• Journal of Electrical Engineering and Technology
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• v.9 no.5
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• pp.1719-1723
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• 2014

In this study, the microwave dielectric properties of nano spheroidization glass powders added $Ba(Zn_{1/3}Ta_{2/3})O_3$ ceramics prepared by solid state reaction have been investigated. Adding $(Ba_{0.4}Ca_{0.6})SiO_3$ nano spheroidization glass powders could effectively promote the densification even in the case of decreasing the sintering temperature. When the glass frit is 0.3 wt% and sintering is carried out at a temperature of $1500^{\circ}C$ for 6 hr, a temperature stable microwave dielectric ceramic could be obtained, which has a dielectric constant (${\varepsilon}_r$) of 30.2, a quality factor ($Q{\times}f_0$) of 124,000 GHz and a temperature coefficient of resonance frequency (${\tau}_f$) of $2ppm/^{\circ}C$.

• 보존과학연구
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• s.22
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• pp.93-114
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• 2001

The composition analysis of Danchung pigments at Geunjeongjeon Hall in Gyeongbokgung Palace were carried out by FXRF and MXRD. The analytical result of the inside pigments at Geunjeongjeon showed that these painted in use the mineral pigments. Gold pigment was pure gold(Au).The main composition identified in green pigments were chalcanthite($CuSO_4$.$5H_2O$) and celadonite($K(Mg, Fe, Al)_2$.$(Si, Al)_4O_10(OH)_2$ ). Red pigments werecinnnabar(HgS).The analytical result of the outside pigments at Geunjeongjeon revealed that these applied to the artificial synthetic pigment. Yellow pigment was chromeyellow($PbCrO_4$). The main composition identified in red pigments were red lead($Pb_3O_4$)and hematite($Fe_2O_3$). Green pigments were emeral green($C_2H_3A_s3Cu_2O_8$) and chromegreen($Cr_2O_3$). Blue pigment was lazurite($Na_6Ca2Al_6Si_6O_24(SO_4)_2$), titanium dioxide($TiO_2$) of white pigment.

• Journal of the Korean Home Economics Association
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• v.41 no.8
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• pp.55-62
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• 2003

Natural dyes generally fan into two categories; organic dyes coming from animals and plants and inorganic dyes obtained from various minerals such as bengala, loess, ultramarine, prussian blue and etc. The main components of volcanic ash is clay mineral such as kaolinite, illite, quartz. Clay minerals Composing volcanic ash are kaolinite［$Al_4Si_4O_{10}{(OH)_{8}}$］, illite［$K_{X}Al_2(Si,\;Al)_4O_{10}{(OH)}_2$］, quartz［$SiO_2$］, homblende［$Na_{0-1}\;Ca_2{(Mg,\;Fe,\;Al)}_5{(Si,\;Al)}_{8}O_{22}{(OH)}_2$］and etc. And the redish color mainly comes from iron oxide. In this paper, two different classes of dyeing process were tested; dyeing with volcanic ash only and cationic agent pre-treatment followed by dyeing with volcanic ash. The compositions of the volcanic ash powder and the volcanic ash deposited on the cotton knitted fabrics identified by energy dispersive spectrometer and XRD analysis. The major chemical components of volcanic ash deposited on the cotton knitted fabrics were confirmed to be the saicon oxide, iron oxide, and aluminum oxide and etc. According to the analysis by XRD and EDS-SEM, kaolinite, illite and quartz were also identified.

