• 제목/요약/키워드: $E_h-pH$diagram

검색결과 17건 처리시간 0.019초

고온-고압하에서 티탄철석에 대한 상면이 연구 (Phase Transition Study on Ilmenite under High Pressure and Temperature)

  • Kim, Young-Ho
    • 한국광물학회지
    • /
    • 제15권3호
    • /
    • pp.161-169
    • /
    • 2002
  • 고온-고압 상태에서 티탄철석 ($FeTiO_3$)의 상변이에 대한 연구가 있었으나, 그 결과는 서로 일치하지 않고 있다. 특히, 티탄철석상과 페롭스카이트상의 상변이 경계는 담금방법에 의해 결정된 것으로 신뢰도에 의문이 제기되고 있다. 이러한 문제를 해결하기 위해, 고온-고압 현장상태에서 라지 볼륨 기기와 방사광을 이용하여 19 GPa와 $700^{\circ}C$의 범위에서 X선 회절실험을 시행하였다. 이러한 실험결과, 페롭스카이트상은 상온에서 16 CPa 이상의 압력에서 안정하며, 15 CPa 근처에서 $LiNbO_3$상으로 변이한다. 또한 이 두 고온-고압상은 $500^{\circ}C$에서는 순간적인 상변이를 하고 있다. $LiNbO_3$상은 각각 13 CPa 및 300'E와 10.8 GPa 및 400'E에서 티탄철석상으로 상변이 한다. 따라서 본 실험결과는 $LiNbO_3$상은 고온-고압하에서 안정 영역을 확보하고 있으며, 페롭스카이트-티탄철석상경계는 이전에 발표된 결과와는 매우 다르다는 것을 지시해주고 있다.

Evolutionary properties of red supergiants with MESA

  • Chun, Sang-Hyun;Jung, Moo-Keon;Kim, Dong uk;Kim, Jihoon;Yoon, Sung-Chul
    • 천문학회보
    • /
    • 제42권1호
    • /
    • pp.42.1-42.1
    • /
    • 2017
  • We investigate the evolutionary properties of red supergiant stars (RSGs), using stellar evolution model of Modules for Experiments in Stellar Astrophysics (MESA). In this study, we calculate models with mass range of 9-39M_sun and several different convection parameters (e.g. mixing length, overshooting, and semiconvection) at SMC, LMC, Milky Way, and M31 metallicities. We compare the calculated evolutionary tracks with observed RSGs in SMC, LMC, Milky Way and M31, and discuss appropriate input physical parameters in model calculation. We find that a larger mixing length parameter is necessary for M31 metallicity to fit the positions of RSGs in H-R diagram, compared to lower metallicity environments. Theoretically predicted numbers of yellow supergiant stars (YSGs) are also compared with the observed population. We find that Ledoux models with semiconvection can better explain the number of YSGs. Finally, we investigate the final radius, final star mass, and final hydrogen envelope mass of RSGs and discussed the their properties as type II-P supernova progenitors.

  • PDF

A study of glass and carbon fibers in FRAC utilizing machine learning approach

  • Ankita Upadhya;M. S. Thakur;Nitisha Sharma;Fadi H. Almohammed;Parveen Sihag
    • Advances in materials Research
    • /
    • 제13권1호
    • /
    • pp.63-86
    • /
    • 2024
  • Asphalt concrete (AC), is a mixture of bitumen and aggregates, which is very sensitive in the design of flexible pavement. In this study, the Marshall stability of the glass and carbon fiber bituminous concrete was predicted by using Artificial Neural Network (ANN), Support Vector Machine (SVM), Random Forest (RF), and M5P Tree machine learning algorithms. To predict the Marshall stability, nine inputs parameters i.e., Bitumen, Glass and Carbon fibers mixed in 100:0, 75:25, 50:50, 25:75, 0:100 percentage (designated as 100GF:0CF, 75GF:25CF, 50GF:50 CF, 25GF:75CF, 0GF:100CF), Bitumen grade (VG), Fiber length (FL), and Fiber diameter (FD) were utilized from the experimental and literary data. Seven statistical indices i.e., coefficient of correlation (CC), mean absolute error (MAE), root mean squared error (RMSE), relative absolute error (RAE), root relative squared error (RRSE), Scattering index (SI), and BIAS were applied to assess the effectiveness of the developed models. According to the performance evaluation results, Artificial neural network (ANN) was outperforming among other models with CC values as 0.9147 and 0.8648, MAE values as 1.3757 and 1.978, RMSE values as 1.843 and 2.6951, RAE values as 39.88 and 49.31, RRSE values as 40.62 and 50.50, SI values as 0.1379 and 0.2027 and BIAS value as -0.1 290 and -0.2357 in training and testing stage respectively. The Taylor diagram (testing stage) also confirmed that the ANN-based model outperforms the other models. Results of sensitivity analysis showed that the fiber length is the most influential in all nine input parameters whereas the fiber combination of 25GF:75CF was the most effective among all the fiber mixes in Marshall stability.

