• Title/Summary/Keyword: $EC{\mu}M$

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Variation of OC and EC in PM2.5 at Mt. Taehwa (태화산 PM2.5 OC와 EC의 변화 특성)

  • Ham, Jeeyoung;Lee, Meehye;Kim, Hyun Seok;Park, Hyunju;Cho, Gangnam;Park, Jungmin
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.1
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    • pp.21-31
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    • 2016
  • Organic carbon (OC) and elemental carbon (EC) in $PM_{2.5}$ were measured with Sunset OC/EC Field Analyzer at Taehwa Research Forest (TRF) near Seoul metropolitan area from May 2013 to April 2014. During the study period, the mean concentrations of OC and EC were $5.0{\pm}3.2{\mu}gC/m^3$ and $1.7{\pm}1.0{\mu}gC/m^3$, respectively. They showed clear seasonality reaching their maximum in winter ($6.5{\mu}gC/m^3$ and $1.9{\mu}gC/m^3$) and minimum in wet summer ($2.5{\mu}gC/m^3$ and $1.4{\mu}gC/m^3$). While OC showed greater seasonal variation, the diurnal variation was more noticeable for EC through all seasons with a clear maximum in the morning, which reveals the influence of vehicle emissions. In contrast, OC exhibited a broad second peak in the afternoon during May~June, when biological activities were the highest. Using the morning peaks of EC and OC, primary OC/EC ratio was assessed, which was assumed to be anthropogenic origin. It was the greatest in winter followed by spring and the lowest in wet summer. The seasonal difference in primary OC/EC ratio implies the influence of non-local sources of OC at the Mt. Taehwa.

Evaluation of the Corrosion Resistance of Plated Ni and Ni-Cr Layers on Fe Substrate by Using Salt Spray, CASS and EC Tests (철소지 위에 형성된 니켈 및 니켈-크롬 도금층의 염수분무, 캐스, 전해부식시험법을 이용한 내식성평가)

  • 신재호;이동훈;이재봉;신성호
    • Journal of the Korean institute of surface engineering
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    • v.36 no.4
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    • pp.307-316
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    • 2003
  • Salt spray, CASS(copper accelerated acetic salt spray) and EC(electrolytic corrosion) tests were performed in order to evaluate the corrosion resistance of plated Ni and Ni-Cr layers on Fe substrate. Compared with the conventional methods such as salt spray and CASS, the electrochemical method such as EC test may be beneficial in terms of test time span and quantitative accuracy. Furthermore, EC test can also become the alternative method to evaluate the resistance to corrosion of coatings by measuring the corrosion potentials of the coated layers in the electrolyte during the off-time of EC cycles. Compared with the corrosion potentials of pure iron, nickel, chromium, those potentials of coated layers can be used to anticipate the extent of corrosion. Results showed that in terms of the test time span, EC test gave 14 times and 21 times faster results than the salt spray test in cases of $5\mu\textrm{m}$ Ni and $20\mu\textrm{m}$ Ni plated layers, respectively. In addition, EC test also offered the shorter test time span than CASS test in cases of $5 \mu\textrm{m}$ Ni + $0.5\mu\textrm{m}$ Cr, and $20\mu\textrm{m}$ Ni + $0.5\mu\textrm{m}$ Cr on Fe substrate by 78 times and 182 times, respectively. Therefore, EC test can be regarded as the better method to evaluate the resistance to corrosion of coated layers than the conventional methods such as salt spray and CASS.

Sensitivity of Sclerotium cepivorum Causing Garlic White Rot Isolated from Taeahn, Seosan and Goheung Areas to Fungicides (서산, 태안 및 고흥 지역에서 마늘 흑색썩음병을 일으키는 Sclerotium cepivorum의 살균제 감수성 조사)

