• Title/Summary/Keyword: $C_3A$량

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Fuel Characteristics of Quercus variabilis bio-oil by Vaccum Distillation (감압증류에 의한 굴참나무 바이오오일의 연료 특성 변화)

  • Chea, Kwang-Seok;Jo, Tae-Su;Lee, Soo-Min;Lee, Hyung Won;Park, Young-Kwon
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.75-82
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    • 2016
  • The technology of fast pyrolysis is regarded as a promising route to convert lignocellulose biomass into bio-oil which can be upgraded to transportable fuels and high quality chemical products. Despite these promises, commercialization of bio-oil for fuels and chemicals production is limited due to its notoriously undesirable characteristics, such as high and changing viscosity, high water and oxygen contents, low heating value and high acidity. Therefore, in this study quality improvement of bio-oil through vaccum distillation had been targeted. A 600 g of cork oak(Quercus variabilis) which grounded 0.8~1.4 mm was processed into bio-oil via fast pyrolysis for 1.64 seconds at $465^{\circ}C$ and temperature of vaccum distillation(100hPa) was designed to control, $40^{\circ}C$, 50, 60, 70, and 80 for 30min. Bio-oil, biochar, and gas of pyrolytic product were produced to 62.6, 18.0 and 19.3 wt%, respectively. The water content, viscosity, HHV(Higher Heating Value) and pH of bio-oil were measured to 0.9~26.1 wt%, 4.2~11.0 cSt 3,893~5,230 kcal/kg and 2.6~3.0, respectively. Despite these quality improvement, production was still limited due to its notoriously undesirable characteristics, therefore continous quality improvement will be needed in order to use practical fuel of bio-oil.

Isolation of a Bacteriocin - Producing Lactobacillus sakei Strain from Kimchi (김치에서 박테리오신을 분비하는 Lactobacillus sakei균주의 분리)

  • 김한택;박재용;이강권;김정환
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.3
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    • pp.560-565
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    • 2004
  • Bacteriocin producing lactic acid bacteria (LAB) were isolated from Kimchi by using spot-on-the-lawn method. Listeria monocytogenes, Staphylococcus aureus, and Lactobacillus plantarum were used as indicators. One isolate (P3-l) produced a bacteriocin efficiently inhibiting the growth of Listeria monocytogenes. 16S rDNA sequence and sugar utilization test identified that P3-1 was a Lactobacillus sakei strain. Accordingly, the isolate was named as Lactobacillus sakei P3-1. L. sakei P3-1 produced a bacteriocin which efficiently inhibited the growth of Listeria monocytogenes but did not inhibit other Gram positive and negative organisms tested. The bacteriocin was stable against heat, organic solvent, and pH variation and it retained 50% of activity after 10 min heat treatment at 10$0^{\circ}C$. The molecular weight of Sakacin P3-1 was estimated to be 4 kDa by SDS-PAGE.

Fundamental Study on High Strength and High Durability Cement Concrete Pavement : Part I Optimum Mix Proportions (시멘트콘크리트 포장의 고강도 고내구성을 위한 기초 연구 : Part I 최적배합에 관한 연구)

  • Yun, Kyong-Ku;Park, Cheol-Woo
    • International Journal of Highway Engineering
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    • v.11 no.3
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    • pp.41-49
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    • 2009
  • Cement concrete pavement has become more common in Korean highway systems. However, as its service period increases, there are some technical problems occurs and no clear solution is available primarily due to the lack of active researches. This research, hence, aims to develop a new mix proportion that may provide better strength and durability with extended service life. Based on a variety of literature reviews, the experimental variables were determined as unit cement content, S/a ratio and W/C ratio. From the experimental works, it is recommended to increase the unit cement content up to 375kg/$m^3$, 400kg/$m^3$ and 425kg/$m^3$. The target slump and air content were set 40mm and 5%, respectively. The maximum size of coarse aggregate was decided to be 25mm because of the easiness of supply in the field. The reduction of W/C ratio was necessarily required and decreased to 0.4 which was proven not to cause any mixing problem with the increased unit cement contents along with polycarbon-based high range water reducing agent. In addition, it was known that the S/a ratio could be reduced to 0.34. The lowered S/a might be possible because of the increased cement paste and hence increased cohesiveness and workability.

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Denaturation of Heat Treated Lysozyme under High Pressure Conditions (고압조건에서 가열 처리된 Iysozyme의 변성)

  • Cho, Rae-Kwang;Hong, Jin-Hwan
    • Korean Journal of Food Science and Technology
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    • v.23 no.3
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    • pp.366-369
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    • 1991
  • In order to elucidate texturization mechanism of extrudated protein, egg white lysozyme was heated under high pressure conditions, and its solubility and changes of molecular weight were investigated. Under high pressure conditions of $100,\;300\;and\;600\;kg/cm^2$, solubility decreased gradually with increasing temperature in the samples heated at $70,\;120\;and\;150^{\circ}C$ and decreased notably with increasing pressure at $200^{\circ}C$. Polymerization was found in the samples heated at $150\;and\;200^{\circ}C$ while a band which located below monomer(low-molecular) could be recognized. Molecular weight of the low-molecular was estimated to be about $6,000{\sim}9,000$ and no smaller peptide was recognized. The polymerization may have occured by disulfide crosslinking in the samples heated at $120^{\circ}C$ but other crosslinking may have played a role in those at $150\;and\;200^{\circ}C$.

