• Title/Summary/Keyword: $FePO_4$

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The Development of Estimation Model for Iron Compound Originated from Anaerobic Microbial Corrosion (혐기성 미생물부식에 의해 생성되는 철화합물 추정식 개발)

  • Jeon, Seok-Jun
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.379-386
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    • 2002
  • In this study, estimation model for iron compound originated from upflow, anaerobic fixed bed reactor, which treats sewage domestic wastewater, was developed. The estimation model was formulated by a mathematical expression which was based on the mass balance. Below the HRT of 60 minute, sulfide concentration combining with iron $FeS_2$ is the highest because the maximum sulfate consumption rate $V_{maxS}$ and half-saturation constant of sulfate $K_{mS}$ exert an important effect on the estimation model as temperature was increased. But increment of $FeS_2$ concentration is weakened above the HRT of 60 minutes and represent the lowest value at the HRT of 108 minutes. It implies that liquid phase distribution ratio of sulfide ${\alpha}r$ becomes lower as temperature was increased. While phosphorus concentration combining with iron $Fe_3(PO_4)_3$ is increased as HRT and temperature are increased, which is affected by phosphorus removal rate constant $k_p$. As the result of estimating the iron concentrations of corrosion by the model, the concentration of iron corrosion is higher than any other at the HRT of 108 minute and $20^{\circ}C$. The predicted values were compared with measured ones at different HRT(13.5, 27, 54, 108 min) and temperature(20, 25, $30^{\circ}C$). The experimental data could be fitted with the simulated curves. Therefore, the mathematical expression could be applicable to design full-scale wastewater treatment plants.

Optimization of Medium Composition for Lipopeptide Production from Bacillus subtilis N7 using Response Surface Methodology

  • Luo, Yi;Zhang, Guoyi;Zhu, Zhen;Wang, Xiaohui;Ran, Wei;Shen, Qirong
    • Microbiology and Biotechnology Letters
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    • v.41 no.1
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    • pp.52-59
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    • 2013
  • The nutritional requirements for the maximum production of lipopeptides by Bacillus subtilis N7 (B. subtilis N7) were investigated and optimized using response surface methodology (RSM) under shake flask fermentation. A one-factor-at-a-time experimental setup was used to screen carbon and nitrogen sources. A Plackett-Burman design (PBD) was employed to screen the most critical variables for lipopeptides production amongst ten nutritional elements. The central composite experimental design (CCD) was finally adopted to elucidate the composition of the fermentation medium. Statistical analyses (analysis of variance, ANOVA) of the results showed that KCl, $MnSO_4$ and $FeSO_4{\cdot}6H_2O$ were important components and that their interactions were strong. Lipopeptide production was predicted to reach 709.87 mg/L after a 60 h incubation using an optimum fermentation medium composed of glucose 7.5 g/L, peanut oil 1.25 g/L, $MgSO_4$ 0.37 g/L, $KH_2PO_4$ 0.75 g/L, monosodium glutamate 6.75 g/L, yeast extract and $NH_4Cl$ (5:3 w/w) 10 g/L, KCl 0.16 g/L, $FeSO_4{\cdot}6H_2O$ 0.24 mg/L, $MnSO_4$ 0.76 mg/L, and an initial pH of 7.0. Lipopeptide production ($706.57{\pm}3.70$ mg/L) in the optimized medium confirmed the validity of the predicted model.

Temperature-Dependent Electrochemical Characteristic Analysis for 10kW Li-Polymer Energy Storage System (ESS) (10kW급 에너지 저장장치(ESS)의 전기화학적 온도특성 분석)

  • Kim, J.H.;Choi, H.J.;Song, J.W.;Kim, S.J.;Park, J.P.
    • Proceedings of the KIPE Conference
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    • 2012.11a
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    • pp.61-62
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    • 2012
  • 본 논문에서는 10kW급 리튬계열 에너지 저장장치 (ESS;Energy storage system)의 전기화학적 온도특성을 분석하였다. 70개 $LiFePO_4$ 단위 셀의 직렬결합(70S1P)으로 이루어진 ESS의 온도특성 분석을 위해 여름(7월)과 겨울(1월)일때의 ESS Tray/Rack/Cell 전압(표준편차) 및 온도데이터(최대값/최소값)의 통계처리를 실시하였다. 실험결과를 통해, 주변 외기온도에 영향을 최소화한 안정적인 ESS의 최적구축을 위한 가이드 라인을 제시할 수 있다.