Gene Expression Analysis of So Called Asian Dust Extracts in Human Acute Myeloid Leukemia Cells

  • Choi, You-Jin;Yin, Hu-Quan;Park, Eun-Jung;Park, Kwang-Sik;Kim, Dae-Seon;Lee, Byung-Hoon
    • Toxicological Research
    • /
    • 제26권1호
    • /
    • pp.21-28
    • /
    • 2010
  • As the frequency and the intensity of so called Asian dust (AD) events have increased, public concerns about the adverse health effects has spiked sharply over the last two decades. Despite the recent reports on the correlation between AD events and the risk for cardiovascular and respiratory disease, the nature of the toxicity and the degree of the risk are yet largely unknown. In the present study, we investigated the effects of the dichloromethane extract of AD (AD-X) and that of urban dust (NAD-X) collected during a non-AD period on gene expression in HL-60 cells using Illumina Sentrix HumanRef-8 Expression BeadChips. Global changes in gene expression were analyzed after 24 h of incubation with 50 or 100 ${\mu}g$/ml AD-X and NAD-X. By one-way analysis of variance (p < 0.05) and Benjamini-Hochberg multiple testing correction for false discovery rate of the results, 573 and 297 genes were identified as AD-X- and NAD-X-responsive, respectively. The genes were classified into three groups by Venn diagram analysis of their expression profile, i.e., 290 AD-X-specific, 14 NAD-X-specific, and 283 overlapping genes. Quantitative realtime PCR confirmed the changes in the expression levels of the selected genes. The expression patterns of five genes, namely SORL1, RABEPK, DDIT4, AZU1, and NUDT1 differed significantly between the two groups. Following rigorous validation process, these genes may provide information in developing biomarker for AD exposure.

한국주요빙계의 소유역에 대한 순간단위권 유도에 관한 연구 (I) (Studies on the Derivation of the Instantaneous Unit Hydrograph for Small Watersheds of Main River Systems in Korea)