  • Kim, Hyung Jo;Choi, Woobong;Kim, Heung Tae
    • The Korean Journal of Pesticide Science
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    • v.17 no.2
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    • pp.133-139
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    • 2013
  • To investigate the sensitivity of Sclerotium cepivorum causing garlic white rot to 5 fungicides, including prochloraz, tebuconazole, flutolanil, iminoctadine and isoprothiolane, 147 isolates isolated from infected garlics from 2008 to 2009 through a single sclerotium isolation were screened. While each mean value of $EC_{50}$ (effective concentration reducing mycelial growth by 50%) of S. cepivorum isolates collected in 2008 to each fungicide was 0.054, 0.012, 23.189, 0.901, and $21.362{\mu}g\;mL^{-1}$, that of 2009 isolates were 0.030, 0.020, 10.367, 1.684, $33.406{\mu}g\;mL^{-1}$. There was a difference in mean value of $EC_{50}$ of S. cepivorum according to regions isolated. $EC_{50}$ values of S. cepivorum isolated in Goheung to flutolanil and isoprothiolane were 14.468 and $24.653{\mu}g\;mL^{-1}$, respectively, which was lower than those of Seosan and Taeahn. Isolates from Taeahn showed the lowest $EC_{50}$ value to prochloraz as $0.008{\mu}g\;mL^{-1}$. In addition, we could not find any resistant isolates to fungicides tested. The $EC_{50}$ values in this study will be used in a fungicide resistance monitoring program to determine whether shifts in sensitivity to fungicides included into different groups are occurring in S. cepivorum populations.

Antioxidant and Xanthine Oxidase Inhibition Activities of Cynomorium songaricum Extracts

  • Seo, Soo-Jung;Han, Mi-Ra;Lee, Yang-Suk
    • Preventive Nutrition and Food Science
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    • v.16 no.4
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    • pp.307-312
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    • 2011
  • In this study, we evaluated the antioxidant activities and xanthine oxidase inhibition effects of water and ethanol extracts of Cynomorium songaricum. The ethanol extract of C. songaricum (EE) contained more phenolic and flavonoid compounds than the water extract (WE). The antioxidant activities of the extracts were increased as the concentration of the extract increased. The WE has better effectiveness than the EE for DPPH free radical scavenging activity and nitrite scavenging ability. The nitrite scavenging abilities of WE were 90.02% ($EC_{50}$ 653.15 ${\mu}g$/mL) at conditions of pH 1.2 and 2,000 ${\mu}g$/mL, and 84.34% ($EC_{50}$ 817.17 ${\mu}g$/mL) at pH 3.0. The EE has more effective SOD-like activity and XO inhibition than WE. The SOD-like activity of EE was 81.47% at a concentration of 2,000 ${\mu}g$/mL, $EC_{50}$ was 951.70 ${\mu}g$/mL. The xanthine oxidase inhibition of the EE, with an $EC_{50}$of 112.47 ${\mu}g$/mL, is greater than that of ascorbic acid, which was 192.50 ${\mu}g$/mL (p<0.05). These results suggest that the C. songaricum is a potentially useful antioxidant source for the development of nutraceuticals and medicines.

Baseline Sensitivity and Monitoring for the Resistance to Benomyl of Fusarium Species Causing Bakanae Disease in Korea (국내 벼 키다리병균의 Benomyl 약제에 대한 감수성 기준 및 저항성 변화)

  • Choi, Hyo-Won;Lee, Yong Hwan;Hong, Sung Kee;Lee, Young Kee;Lee, Jae Guem;Kim, Hyo Won
    • The Korean Journal of Mycology
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    • v.43 no.4
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    • pp.260-266
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    • 2015
  • To examine the changes in resistance to benomyl of Fusarium species causing bakanae disease, Fusarium isolates were collected in Korea, and pathogenicity tests were performed using rice seeds in vitro. Minimum inhibitory concentration (MIC) and effective concentration of 50% ($EC_{50}$) values of isolates were examined using the agar dilution method. High frequency distribution of MIC values to benomyl against isolates collected in 2006~2007 and 2013~2014 years were $1.5625{\sim}3.125{\mu}g/mL$ and more than $25{\mu}g/mL$, respectively. The mean $EC_{50}$ value of isolates to benomyl increased from $1.6397{\mu}g/mL$ in 2006~2007 to $2.4892{\mu}g/mL$ in 2013~2014. Based on MIC and $EC_{50}$ values of isolates, the moderate resistance of benomyl were determined as more than $25{\mu}g/mL$ of MIC and less $2.4{\mu}g/mL$ of $EC_{50}$ value, and resistant isolates to benomyl were determined as more than $2.4{\mu}g/mL$ of $EC_{50}$ value. Compared with the ratio of resistant isolates in 2006~2007, the ratio of resistance isolates in 2013~2014 increased from 12.5% to 36.4%. In addition, multiple resistant isolates to prochloraz as well as benomyl increased to 20.3% in 2013~2014.