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Phosphate Removal from Wastewater by Surface-Modified Pinus rigida Powder (표면개질된 Pinus rigida 분말에 의한 하수의 인산염 제거)

  • Jeong, Myoung-Sun;Kim, Yeong-Kwan
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.2
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    • pp.241-248
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    • 2011
  • This research was performed to evaluate the efficacy of phosphate removal from wastewater by surface-modified wood powder and to clarify the removal mechanisms. In this work, Pinus rigida which is abundant in Korea and has little economic value was used in preparation of the wood powder as a sorbent material. The experiments were carried out in 2 phases, isothermal adsorption test and column test. The results of adsorption test fitted well both the Langmuir and Freundlich isothermal equations. Adsorption capacity was highest with the bark powder followed by the mixed powder(50% bark powder and 50% woody powder) and woody powder. Phosphate removal efficiency was as high as 98% at initial phosphate concentration of 50mg/L. Specific surface area of the powder increased following the experiment and phosphate removal was speculated to occur through adsorption mechanism. Energy dispersive X-ray analysis(EDXA) revealed that the phosphate adsorbed onto the surface of the powder was in the form of strengite($FePO_{4}$).

SOC Estimation Algorithm based on the Coulomb Counting Method and Extended Kalman Filter for a LiFePO4 Battery (확장 칼만 필터를 이용한 전류 적산법 기반의 리튬 폴리머 배터리 SOC 추정)

  • Chun, C.Y.;Cho, B.H.;Kim, J.H.
    • Proceedings of the KIPE Conference
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    • 2012.07a
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    • pp.271-272
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    • 2012
  • 전류 적산법(Coulomb counting, ampere counting)을 이용한 배터리 SOC(State-of-Charge) 추정 방법은 상용화된 IC를 사용할 수 있기에 구현이 간단하고 SOC 정의를 통해 배터리 사용 가능한 시간을 쉽게 예측할 수도 있다. 하지만 초기 SOC 오류와 누적되는 전류 정보의 오차로 인해 추정이 실패하는 단점이 존재하기 때문에 이를 해결해주는 알고리즘이 필요하다. 본 논문에서는 전류 적산법 기반의 배터리 SOC 추정 회로에 확장 칼만 필터(EKF, Extended Kalman Filter)를 접목하여 전류 적산법을 이용하였을 때 나타날 수 있는 오차 누적을 줄이는 알고리즘을 제안한다. 또한 실험을 통해 제안된 배터리 SOC 추정 회로의 성능을 확인해본다.

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A novel OCV Hysteresis Modeling for SOC estimation of Lithium Iron Phosphate battery (리튬인산철 배터리를 위한 새로운 히스테리시스 모델링)

  • Nguyen, Thanh Tung;Khan, Abdul Basit;Choi, Woojin
    • Proceedings of the KIPE Conference
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    • 2016.11a
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    • pp.75-76
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    • 2016
  • The relationship of widely used Open circuit Voltage (OCV) versus State of Charge (SOC) is critical for any reliable SOC estimation technique. However, the hysteresis existing in all type of battery which has been come to the market leads this relationship to a complicated one, especially in Lithium Iron Phosphate (LiFePO4) battery. An accurate model for hysteresis phenomenon is essential for a reliable SOC identification. This paper aims to investigate and propose a method for hysteresis modeling. The SOC estimation is done by using Extended Kalman Filter (EKF), the parameter of the battery is modeled by Auto Regressive Exogenous (ARX) and estimated by using Recursive Least Square (RLS) filter to tract each element of the parameter of the model.

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X-Ray Absorption Spectroscopy: A Complementary Tool for Structural and Electronic Characterization of Solids

  • Jean Etourneau
    • Bulletin of the Korean Chemical Society
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    • v.19 no.1
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    • pp.5-21
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    • 1998
  • The purpose of this paper is to show that X-ray absorption spectroscopy (XANES and EXAFS) is a powerful technique for characterizing both crystalline and amorphous solids from structural (local order) and electronic point of view. The principle of this technique is briefly described by showing the main factors which must be considered for recording and fitting the experimental results. Some non-trivial examples have been selected for demonstrating that XAS spectroscopy is the only technique for bringing a definitive answer as for example: the determination of the local distortion of the $NiO_6$ octahedra in the $Li_{1-z}Ni_{1+z}O_2$ layered oxides and the evidence of the presence of copper pairs in the NASICON-type phosphate $CuZr_2 (PO_4)_3$. Are also reported some significant examples for which XAS spectroscopy is decisive with other characterization methods as (i) Raman spectroscopy for glasses (ii) Mossbauer spectroscopy for $LiNi_{1+z-t}Fe_To_2$ oxides (iii) magnetic measurements for Ce-based intermetallic compounds.