• Journal of Microbiology and Biotechnology
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• v.18 no.12
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• pp.1903-1907
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• 2008

Prodigiosin is a natural red pigment with algicidal activity against Cochlodinium polykrikoides, a major harmful red-tide microalga. To increase the yield of prodigiosin production by Hahella chejuensis KCTC 2396, significant medium components were determined using a two-level Plackett-Burman statistical design technique. Among 12 components included in basal medium, $NaHCO_3$, ${Na}_{2}{SiO}_{3}$, ${NH_4}{NO_3}$, ${Na}_{2}{SO}_{4}$ and $CaCl_2$ were determined to be important for prodigiosin production. The medium formulation was finally optimized using a Box-Behnken design as follows: 1% sucrose; 0.4% peptone; 0.1 % yeast extract; and (g/l): NaCl, 20.0; ${Na}_{2}{SO}_{4}$, 9.0; $CaCl_2$, 1.71; KCl, 0.4; and (mg/l): ${H_3}{BO_3}$, 10.0; KBr, 50.0; NaF, 2.0; $NaHCO_3$, 45.0; ${Na}_{2}{SiO}_{3}$, 4.5; ${NH_4}{NO_3}$, 4.5. The predicted maximum yield of prodigiosin in the optimized medium was 1.198 g/l by the Box-Behnken design, whereas the practical production was 1.495 g/l, which was three times higher than the basal medium (0.492 g/l).

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.5
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• pp.436-441
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• 2015

The chemical properties of paddy fields in Gyeonggi province were monitored every 4 years from 1999 to 2015 in order to provide basic information for soil fertility management of paddy fields. In 2015, the soil chemical properties of paddy fields were 5.9 in pH, $23g\;kg^{-1}$ in organic matter (OM), and $84mg\;kg^{-1}$ in available phosphate (Avail. $P_2O_5$). Exchangeable (Exch.) potassium (K), calcium (Ca) and magnesium (Mg) were 0.30, 5.1 and $1.3cmol_ckg^{-1}$, respectively, and available silicate (Avail. $SiO_2$) was $129mg\;kg^{-1}$. In the long-term analysis, the contents of Avail. $SiO_2$, Exch. Ca and pH of paddy soils showed increasing tendency. However, Avail. $P_2O_5$ and Exch. K tended to decrease, and there were no significant changes in the contents of OM and Exch. Mg. Paddy soil within appropriate pH range increased from 44% in 1999 to 76% in 2003, 84% in 2007, 63% in 2011, and 80% in 2015. But soil within appropriate range of Exch. Ca tended to decrease, showing 36% in 1999, 42% in 2003, 38% in 2007, 37% in 2011 and 32% in 2015. In case of Avail. $SiO_2$, soil within appropriate range increased from 14% in 1999 to 17% in 2003, 18% in 2007, 16% in 2011, and 31% in 2015. As a result, paddy fields with less in nutrient level need to be more fertilized based on soil analysis. And the application of silicate fertilizer is strongly recommended to those of paddy fields in need. Also soil management such as the cultivation of green manure crop or application of rice straw will be necessary to increase the organic matter content of paddy soil.

• Journal of the Korean Magnetics Society
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• v.20 no.3
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• pp.114-119
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• 2010

Fe compounds of volcanic rock samples distributed in the seaside area of Ulleung island were investigated by means of X-ray diffractometry (XRD), X-ray fluorescence spectroscopy (XRF) and M$\ddot{o}$ssbauer spectroscopy. We found that samples were typical basic rock which had the total amount of iron compounds including hematite ($\alpha-Fe_2O_3$) varies from 10.6 w% to 14.5 w% depending on the different regions by XRF. The M$\ddot{o}$ssbauer spectra of the samples were consisted of one sextet due to hemitite and doublets due to $Fe^{3+}$ in various clay mineral and $Fe^{2+}$ in pyroxene $(Ca,Fe,Mg)_2(SiO_4)_2$, ilmenite ($FeTiO_3$) and olivine $(Mg,Fe)_2SiO_4$. The balance state of Fe ions of all samples was chiefly $Fe^{3+}$, so we could find that the volcanic rocks distributed in the seaside area of Ulleung island were made in inland.