  • 이순혁
    • 한국농공학회지
    • /
    • 제19권1호
    • /
    • pp.4296-4311
    • /
    • 1977
  • This study was conducted to derive an Instantaneous Unit Hydrograph for the accurate and reliable unitgraph which can be used to the estimation and control of flood for the development of agricultural water resources and rational design of hydraulic structures. Eight small watersheds were selected as studying basins from Han, Geum, Nakdong, Yeongsan and Inchon River systems which may be considered as a main river systems in Korea. The area of small watersheds are within the range of 85 to 470$\textrm{km}^2$. It is to derive an accurate Instantaneous Unit Hydrograph under the condition of having a short duration of heavy rain and uniform rainfall intensity with the basic and reliable data of rainfall records, pluviographs, records of river stages and of the main river systems mentioned above. Investigation was carried out for the relations between measurable unitgraph and watershed characteristics such as watershed area, A, river length L, and centroid distance of the watershed area, Lca. Especially, this study laid emphasis on the derivation and application of Instantaneous Unit Hydrograph (IUH) by applying Nash's conceptual model and by using an electronic computer. I U H by Nash's conceptual model and I U H by flood routing which can be applied to the ungaged small watersheds were derived and compared with each other to the observed unitgraph. 1 U H for each small watersheds can be solved by using an electronic computer. The results summarized for these studies are as follows; 1. Distribution of uniform rainfall intensity appears in the analysis for the temporal rainfall pattern of selected heavy rainfall event. 2. Mean value of recession constants, Kl, is 0.931 in all watersheds observed. 3. Time to peak discharge, Tp, occurs at the position of 0.02 Tb, base length of hlrdrograph with an indication of lower value than that in larger watersheds. 4. Peak discharge, Qp, in relation to the watershed area, A, and effective rainfall, R, is found to be {{{{ { Q}_{ p} = { 0.895} over { { A}^{0.145 } } }}}} AR having high significance of correlation coefficient, 0.927, between peak discharge, Qp, and effective rainfall, R. Design chart for the peak discharge (refer to Fig. 15) with watershed area and effective rainfall was established by the author. 5. The mean slopes of main streams within the range of 1.46 meters per kilometer to 13.6 meter per kilometer. These indicate higher slopes in the small watersheds than those in larger watersheds. Lengths of main streams are within the range of 9.4 kilometer to 41.75 kilometer, which can be regarded as a short distance. It is remarkable thing that the time of flood concentration was more rapid in the small watersheds than that in the other larger watersheds. 6. Length of main stream, L, in relation to the watershed area, A, is found to be L=2.044A0.48 having a high significance of correlation coefficient, 0.968. 7. Watershed lag, Lg, in hrs in relation to the watershed area, A, and length of main stream, L, was derived as Lg=3.228 A0.904 L-1.293 with a high significance. On the other hand, It was found that watershed lag, Lg, could also be expressed as {{{{Lg=0.247 { ( { LLca} over { SQRT { S} } )}^{ 0.604} }}}} in connection with the product of main stream length and the centroid length of the basin of the watershed area, LLca which could be expressed as a measure of the shape and the size of the watershed with the slopes except watershed area, A. But the latter showed a lower correlation than that of the former in the significance test. Therefore, it can be concluded that watershed lag, Lg, is more closely related with the such watersheds characteristics as watershed area and length of main stream in the small watersheds. Empirical formula for the peak discharge per unit area, qp, ㎥/sec/$\textrm{km}^2$, was derived as qp=10-0.389-0.0424Lg with a high significance, r=0.91. This indicates that the peak discharge per unit area of the unitgraph is in inverse proportion to the watershed lag time. 8. The base length of the unitgraph, Tb, in connection with the watershed lag, Lg, was extra.essed as {{{{ { T}_{ b} =1.14+0.564( { Lg} over {24 } )}}}} which has defined with a high significance. 9. For the derivation of IUH by applying linear conceptual model, the storage constant, K, with the length of main stream, L, and slopes, S, was adopted as {{{{K=0.1197( {L } over { SQRT {S } } )}}}} with a highly significant correlation coefficient, 0.90. Gamma function argument, N, derived with such watershed characteristics as watershed area, A, river length, L, centroid distance of the basin of the watershed area, Lca, and slopes, S, was found to be N=49.2 A1.481L-2.202 Lca-1.297 S-0.112 with a high significance having the F value, 4.83, through analysis of variance. 10. According to the linear conceptual model, Formular established in relation to the time distribution, Peak discharge and time to peak discharge for instantaneous Unit Hydrograph when unit effective rainfall of unitgraph and dimension of watershed area are applied as 10mm, and $\textrm{km}^2$ respectively are as follows; Time distribution of IUH {{{{u(0, t)= { 2.78A} over {K GAMMA (N) } { e}^{-t/k } { (t.K)}^{N-1 } }}}} (㎥/sec) Peak discharge of IUH {{{{ {u(0, t) }_{max } = { 2.78A} over {K GAMMA (N) } { e}^{-(N-1) } { (N-1)}^{N-1 } }}}} (㎥/sec) Time to peak discharge of IUH tp=(N-1)K (hrs) 11. Through mathematical analysis in the recession curve of Hydrograph, It was confirmed that empirical formula of Gamma function argument, N, had connection with recession constant, Kl, peak discharge, QP, and time to peak discharge, tp, as {{{{{ K'} over { { t}_{ p} } = { 1} over {N-1 } - { ln { t} over { { t}_{p } } } over {ln { Q} over { { Q}_{p } } } }}}} where {{{{K'= { 1} over { { lnK}_{1 } } }}}} 12. Linking the two, empirical formulars for storage constant, K, and Gamma function argument, N, into closer relations with each other, derivation of unit hydrograph for the ungaged small watersheds can be established by having formulars for the time distribution and peak discharge of IUH as follows. Time distribution of IUH u(0, t)=23.2 A L-1S1/2 F(N, K, t) (㎥/sec) where {{{{F(N, K, t)= { { e}^{-t/k } { (t/K)}^{N-1 } } over { GAMMA (N) } }}}} Peak discharge of IUH) u(0, t)max=23.2 A L-1S1/2 F(N) (㎥/sec) where {{{{F(N)= { { e}^{-(N-1) } { (N-1)}^{N-1 } } over { GAMMA (N) } }}}} 13. The base length of the Time-Area Diagram for the IUH was given by {{{{C=0.778 { ( { LLca} over { SQRT { S} } )}^{0.423 } }}}} with correlation coefficient, 0.85, which has an indication of the relations to the length of main stream, L, centroid distance of the basin of the watershed area, Lca, and slopes, S. 14. Relative errors in the peak discharge of the IUH by using linear conceptual model and IUH by routing showed to be 2.5 and 16.9 percent respectively to the peak of observed unitgraph. Therefore, it confirmed that the accuracy of IUH using linear conceptual model was approaching more closely to the observed unitgraph than that of the flood routing in the small watersheds.