Effects of Organic Nutrients on Chitinase Production in Minimal Media (배양액중의 유기영양물이 Chitinase 생산에 미치는 영향)

  • Jang, Ji-Yun;Kim, In-Cheol;Jang, Hae-Chun
    • Microbiology and Biotechnology Letters
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    • v.32 no.4
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    • pp.366-370
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    • 2004
  • Four chitinase producing bacteria, Arthrobacter nicotinae CH4, Arthrobacter nicotinae CHI3, Arthrobacter sp. CH5 and Micrococcus sp. CH3, were isolated from small crabs and shrimps. We investigated the optimum medium condition for the production of enzyme and high cell mass. The preferable medium composition was as follows: colchitin 0.1 %(w/v), glycerol 0.25%(w/v) and yeast extract 0.05%(w/v) in minimal midium ($K_{2}HPO_{4}$ 0.7 g/l, $KH_{2}PO_{4}$ 0.3 g/l, $MgSO_{4}{\cdot}5H_{2}O$ 0.5 g/l, $FeSO_{4}}{\cdot}7H_{2}O$ 0.01 g/l, $ZnSO_{4}$ 0.001 g/l, $MnCI_2$ 0.001 g/l, pH 7.0). This cell culture medium could be used directly as sample for measuring chitinase activity. Because it hardly conreducing sugar such as glucose (blank value=0), the detected reducing sugar can be considered as a chitinase reaction product. The results can be used for easy preparation method for determination of enzyme activity and analysis of enzyme-substrate reaction in step of screening of chitinase producing bacteria.

Analysis of Environmental Factors Associated with Cyanobacteria Dominance in Baekje Weir and Juksan Weir (백제보와 죽산보에서 남조류 우점 환경요인 분석)

  • Kim, Sung-Jin;Chung, Se-Woong;Park, Hyung-Seok;Cho, Young-Cheol;Lee, Hee-Suk;Park, Yeon-Jeong
    • Journal of Korean Society on Water Environment
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    • v.35 no.3
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    • pp.257-270
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    • 2019
  • Followingthe Four Rivers Project, cyanobacterial blooms have been frequently observed in the upstream of the installed weirs. The aim of this study was to characterize the major environmental factors that are associated with the cyanobacteria dominance in Baekje Weir (Geum River) and Juksan Weir (Youngsan River) based on intensive experiments and systematic data mining methods. The factors related to the cyanobacteria dominance include7-days cumulative rainfall (APRCP7), 7-days averaged flow (Q7day), water temperature (Temp), stratification strength (${\Delta}T$), electronic conductivity (EC), DO, pH, $NO_3-N$, $NH_3-N$, TN, TP, $PO_4-P$, Chl-a, Fe, BOD, COD, TOC, and $SiO_2$. The most highly correlatedfactors to the dominant cyanobacteria were found to be EC, Temp, Q7day, $PO_4-P$ in theBaekje Weir. On the other hand, those dominant in the Juksan Weir were ${\Delta}T$, TOC, Temp, EC and TN. The EC showed a strong correlation with cyanobacteria dominance in both weirs because a high EC represents a persisted low flow condition. The cyanobacteria dominance was as high as 56 % when the EC was equal or greater than $418{\mu}S/cm$ in Baekje Weir. It was as high as 63% when the ${\Delta}T{\geq}2.1^{\circ}C$ in the Juksan Weir. However, nutrients showed a minor correlation with cyanobacteria dominance in both weirs. The results suggest that the cyanobacteria dominate in astate where the water flow rate is low, water temperature is high and thermal stratification is strengthened. Therefore, the improvement of flow regimes is the most important to prevent persistent thermal stratification and formation of cyanobacteria bloom in theBaekje and JuksanWeirs.

New synthetic medium for growth of mycelium of Pleurotus species (느타리속(Pleurotus species) 균의 균사 배양을 위한 새로운 합성 배지)

  • Park, Won-Mok;Kim, Gyu-Hyun;Hyeon, Jae-Wook
    • The Korean Journal of Mycology
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    • v.23 no.3 s.74
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    • pp.275-283
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    • 1995
  • The nutritional requirements of mycelial growth for Pleurotus spp. were studied. As the carbon sources, soluble starch and dextrin, nitrogen sources, arginine and ammonium tartrate, and calcium sources, $CaCO_3$ enhanced mycelial growth. Optimum C/N ratio was 100 : 1. On the base of results from the experiment on nutritional requirements, the following receipe is suggested for growth of Pleurotus spp.; starch 15 g, arginine 3.484 g, ammonium tartrate 3.06 g, $CaCO_3$ 0.314 g, $KH_2PO_4$ 8.138 g, $K_2HPO_4$ 1.584 g, $MgSO_4{\cdot}7H_2O$ 1.5 g for P. sajor-caju and 2.5 g for P. ostreatus. $FeSO_4{\cdot}7H_2O$ 0.02 g, $ZnSO_4{\cdot}7H_2O$ 0.03 g, $MnSO_4{\cdot}7H_2O$ 0.02 g, optimum pH 6.0. This new synthetic medium is tentatively designated as Park's medium.

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