• Title/Summary/Keyword: $H_{2}O_2$

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Characteristics of Tropical Cyclones over the Western North Pacific in 2008 (2008년 태풍 특징)

  • Cha, Eun-Jeong;Hwang, Ho-Seong;Yang, Kyung-Jo;Won, Seong-Hee;Ko, Seong-Won;Kim, Dong-Ho;Kwon, H. Joe
    • Atmosphere
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    • v.19 no.2
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    • pp.183-198
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    • 2009
  • The purpose of this study is to summarize the tropical cyclone (TC) activity of 2008 over the western North Pacific including the verification of the official track and intensity forecast errors of these TCs. The TC activity - frequency, Normalized Typhoon Activity (NTA), and life span - was lower than 58-year (1951-2008) average. 22 tropical cyclones of tropical storm (TS) intensity or higher formed in the western North Pacific and the South China Sea in 2008. The total number is less than 58-year average frequency of 26.4. Out of 22 tropical cyclones, 11 TCs reached typhoon (TY) intensity, while the rest 11 TCs only reached severe tropical storm (STS) and tropical storm (TS) intensity - six STS and five TS storms. One typhoon KALMAEGI (0807) among them affected the Korea peninsula. However, no significant impact - casualty or property damage - was reported. On average of 22 TCs in 2008, the Korea Meteorological Administration (KMA) official track forecast error for 48 hours was 229 km. There was a big challenge for individual cyclones such as 0806 FENGSHEN and 0817 HIGOS presenting significant forecast error, with both intricate tracks and irregular moving speed. The tropical cyclone season in 2008 began in April with the formation of NEOGURI (0801). In May, four TCs formed in the western North Pacific in response to enhanced convective activity. On the other hand, the TC activity was very weak from June to August. It is found that the unusual anti-cyclonic circulation in the lower level and weak convection near the Philippines are dominant during summertime. The convection and atmospheric circulation in the western North Pacific contributed unfavorable condition for TC activity in the 2008 summertime. The 2008 TC activity has continued the below normal state since mid 1990s which is apparent the decadal variability in TC activity.

Effects on Chemical Compositions and Digestibilities of the Bulking Agents as a Moisture Control and fermentation Methods of food Waste (음식찌꺼기의 발효사료화시 수분조절제와 발효방법이 화학적 조성분 및 소화율에 미치는 영향)

  • Bae, Dong-Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.4
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    • pp.100-110
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    • 2000
  • Studies were conducted to know effects of the bulking agents (saw dusts, mushroom waste, wheat bran coconut meal, rice hulls) adding o moisture control, fermentation methods (aerobic and anaerobic) and periods (1 to 20 days) of food waste fermentation for animal feeds on chemical compositions and in vitro DDM (digestibility of dry matter). Experiment designs were focussed basically to obtain extension service data. The NDF (neutral detergent fiber) composition in the oak and pine saw dust were 93.5% and 95.4% (DM basis) in respectively. Thus, the fermented food waste feeds using saw dust (50%) increased NDF(12%), and decreased in vitro DDM(48%) compared to those of raw materials before aerobic fermentation. The oak saw dust showed higher DDM compared to pine. Mushroom wastes which is a residues of mushroom culture mixed originally willow saw dust (80%) and wheat bran (20%) showed quite higher feed value compared to both saw dusts. It was found that an in vitro DDM and NDF composition in fermented feeds appeared highly dependent or the NDF composition in bulking agents. With an increase wheat bran ratio substitute mushroom waste showed linearly decreased NDF, and increased in vitro DDM in the fermented food waste feeds. The fermented feeds added bottling agents composed higher NDF resulted in higher NDF and lower in vitro DDM with prolonged fermentation time. The feeds from anaerobic fermentation appeared lower NDF and higher in vitro DDM compared to those of aerobic fermentation.

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Experimental Study on Compression/Absorption High-Temperature Hybrid Heat Pump with Natural Refrigerant Mixture (천연혼합냉매를 이용한 압축/흡수식 고온히트펌프의 실험적 연구)

  • Kim, Ji-Young;Park, Seong-Ryong;Baik, Young-Jin;Chang, Ki-Chang;Ra, Ho-Sang;Kim, Min-Sung;Kim, Yong-Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.12
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    • pp.1367-1373
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    • 2011
  • This research concerns the development of a compression/absorption high-temperature hybrid heat pump that uses a natural refrigerant mixture. Heat pumps based on the compression/absorption cycle offer various advantages over conventional heat pumps based on the vapor compression cycle, such as large temperature glide, temperature lift, flexible operating range, and capacity control. In this study, a lab-scale prototype hybrid heat pump was constructed with a two-stage compressor, absorber, desorber, desuperheater, solution heat exchanger, solution pump, liquid/vapor separator, and rectifier as the main components. The hybrid heat pump system operated at 10-kW-class heating capacity producing hot water whose temperature was more than $90^{\circ}C$ when the heat source and sink temperatures were $50^{\circ}C$. Experiments with various $NH_3/H_2O$ mass fractions and compressor/pump circulation ratios were performed on the system. From the study, the system performance was optimized at a specific $NH_3$ concentration.