  • PDF

L-모멘트법을 이용한 지역홍수빈도분석을 통한 금강유역 미계측 유역의 설계홍수량 산정 (Estimating design floods for ungauged basins in the geum-river basin through regional flood frequency analysis using L-moments method)

  • 이진영;박동혁;신지예;김태웅
    • 한국수자원학회논문집
    • /
    • 제49권8호
    • /
    • pp.645-656
    • /
    • 2016
  • 본 연구에서는 금강유역에 대한 지역홍수빈도분석을 실시하고 재현기간에 따른 홍수량을 추정하는 관계식을 제안하였다. 유역 내 유량자료의 수문학적 독립성과 동질성에 대한 검증을 위하여 Lag-1 자기상관성 분석, 동질성 검정, 이상치 검정, 불일치척도 검정을 수행하였다. 검정 결과, 금강유역의 대상 관측소들은 시간에 대하여 독립적이고 동질적 모집단에 속하며 이상치는 없었다. 일반 극치 분포(GEV), 3변수 대수정규 분포(LN-III), 피어슨-III 분포(P-III), 일반 로지스틱 분포(GLO), 일반 파레토 분포(GPA) 등 5개의 3변수 확률분포함수에 대한 L-모멘트비도와 평균가중거리(AWD), 그리고 $Z^{DIST}$ 적합도 산정 결과, GLO 분포함수가 금강유역의 최적 확률분포형으로 선정되었다. GLO 분포를 바탕으로 지역홍수빈도를 추정하는 회귀모형을 제안하였고, 강경 관측소의 관측 유량을 이용하여 회귀모형의 적용성을 검증하였다.

경북-강원일대 탄산약수의 수질화학과 탄산 및 영족기체 기원 (Hydrochemistry and Origin of Noble Gases and $CO_2$ Gas Within Carbonated Mineral Waters in the Kyeoungbuk-Kangwon Province, Korea)

  • 정찬호;유상우;김규한
    • 지질공학
    • /
    • 제21권1호
    • /
    • pp.65-77
    • /
    • 2011
  • 본 연구에서는 경북 봉화지역, 강원도 오대산 및 춘천지역에서 산출되는 8개 탄산약수터에서 11개 탄산약수 시료를 대상으로 수리화학적 특성을 규명하고, 용존무기탄소의 동위원소(${\delta}^{13}C_{DIC}$)분석을 통해 탄산가스의 기원을 해석하며, 영족기체 동위원소($^3He/^4He$, $^{20}Ne/^{22}Ne$)의 동위원소 존재비를 분석하여 탄산가스의 기원과 연계한 영족기체의 기원을 밝히고자 하였다. 연구결과 탄산약수의 수리화학적 특성은 pH 5.59~6.04 범위로 약산성의 특성을 보이고, 전기전도도 값은 $302{\sim}864\;{\mu}S/cm$ 범위를 보인다. 모든 탄산약수의 수리화학적 유형은 Ca-$HCO_3$ 형에 속한다. 특히 Fe, Mn의 함량이 높아 음용수 수질기준치를 초과한다. 연구지역 탄산약수의 ${\delta}^{13}C_{DIC}$ 값은 -2.84~5.3‰ 범위를 보이므로 $CO_2$의 기원은 주로 심부기원이며, 물-암석 반응과정에서 탄산염광물등의 영향을 일부 받은 것으로 해석된다. 탄산약수의 $^3He/^4He$ 동위원소비와 $^4He/^{20}Ne$동위원소비 상관관계에서 탄산약수는 기원상 3개의 군으로 분류된다. 맨틀과 같은 심부기원의 영역, 대기기원에 가까운 영역, 맨틀기원과 대기기원의 혼합영역으로 도시된다. 이는 심부기원의 영족기체가 천부지하수와 지표노출에 의해 대기기원과 혼합된 것으로 해석되며, 맨틀과 같은 심부기원의 헬륨가스의 공급은 지질경계 및 단층과 같은 지질구조와 밀접한 관계가 있는 것으로 추정된다.