Concentrations of Carbonaceous Compounds and Quantitation of Secondary Organic Carbon in PM2.5 at Taehwa Research Forest

  • Lee, Seung-Ha;Lee, Sang-Deok;Kim, Dan-Bi;Kim, Rhok-Ho;Lee, Sang-Bo
    • Journal of Forest and Environmental Science
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    • v.34 no.1
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    • pp.53-56
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    • 2018
  • Elemental carbon (EC) and organic carbon (OC) mass concentrations in PM2.5 were measured from March through October 2015 in Taehwa Research Forest (TRF). The concentration of carbon in the TRF was $3.4{\mu}g/m^3$ and the concentration of EC was $1.4{\mu}g/m^3$. Also the concentration of $OC_{sec}$ was the highest at $2.84{\mu}g/m^3$ in the summer and the lowest at 1.66 in the spring. The ratio of the secondary generation OC in the total OC was the highest at 62% in the summer. Monthly OC concentration was the lowest at $2.38{\mu}g/m^3$ in April and the highest at $6.60{\mu}g/m^3$ in July. In case of EC concentration was the lowest in April ($0.98{\mu}g/m^3$) and the highest in July ($3.41{\mu}g/m^3$). The OC/EC ratio showed the lowest ratio in March and the highest rate in September. It is suggested that the secondary generation reaction of OC component was active due to sufficient irradiation amount in summer.

Detection for the Resistance of Fusarium spp. Isolated from Rice Seeds to Prochloraz and Cross-resistance to Other Fungicides Inhibiting Sterol Biosynthesis (벼 종자에서 분리한 Fusarium속 균주들의 prochloraz에 대한 저항성 검정 및 교차 저항성 조사)

  • Shin, Myeong-Uk;Kang, Hyo-Jung;Lee, Yong-Hwan;Kim, Heung-Tae
    • The Korean Journal of Pesticide Science
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    • v.12 no.3
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    • pp.277-282
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    • 2008
  • To assess the resistance to prochloraz, $EC_{50}$ values of Fusarium isolates obtained from rice seed were investigated through the agar dilution method. $EC_{50}$ value of 36 isolates of Fusarium spp. to prochloraz ranged from 0.020 to $1.78{\mu}g\;mL^{-1}$ with an average of $0.25{\mu}g\;mL^{-1}$. According to the species of Fusarium, the average $EC_{50}$ value was fluctuated; $0.091{\mu}g\;mL^{-1}$ for F. moniliformis, $0.11{\mu}g\;mL^{-1}$ for F. proliferatum and $0.31{\mu}g\;mL^{-1}$ for F. fujikuroi. The resistant baseline was decided at $0.5{\mu}g\;mL^{-1}$ to determine if the isolate was resistant to prochloraz or not. Based on the resistant baseline, the ratio of resistant isolates was 14%. There was no correlation between the resistance to prochloraz and the pathogenicity of Fusarium spp. on rice seedlings. The resistant isolates of F. fujikuroi did not show the cross-resistance to other sterol biosynthesis inhibiting fungicides, triflumizole, hexaconazole, difenoconazole and tebuconazole.

Acute Toxicity Assessment of New Algicides of Thiazolidinediones Derivatives, TD53 and TD49, Using Ulva pertusa Kjellman

  • Yim, Eun-Chae;Park, In-Taek;Han, Hyo-Kyung;Kim, Si-Wouk;Cho, Hoon;Kim, Seong-Jun
    • Environmental Analysis Health and Toxicology
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    • v.25 no.4
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    • pp.273-278
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    • 2010
  • Objectives : This study was aimed to examine the acute toxicity assessment of two new algicides, thiazolidinediones derivatives (TD53 and TD49), which were synthesized to selectively control red tide, to the marine ecosystem. Methods : The assessment employed by a new method using Ulva pertusa Kjellman which has been recently accepted as a standard method of ISO. The toxicity was assessed by calculating the $EC_{50}$ (Effective Concentration of 50%), NOEC (No Observed Effect Concentration) and PNEC (Predicted No Effect Concentration) using acute toxicity data obtained from exposure experiments. $EC_{50}$ value of TD49 and TD53 was examined by 96-hrs exposure together with Solutol as a TD49 dispersing agent and DMSO as a TD53 solvent. Results : $EC_{50}$ value of TD53 was $1.65\;{\mu}M$. From the results, values of NOEC and PNEC were calculated to be $0.63\;{\mu}M$ and 1.65 nM, respectively. DMSO under the range of $0{\sim}10\;{\mu}M$, which is same solvent concentration used in examining TD53, showed no toxic effect. $EC_{50}$ value of TD49 was $0.18\;{\mu}M$ and that of Solutol was $1.70\;{\mu}M$. NOEC and PNEC of TD49 were $0.08\;{\mu}M$ and 0.18 nM, respectively and those for Solutol were $1.25\;{\mu}M$ and 1.25 nM, respectively. Conclusions : From the values of NOEC, PNEC of TD53 and TD49, TD49 showed 9 times stronger toxicity than TD53. On the other hand, DMSO showed no toxicity on the Ulva pertusa Kjellman, but Solutol was found to be a considerable toxicity by itself.