Oxidative Desulfurization of Marine Diesel Using WOx/SBA-15 Catalyst and Hydrogen Peroxide (WOx/SBA-15 촉매와 과산화수소를 이용한 선박용 경유의 산화 탈황 연구)

  • Oh, Hyeonwoo;Kim, Ji Man;Huh, Kwang-Sun;Woo, Hee Chul
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.567-573
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    • 2017
  • In this work, tungsten oxide ($WO_x$) supported on SBA-15 (mesoporous silica) were prepared and applied for oxidative desulfurization of sulfur compounds in marine diesel containing about 230 ppmw of sulfur concentration. Prepared catalysts were examined by two steps; at first step, oxidation reaction carried out with hydrogen peroxide as oxidant and then the oxidized sulfur compounds were extracted by acetonitrile as solvent. Catalysts were characterized by using X-ray diffraction, X-ray fluorescence, X-ray photoelectron spectroscopy and $N_2$ adsorption-desorption isotherms. Tungsten oxide exists as monoclinic crystal system on SBA-15 and over about 10 wt% of the $WO_x$ loading took the form of multi-layers on SBA-15. The 13 wt% $WO_x$/SBA-15 catalyst exhibite highest activity, achieving about 76.3% sulfur removal in the reaction conditions, such as catalyst amount of 0.1 g, reaction temperature at $90^{\circ}C$, reaction time for 3 h and O/S molar ratio of 10. One time oxidation reaction is enough oxidize the sulfur compounds in marine diesel completely. The repetition experiment of extraction process indicated that sulfur removal could reach 94.4% after 5 times.

Lipase Inhibitory Mode of Dieckol Isolated from Eisenia bicyclis Ethanol Extract (Eisenia bicyclis 에탄올 추출물로부터 분리한 Dieckol의 Lipase 저해 Mode)

  • Jung, Seul-A;Kim, Koth-Bong-Woo-Ri;Kim, Dong-Hyun;Cho, Ji-Young;Kim, Tae-Wan;Ahn, Dong-Hyun
    • Microbiology and Biotechnology Letters
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    • v.41 no.1
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    • pp.112-118
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    • 2013
  • This study was performed to investigate the possible use of Eisenia bicyclis (EB) ethanol extract to inhibit activity against lipase. In tests, the lipase inhibitory activity of EB ethanol extract was noted as being 43, 27, and 24% at concentrations of 5, 2.5, and 1 mg/ml, respectively. Isolation was carried out by liquid and liquid extraction, silica-gel column chromatography, and HPLC. The results showed that the lipase inhibitory activity of the ethyl acetate (EA) fraction from EB ethanol extract exhibited the strongest lipase inhibitory activity with an $IC_{50}$ value of 1.31 mg/ml. The EA fraction was separated using silica-gel column chromatography and we obtained 22 sub-fractions. Amongst them, the EA1 fraction showed the highest lipase inhibitory activity with an $IC_{50}$ value of 0.54 mg/ml. Eight peaks were obtained from the EA1 fraction by HPLC. Fraction 5 also showed a strong lipase inhibitory activity with an $IC_{50}$ value of 0.37 mg/ml. The fraction 5 was identified as dieckol and the inhibition pattern analyzed from Lineweaver-Burk plots revealed a non-competitive inhibitor. These results suggest that EB has potential as a natural anti-obesity agent.

