural evolution at high temperature, which was investigated through X-ray diffraction and DSC measurements, and electron microscope observations.

Atmospheric Oxidation of Fe-16Cr-6Ni-6Mn-1.7Mo Stainless Steel between 700 and 900℃ (Fe-16Cr-6Ni-6Mn-1.7Mo 스테인리스 합금의 700~900℃에서의 대기중 산화)

  • Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.49 no.2
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    • pp.153-160
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    • 2011
  • The AISI 216L stainless steel with a composition of Fe-16Cr-6Ni-6Mn-1.7Mo (wt.%) was oxidized at $700{\sim}900^{\circ}C$ in air for 100 h. At $700^{\circ}C$, a thin $Mn_{1.5}Cr_{1.5}O_4$ oxide layer with a thickness of $0.4{\mu}m$ formed. At $800^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $FeCr_2O_4$ oxide layer with a total thickness of $30{\mu}m$ formed. The non-adherent scale formed at $800^{\circ}C$ was susceptible to cracking. At $900^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $Mn_{1.5}Cr_{1.5}O_4$ oxide layer formed, whose total thickness was $10{\sim}15{\mu}m$. The scales formed at $900^{\circ}C$ were non-adherent and susceptible to cracking. 216 L stainless steel oxidized faster than 316 L stainless steel, owing to the increment of the Mn content and the decrement of Ni content.

Effect of Simulated Acid Rain on Fatty Acid Composition and Antioxidant System in Garden Balsam(Impatiens balsamina L.) (인공산성비가 봉선화(Impatiens balsamina L.)의 지방산 구성 및 항산화 작용에 미치는 영향)

  • Kim, Hak-Yoon
    • Korean Journal of Weed Science
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    • v.31 no.2
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    • pp.152-159
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    • 2011
  • The effects of simulated acid rain (SAR) on fatty acid composition and biochemical defense responses of plant was investigated. Garden balsam (Impatiens balsamina L.) was exposed to four pH levels (5.6, 4.0, 3.0, 2.0) of SAR and placed in the growth chambers for 2 weeks. SAR drastically inhibited chlorophyll content of garden balsam. The level of $H_2O_2$ was significantly increased by SAR. As pH levels decreased from 5.6 to 2.0, the ratio of unsaturated to saturated fatty acids of garden balsam was increased. Changes of three major polyamines (putrescine, spermidine and spermine) of garden balsam leaves were observed. All of the polyamine contents were increased with SAR. Catalase activities of the plant affected by SAR were increased as the pH decreased. The results indicate that the application of SAR generates oxidative stresses from the garden balsam and retards the plant growth significantly. A biochemical protect mechanism might be activated to neutralize the oxidative stresses generated through SAR.

Preparation and Electrical Conductivity of CuO-Bi2O3-V2O5 Glass for Solid State Batteries

  • Jeong, Dong-Jin;Park, Hee-Chan;Lee, Heun-Soo;Park, Chan-Young
    • The Korean Journal of Ceramics
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    • v.5 no.2
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    • pp.183-188
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    • 1999
  • The crystallization behavior and electrical conductivity of the $CuO-Bi_2O_3-V_2O_5$ glasses with various CuO content were investigated. The glass formation regin was 0~20 mol% Bi2O3, 5~55 mol% CuO, and 30~90 mol% $V_2O_5$ with Tg=$275^{\circ}C$~$290^{\circ}C$. Among glasses with various compositions, the 31CuO-$14Bi_2O_3-55V_2O_5$ (mol%) glass heat-treated at $358^{\circ}C$ for 8 h showed the highest conductivity of ~ at room temperature. The heat-treated glasses increased in electrical conductivity by the order of 104 compared to non heat-treated glass. The linear relationship between 1n($\sigma$T)and $T^{-1}$ indicated that electrical conduction in the 31CuO-$14Bi_2O_3-55V_2O_5$ (mol%) glass occurred by a small polaron hopping.

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Preparation of Aluminum Nitride from an Alkoxide and its Properties (알콕사이드로부터 AlN분말의 합성 및 분말 특성)

  • 이홍림;박세민;조덕호
    • Journal of the Korean Ceramic Society
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    • v.26 no.1
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    • pp.100-108
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    • 1989
  • Aluminum hydroxides were prepared by the alkoxide hydrolysis method using Al-isopropoxide as a starting material and NH4OH as a catalytic agent. When Al-isopropoxide was hydrolyzed in a H2O-NH3 system, only Al(OH)3 was obtained over all pH values. However, AlOOH was formed besides Al(OH)3 when Al-isopropoxide was hydrolyzed in a H2O-NH3-isopropyl alcohol system. The AlOOH/Al(OH)3 ratio was increased as the isopropyl alcohol content was increased. The hydroxides, Al(OH)3 and AlOOH, obtained in this study and the commerical products, $\alpha$-Al2O3 and AlOOH were subjected to the carbothermal reduction and nitridation reaction to product AlN powder, using carbon black as a reducing agent under N2 atmosphere at various temperatures. AlN was synthesized from the obtained Al(OH)3 and the commercial AlOOH at 145$0^{\circ}C$, however, synthesized from the obtained AlOOH and the commercial alpha-alumina at 135$0^{\circ}C$. The temperature difference is assumed to be attributed to the reactivity of those powders. AlN powder prepared from the Al-isopropoxide was observed to have the narrower particle size distribution than that prepared from the commercial $\alpha$-Al2O3 or AlOOH.

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