• Journal of the Korean Chemical Society
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• v.34 no.1
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• pp.63-68
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• 1990

The chemical ingredients such as $SiO_2,\;Al_2O_3,\;MgO,\;Fe_2O_3,\;CaO$ and $TiO_2$in silica minerals were determined by X-ray fluorescence spectrometry using a matrix correction method. The synthesized standards mixed with reagent grade oxides and the sample were diluted by fusing with 16 times $Li_2B_4O_7$. The matrix effects correlated among the ingredients were corrected by the empirical coefficient method based on the Lucas-Tooth and Pyne model. The analytical results showed relatively good agreement between the different sets of coefficients but were improved with increasing the number of standard. The accuracy of this method was also examined with the standard reference material of NIST.

• Journal of the Korean Geophysical Society
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• v.7 no.2
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• pp.113-120
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• 2004

Hydrochemical characteristics of deep groundwater at Surak-ri, Nonsan-gun, Chungnam Province was explained by major ion concentration, water type, and phase stability diagram. The area is composed of meta-sedimentary rock and quartz pophyry. The 5 boreholes where deep groundwater was sampled and analyzed are located on the meta-sedimentary rocks and drilling depth range of the wells is from 554 m to 928 m. pH, TDS, Na, and SiO2 values are high in the groundwater from meta-sedimentary area intruded by quartz pophyry, while Ca is high in the groundwater from meta-sedimentary area. K and Mg concentrations are low but F concentration is high both groundwater. The content of major anions is in the order of CO3(HCO3)>Cl>SO4(F) in both geology, while that of major cations shows the order of Na>Ca>K(Mg) in meta-sedimentary area intruded by quartz porphyry and a>Na>Mg>Na in meta-sedimentary area. Based on the phase equilibrium in the systems Na2O-Al2O3-SiO2-H2O and K2O-Al2O3-SiO2-H2O, the groundwater is saturated with respect to Quartz and more evolved compared with the natural mineral water. It is concluded that chemical evolution in the groundwater from meta-sedimentary area intruded by quartz porphyry, is nearly saturated with respect to feldspar, while the groundwater from meta-sedimentary area continue to proceed with increasing pH by reaction of feldspar.

• Journal of the Korean Ceramic Society
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• v.25 no.3
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• pp.207-216
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• 1988

Effect of $SO_3$ on the formation of $C_3S$ and its properties were investigated through studies for diffusion of reacting component, the size variation of $C_3S$ and compositional change of the phases in the clinker. When less than 2.0% of $SO_3$ was added to the clinker composition, the formation of $C_3S$ was enhanced, however, addition of more than 2.0% of $SO_3$ rather restrained the reaction remarkably. The diffusion coefficient of Si into the melt was about $3.6~4.2{\times}10^{-7}Cm^2$/sec and it was slightly decreased with the amount of $SO_3$. The crystal size of $C_3S$ formed in the clinker was grown gradually according to the amount of $SO_3$, when more than 1.0% of $SO_3$ was added. With increasing of $SO_3$ content in the clinker composition of CaO and decreasing of $SiO_2$ were found in the melt of the clinker. Consequently, it is considered that the decreasing of $C_3S$ formation is caused by dissolution and transportation of CaO component into liquid phase is interrupted.

• Journal of the Korean Ceramic Society
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• v.47 no.4
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• pp.302-307
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• 2010

This study aims to synthesize emerald-green malayaite pigments using $CaCO_3$, $SiO_2$, $SnO_2$ and $V_2O_5$. For this purpose, the optimum composition is $CaV_{0.25}Sn_{0.687}SiO_5$ and heating condition is at $1250^{\circ}C$ for 6 h of soaking time. The samples were characterized by X-ray diffraction (XRD), the Fourier Transform Infrared Spectrometers(FT-IR), the Raman Spectrometer, Scanning Electron Microscope(SEM) and the UV/Vis spectroscopy. The substituted V ion for Sn was observed to be quadrivalence. The analytical results of the synthesized pigment showed the tetragonal crystal, a typical form of Malayaite, and the particle size to be approximately $5{\sim}10\;{\mu}m$. The color in lime glaze added 12 wt% pigment was emerald green, and CIE Lab parameters are $L^*=67.73$, $a^*=-12.39$ and $b^*=9.28$.