THE EFFECT OF DIETARY PROTEIN AND ALUM IN LITTER ON PERFORMANCE, NH3 GAS CONCENTRATION AND LITTER COMPOSITION IN BROILER

  • 남기홍
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2001.11a
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    • pp.86-88
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    • 2001
  • An experiment was conducted to determine how broiler performance, feces and litter concentration of N can be maintained and whether NH3 gas concentration can be reduced with reducing dietary CP, adding ALUM(AL2(SO4)3.14H20) in litter and supplementing with amino acid and vitamin D in feed. The experiment was divided into a starter period(1 to 21d) and grower period(22 to 42d), each having three different CP with 90 birds per treatment of 3 replications. The CP treatments consisted of a mean CP of 23.0(control 71), 20.4 (72) and 18.0 (73) % for starter and 21.0(control 71),19.3 (72) and 17.0 (73) % for grower, respectively, but with similar amino acid levels as the control. Alum was mixed in each treatment except control treatment with 200g in kilogram litter(rice bran) weight. Results suggested that reducing CP below control in the diets fed during 3wks and 6wks slightly increased feed gain and slightly decreased feed intake and weight gain. However, there were no significant difference among treatments. Reducing CP caused NH3 gas concentration to decline by 74.8 - 80.9% when Alum was mixed in litter(P < 0.05). Litter N concentration did not show any difference(P > 0.05) among treatments. These results suggest that dietary manipulation with adding Alum in litter show for significant reducing NH3 gas concentration while maintaining acceptable Production performance from broiler.

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Herbicide Response to Cultural Environment in Flooded Direct-seeded Rice (벼 담수직파(湛水直播)에서 재배환경(栽培環境)에 따른 제초제(除草劑) 반응(反應))

  • Huh, S.M.;Kim, B.H;Im, I.B.;Kwon, O.D.
    • Korean Journal of Weed Science
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    • v.16 no.4
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    • pp.282-291
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    • 1996
  • This experiment was conducted to investigate the phytotoxicity of several herbicides for rice and weed control with herbicides application times and seeding times in flooded direct-seeded rice field. The phytotoxicity of herbieides(bensulfuron methyl+dimepiperate, bensulfuron methyl+mefenacet+dymron, bensulfuron methyl+quinclorac, pyrazosulfuron-ethyl+molinate, pyrazosulfuron-ethyl+thiobencarb, pyrazosulfuron-ethyl+cyhalofop, imazosulfuron+molinate, imazosul-furon+cyhalofop) for rice in different seeding dates was the most high at 7 days after seeding(DAS) Followed by 12 and 17 DAS. In particular, the bensulfuron methyl+mefenacet+dymron showed very high phytotoxicity to rice plants. Weed species occurred in direct-seeding field seeded on May 1 were 10 species (grasses ; 1, broad-leaves ; 6, sedges ; 3) and Echinochloa crus-galli was the most dominant weed among them. Whereas weed species occurred rice field seeded on May 22 were 7 species(grasses ; 1, broad-leaves : 3, ridges ; 3) and Echirochloa crus-galli was the most dominant weed among them. The weed control for annual weeds(Echinochloa crus-galli, Aneilema keisak, and so on) and perennial weeds(Cyperus serotinus, Scipurus juncoides) was remarkably effective at the application of 7 and 12 DAS, but it of Eleocharis kuroguwai was effective at the application of 17 DAS on two seeding times. The yields were decreased significantly at the plot affected severely by herbicides applied at 7 DAS and the plots showed low efficacy at herbicides application of 17 DAS.

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Experimental Study on Fabrication of AZO Transparent Electrode for Organic Solar Cell Using Selective Low-Temperature Atomic Layer Deposition (저온 선택적 원자층 증착공정을 이용한 유기태양전지용 AZO 투명전극 제조에 관한 실험적 연구)

  • Kim, Ki-Cheol;Song, Gen-Soo;Kim, Hyung-Tae;Yoo, Kyung-Hoon;Kang, Jeong-Jin;Hwang, Jun-Young;Lee, Sang-Ho;Kang, Kyung-Tae;Kang, Heui-Seok;Cho, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.6
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    • pp.577-582
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    • 2013
  • AZO (aluminum-doped zinc oxide) is one of the best candidate materials to replace ITO (indium tin oxide) for TCOs (transparent conductive oxides) used in flat panel displays, organic light-emitting diodes (OLEDs), and organic solar cells (OSCs). In the present study, to apply an AZO thin film to the transparent electrode of an organic solar cell, a low-temperature selective atomic layer deposition (ALD) process was adopted to deposit an AZO thin film on a flexible poly-ethylene-naphthalate (PEN) substrate. The reactive gases for the ALD process were di-ethyl-zinc (DEZ) and tri-methyl-aluminum (TMA) as precursors and H2O as an oxidant. The structural, electrical, and optical characteristics of the AZO thin film were evaluated. From the measured results of the electrical and optical characteristics of the AZO thin films deposited on the PEN substrates by ALD, it was shown that the AZO thin film appeared to be comparable to a commercially used ITO thin film, which confirmed the feasibility of AZO as a TCO for flexible organic solar cells in the near future.

