• 제목/요약/키워드: $Cu_2$Te

검색결과 91건 처리시간 0.019초

Reverse-bias Leakage Current Mechanisms in Cu/n-type Schottky Junction Using Oxygen Plasma Treatment

  • Kim, Hogyoung
    • Transactions on Electrical and Electronic Materials
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    • 제17권2호
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    • pp.113-117
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    • 2016
  • Temperature dependent reverse-bias current-voltage (I-V) characteristics in Cu Schottky contacts to oxygen plasma treated n-InP were investigated. For untreated sample, current transport mechanisms at low and high temperatures were explained by thermionic emission (TE) and TE combined with barrier lowering, respectively. For plasma treated sample, experimental I-V data were explained by TE or TE combined with barrier lowering models at low and high temperatures. However, the current transport was explained by a thermionic field emission (TFE) model at intermediate temperatures. From X-ray photoemission spectroscopy (XPS) measurements, phosphorus vacancies (VP) were suggested to be generated after oxygen plasma treatment. VP possibly involves defects contributing to the current transport at intermediate temperatures. Therefore, minimizing the generation of these defects after oxygen plasma treatment is required to reduce the reverse-bias leakage current.

CdZnS/CdTe 이종접합의 전기적 특성에 관한 연구 (A study on the electrical characteristics of CdZnS/CdTe heterojunction)

  • 이재형
    • 한국정보통신학회논문지
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    • 제14권7호
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    • pp.1647-1652
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    • 2010
  • CdTe 및 Cu(In,Ga)$Se_2$ 박막 태양전지의 창층으로 널리 이용되는 CdS에서 Cd의 일부를 Zn으로 치환하면 두 물질 사이의 전자 친화력의 정합이 향상되고 에너지 밴드 갭이 증가하여 개방전압 및 광전류를 증가시킬 수 있다. 본 연구에서는 태양전지와 같은 광전소자에 적용되는 CdZnS와 CdTe로 구성되는 이종접합 소자를 제작하고 접합에서의 전류 전도기구를 조사하기 위해 온도에 따른 전류-전압 특성을 분석하였다. CdS/CdTe 접합의 전류 흐름은 계면 재결합과 터널링의 조합에 의해 조절되지만 CdZnS/CdTe 접합의 경우 상온 이상의 온도에서는 공핍층에서의 생성/재결합, 상온 이하의 온도에서는 누설 전류나 터널링에 의해 전류 흐름이 제한됨을 알 수 있었다.

In과 Ga가 미포함 된 Kesterite Cu2ZnSn(S1-x,Sex)4 (CZTSS) 박막형 태양전지 개발 현황 (Development of Kesterite Cu2ZnSn(S1-x,Sex)4 (CZTSS)-Based Thin Film Solar Cells with In and Ga Free Absorber Materials)

  • 신승욱;한준희;강명길;윤재호;이정용;김진혁
    • 한국재료학회지
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    • 제22권5호
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    • pp.259-273
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    • 2012
  • Chalcogenide-based semiconductors, such as $CuInSe_2$, $CuGaSe_2$, Cu(In,Ga)$Se_2$ (CIGS), and CdTe have attracted considerable interest as efficient materials in thin film solar cells (TFSCs). Currently, CIGS and CdTe TFSCs have demonstrated the highest power conversion efficiency (PCE) of over 11% in module production. However, commercialized CIGS and CdTe TFSCs have some limitations due to the scarcity of In, Ga, and Te and the environmental issues associated with Cd and Se. Recently, kesterite CZTS, which is one of the In- and Ga- free absorber materials, has been attracted considerable attention as a new candidate for use as an absorber material in thin film solar cells. The CZTS-based absorber material has outstanding characteristics such as band gap energy of 1.0 eV to 1.5 eV, high absorption coefficient on the order of $10^4cm^{-1}$, and high theoretical conversion efficiency of 32.2% in thin film solar cells. Despite these promising characteristics, research into CZTS-based thin film solar cells is still incomprehensive and related reports are quite few compared to those for CIGS thin film solar cells, which show high efficiency of over 20%. The recent development of kesterite-based CZTS thin film solar cells is summarized in this work. The new challenges for enhanced performance in CZTS thin films are examined and prospective issues are addressed as well.

한국(韓國) 남서부(南西部)의 덕음(德蔭)과 전주(全州)-금은광상(金銀鑛床)에 대(對)한 암석지구화학적(岩石地球化學的) 연구(硏究) (Lithogeochemistry on the Dukum and Jeonjuil gold - silver deposits in Southern - western part of Korea)

  • 윤정한;전용원;전효택
    • 자원환경지질
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    • 제21권4호
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    • pp.389-400
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    • 1988
  • Minor elements such as Ag, As, Au, Bi, Cd, Cu, Co, Ni, Pb, Rb, Sb, Sr and Te were analyzed by atomic absorption spectrophotometry and induced coupled plasma spectrophotometry in order to investigate pathfinders for gold in quartz porphyry, granite porphyry and vein materials in Jeonjuil gold - silver mine, and in altered biotite granites and vein materials in Dukum gold - silver mine. In Dukum gold - silver mine, it is observed that Au contents have positive relation with As, Co, and Rb contents, but negative relation with Bi contents in altered biotite granites. Au contents have positive relation with Ag, As, Co and Te contents in vein materials. In Jeonjuil gold - silver mine, it is observed that Cd, Rb, Sr and Te are enriched near ore vein in quartz porphyry and granite porphyry. Au contents have positive relation with As, Cd, Cu, $Fe_2O_3$ and $K_2O$ in vein materials.