Establishment of Baseline Sensitivity of Phytophthora capsici Causing Pepper Phytophthora Blight to Carboxylic Acid Amide Fungicides (Carboxylic acid amide계 살균제에 대한 고추 역병균 Phytophthora capsici의 감수성 기준 설정)

  • Kim, Jin-Ho;Kim, Joo-Hyung;Lee, Kyeong-Hee;Rho, Chang-Woo;Kim, Heung-Tae
    • The Korean Journal of Pesticide Science
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    • v.14 no.4
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    • pp.456-462
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    • 2010
  • Baseline sensitivity to benthiavalicarb, iprovalicarb and dimethomorph included into carboxylic acid amide (CAA) group was evaluated in 180 isolates of Phytophthora capsici over 4 years from 2005 to 2008. $EC_{50}$ (effective concentration inhibiting mycelial growth by 50%) value of benthiavalicarb ranged from $0.015{\mu}g\;mL^{-1}$ to $0.049{\mu}g\;mL^{-1}$ with a mean of $0.033{\mu}g\;mL^{-1}$. The mean values of $EC_{50}$ of iprovalicarb and dimethomorph were 0.411 (0.197 - 0.556) ${\mu}g\;mL^{-1}$ and 0.271 (0.101 - 0.798) ${\mu}g\;mL^{-1}$, respectively. Although there was no increasing tendency in $EC_{50}$of benthiavalicarb and iprovalicarb during 4 years, $EC_{50}$ of dimethomorph was increased gradually by laps of time. There was no cross-resistance between each fungicide used in this study and metalaxyl. Among fungicides included into CAA group, there was a positive correlation between benthiavalicarb and iprovalicarb, and between dimethomorp and mandipropamid.

Seasonal Variations of OC and EC in PM10, PM2.5 and PM1.0 at Gosan Superstation on Jeju Island (제주도 고산 PM10, PM2.5, PM1.0 중 OC와 EC의 계절별 변화 특성)

  • Lim, Sae-Hee;Lee, Mee-Hye;Kang, Kyeong-Sik
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.5
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    • pp.567-580
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    • 2010
  • Organic carbon (OC) and elemental carbon (EC) concentrations were determined for $PM_{10}$, $PM_{2.5}$ and $PM_{1.0}$ aerosols particles collected at Gosan Superstation on Jeju Island from August 2007 to September 2008. Aerosols were collected on quartz filters for 24 hours and then OC and EC were analyzed by TOR/IMPROVED method. Mean concentrations of OC and EC were $4.66\;{\mu}g/m^3$ and $1.69\;{\mu}g/m^3$ for $PM_{10}$, $3.95\;{\mu}g/m^3$ and $1.69\;{\mu}g/m^3$ for $PM_{2.5}$, and $3.16\;{\mu}g/m^3$ and $1.42\;{\mu}g/m^3$ for $PM_{1.0}$, respectively. The concentrations of OC and EC comprised 16.4% and 6.0% of $PM_{10}$, 22.9% and 9.8% of $PM_{2.5}$, and 23.0% and 10.0% of $PM_{1.0}$. OC and EC showed a clear seasonal variation with the highest in winter and the lowest in summer. The correlations between the two were also the best during the winter ($R^2$=0.87, 0.94, and 0.95 for $PM_{10}$, $PM_{2.5}$ and $PM_{1.0}$). The ratio of OC/EC exhibited the maximum (7.24) during an Asian dust event due to an increase of OC, which was possibly derived from soil. The mass fraction of both OC and EC was the highest in fall. When OC and EC concentrations were highly elevated, EC1 (the first EC fraction determined at $550^{\circ}C$) and pyrolyzed OC (POC) were dominant subcomponents in winter and OC3 (the third OC fraction determined at $450^{\circ}C$) and POC in spring.