Optical Diagnostics of Nanopowder Processed in Liquid Plasmas

  • Bratescu, M.A.;Saito, N.;Takai, O.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.17-18
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    • 2011
  • Plasma in liquid phase has attracted great attention in the last few years by the wide domain of applications in material processing, decomposition of organic and inorganic chemical compounds and sterilization of water. The plasma in liquid is characterized by three main regions which interact each - other during the plasma operation: the liquid phase, which supply the plasma gas phase with various chemical compounds and ions, the plasma in the gas phase at atmospheric pressure and the interface between these two regions. The most complex region, but extremely interesting from the fundamental, chemical and physical processes which occur here, is the boundary between the liquid phase and the plasma gas phase. In our laboratory, plasma in liquid which behaves as a glow discharge type, is generated by using a bipolar pulsed power supply, with variable pulse width, in the range of 0.5~10 ${\mu}s$ and 10 to 30 kHz repetition rate. Plasma in water and other different solutions was characterized by electrical and optical measurements. Strong emissions of OH and H radicals dominate the optical spectra. Generally water with 500 ${\mu}S/cm$ conductivity has a breakdown voltage around 2 kV, depending on the pulse width and the repetition rate of the power supply. The characteristics of the plasma initiated in ultrapure water between pairs of different materials used for electrodes (W and Ta) were investigated by the time-resolved optical emission and the broad-band absorption spectroscopy. The deexcitation processes of the reactive species formed in the water plasma depend on the electrode material, but have been independent on the polarity of the applied voltage pulses. Recently, Coherent anti-Stokes Raman Spectroscopy method was employed to investigate the chemistry in the liquid phase and at the interface between the gas and the liquid phases of the solution plasma system. The use of the solution plasma allows rapid fabrication of the metal nanoparticles without being necessary the addition of different reducing agents, because plasma in the liquid phase provides a reaction field with a highly excited energy radicals. We successfully synthesized gold nanoparticles using a glow discharge in aqueous solution. Nanoparticles with an average size of less than 10 nm were obtained using chlorauric acid solutions as the metal source. Carbon/Pt hybrid nanostructures have been obtained by treating carbon balls, synthesized in a CVD chamber, with hexachloro- platinum acid in a solution plasma system. The solution plasma was successfully used to remove the template remained after the mesoporous silica synthesis. Surface functionalization of the carbon structures and the silica surface with different chemical groups and nanoparticles, was also performed by processing these materials in the liquid plasma.

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Seasonal Soil and Foliar Nutrient Concentrations, and Fruit Quality in a Pesticide-Free Pear Orchard as Affected by Seeding Timing and Method of Cover Crops (녹비작물의 파종시기와 방법이 무농약 배과원의 시기별 토양화학성과 엽내 무기성분, 과실품질에 미치는 영향)

  • Lim, Kyeong-Ho;Choi, Jin-Ho;Kim, Wol-Soo;Kim, Hyun-Ji;Song, Jang-Hoon;Cho, Young-Sik;Yim, Sun-Hee;Jung, Seok-Kyu;Choi, Hyun-Sug
    • Korean Journal of Environmental Agriculture
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    • v.33 no.1
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    • pp.9-16
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    • 2014
  • BACKGROUND: This study was conducted to investigate the effects of seeding timing and method of rye and/or hairy vetch on seasonal soil and foliar nutrient concentrations as well as fruit quality in a pesticide-free pear orchard. METHODS AND RESULTS: The treatments included as followed: single seeding of rye in September (Sep-Mono), November (Nov-Mono), and January (Jan-Mono), or mix seeding of rye+hairy vetch in November (Nov-Mix) and January (Jan-Mix), or sod culture as a control. Cover crops or vegetation was mown and mulched on the soil surface in April and May for two years. Nov-Mix treatment produced the highest dry matter weight of $12,070kg\;ha^{-1}$, with the lowest dry matter weight for sod culture ($6,520kg\;ha^{-1}$), following Jan-Mix ($7,030kg\;ha^{-1}$). Nov-Mix treatments increased potential amount of N, P, and K from the raw materials of the cover crops as well as improved soil physical properties. Nov-Mix treatments overall elevated soil pH, EC, organic matter, and $P_2O_5$ in May compared to other cover crop treatments or sod culture. The difference of the seasonal nutrient concentrations in leaves or fruit qualities were not consistently occurred amongst treatments. CONCLUSION: Nov-Mix treatments showed playing role in a substitute of a chemical fertilizer. Delayed seeding of cover crops such as Jan-Mix did not increase the potential dry matter production due to the short growing period, and the seeding time would affect the dry matter production of cover crops.