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태양전지용 CdTe 박막의 물리적.전기적 특성에 미치는 열처리 효과 (Effects of Annealing Conditions on Physical and Electrical Properties of CdTe Thin Film for Solar Cell)

  • 김현수;조영아;염근영;신성호;박정일;박광자
    • 한국진공학회지
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    • 제4권3호
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    • pp.306-312
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    • 1995
  • 본 연구에서는 비정질 실리콘과 CuInSe2와 함께 지상용 태양전지재료로 널리 연구되고 있는 다결정 CdTe 박막의 열처리방법으로서 로열처리와 반도체 공정에서 사용되는 급속열처리 방법을 이용하여 이들 열처리의 효과를 분석함으로써 태양전지용 다결정 CdTeq 박막에 적합한 효율적인 열처리 방법에 대한 연구를 수행하였다. 증착 후 열처리조건에 따른 결정구조, 결정립 크기, 표면과 박막내부의 성분, 밴드갭 에너지값, 그리고 전기비저항 등을 측정하여 태양전지용 CdTe 박막의 물리적.전기적 특성에 미치는 열처리효과를 관찰하였다. 연구결과 30$0^{\circ}C$에서 증착하고 CdCI2 처리 후 $400^{\circ}C$ 30분간 로열처리를 한 경우, 그리고 $200^{\circ}C$에서 증착한 후 $500^{\circ}C$ 부근에서 1분간 급속열처리를 한 경우 다결정 CdTe 박막의 물리적 전기적 특성이 현저히 향상됨을 알 수 있었다. 특히 급속열처리를 한 경우 로열처리에 비해 결정립의 크기는 작으나 전기비저항이 낮고 밴드갭에너지가 단결정에 더욱 접근하며 태양전지용 다결정 CdTe 박막의 열처리 방법으로 적용할 가치가 있는 방법으로 사료된다.

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Selective tyrosine conjugation with a newly synthesized PCB -TE2A-luminol bifunctional chelator

  • Subramani Rajkumar;Hyun Park;Abhinav Bhise;Seong Hwan Cho;Jung Young Kim;Kyo Chul Lee;Jeongsoo Yoo
    • 대한방사성의약품학회지
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    • 제7권2호
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    • pp.85-91
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    • 2021
  • Selective amino acid conjugation of bulky antibodies is a valuable asset for real-time diagnosis and therapy. However, selective conjugation incorporating a chelate-bearing radioactive atom into an antibody without affecting its immunoreactivity is a challenging task. A bifunctional chelator (BFC), a selective amino acid-targeting probe, and a linker have been developed to overcome this problem. Here, we report the synthesis of a novel propylene cross-bridged chelator (PCB)-1,8-N,N'-bis-(carboxymethyl)-1,4,8,11-tetraazacyclotetradecane (TE2A)-luminol BFC via a click reaction and radiolabel it with a 64Cu ion for tyrosine-selective conjugation of trastuzumab. In the initial optimization study, we tried different oxidative addition conditions such as electro-oxidation, hemin, horseradish peroxidase, iodogen tube, chloramine-T, and iodo beads. In this study, up to 82% of 64Cu-PCB-TE2A-luminol was conjugated with the antibody in an iodo bead-catalyzed oxidative addition reaction with an isolated yield of 24.4%.

CuTBP(Copper-tetra-tert-butylphthalocyanine) 화학 저항 장치를 이용한 NO$_2$ 가스 탐지기의 개발에 관한 연구 (A study on the NO$_2$ gas detector development using the CuTBP (Copper-tetra-te rt-butylphthalocyanine) chemiresistor device)

  • 구자룡;이창희;김태완;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.417-420
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    • 1996
  • We have investigated air/200ppm NO$_2$ gas-detector characteristics of using CuTBP (Copper-tetra-tert-butylphthalocyanine) chemiresistor devices. The CuTBP films were made by Langmuir-Blodgett (LB) techniques. Sensitivity, response time, recovery time, and repoducibility of the devices were measured by current-voltage characteristics. To increase sensitivity, interdigital electrode was used. It was found that a conductance G increases monotonically as the number of interdigital electrode increases, and a Sensitivity, Reproducibility is stable. As far as a current is concerned, the current when N=25 is greater than that when N=1 by 70 or so. It indicates that the number of interdigital electrodes affects the current, sensitivity and stability We have also investigated applicability of the CuTBP chemiresistor device for a gas detector.

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