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Spatial Distribution and Community Structure of Heterotrophic Protists in the Central Barents Sea of Arctic Ocean During Summer (북극해 하계 중앙 바렌츠해에서 종속영양 원생동물의 군집구조와 공간적 분포)

  • Yang, Eun-Jin;Choi, Joong-Ki;Kim, Sun-Young;Chung, Kyung-Ho;Shin, Hyoung-Chul;Kim, Yea-Dong
    • Ocean and Polar Research
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    • v.26 no.4
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    • pp.567-579
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    • 2004
  • To investigate the spatial distribution and community structure of heterotrophic protists, we collected water samples at 23 stations of central Barents Sea in August, 2003. This study area was divided into three area with physico-chemical and chi-a distribution characteristics: Area I of warm Atlantic water mass, Area III of cold Arctic water mass and Area II of mixed water mass. Chl-a concentration ranged from 0.18 to $1.04{\mu}g\;l^{-1}$ and was highest in Area I. The nano-sized chi-a accounted fur more than 80% of the total chi-a biomass in this study area. The contribution of nano-sized chi-a to total chi-a was higher in Area I than in Area II. Communities of heterotrophic protists were classified into three groups such as heterotrophic nanoflagellates (HNF), ciliates and heterotrophic dinoflagellates (HDF). During the study periods, carbon biomass of heterotrophic protists range from 11.3 to $38.7{\mu}gC\;l^{-1}$ (average $21.0{\mu}gC\;l^{-1}$), and were highest in Area I and were lowest in Area III. The biomass of ciliates ranged from 4.2 to $19.3{\mu}gC\;l^{-1}$ and contributed 31.5-66.9% (average 48.1%) to the biomass of heterotrophic protists. Ciliates to heterotrophic protists biomass accounted fur more than 50% in Area I. Heterotrophic dinoflagellates biomass ranged from 5.7 to $18.4{\mu}gC\;l^{-1}$ and contributed 27.1 to 56.3% (average 42.8%) of heterotrophic protists. Heterotrophic dinoflakellates to heterotrophic protists biomass accounted fur about 50% in Area III. Heterotrophic nanoflageltate biomass ranged from 0.5 to $3.4{\mu}gC\;l^{-1}$ and contributed 3.2 to 19.6% (average 9.2%) of heterotrophic protists. Heterotrophic nanoflagellates to heterotrophic protists biomass accounted fur more than 10% in Area III. These results indicate that the relative importance and structure of heterotrophic protists may vary according to water mass. Heterotrophic protists and phytoplankton biomass showed strong positive correlation in the study area The results suggest that heterotrophic protists are important consumers of phytoplankton, and protists might play a pivotal role in organic carbon cycling In the pelagic ecosystem of this study area during the study period.

Effects of Nutrient Levels and Feeding Regimen of a.m. and p.m. Diets on Laying Hen Performances and Feed Cost (산란계에 대한 오전용 사료와 오후용 사료의 영양수준 및 급여방법이 산란능력과 사료비에 미치는 영향)

  • 이규호;오용석
    • Korean Journal of Poultry Science
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    • v.29 no.3
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    • pp.195-204
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    • 2002
  • Two experiments were conducted to study the effects of nutrient level and feeding method of split diets for a.m. and p.m. on laying hen performance, feed cost and eggshell quality. In experiment 1, 384 ISA Brown layers of 30∼38wk of age were assigned to four treatments which comprise of three replicates each containing 32 birds. The control(C) was fed a conventional single diet throughout the day and split diet groups(T1, T2 and T3) were offered high energy/protein-low Ca diets, and low energy/protein-high Ca diets in a.m.(04:00∼15:00) and p.m.(15:00∼21:00), respectively. In the split diet groups, daily ME and CP consumption, and feed cost were significantly reduced(P<0.05) compared to the C, while the hen-day egg production, average egg weight and daily feed intake were not different among treatments. Due to the reduced daily ME and CP intakes and feed cost, the conversions of feed, ME, CP and feed cost required per day and per kg egg mass were also significantly improved(P<0.05) in the split diet groups. Eggshell qualities (egg specific gravity, egg breaking strength and eggshell thickness) were improved(P<0.05) by split diet feeding. As the Ca level of the p.m. diet increased. In Experiment 2, 384 ISA Brown layers of 50∼58 wk of age were used in three treatments and each treatment was represented by four replicates each containing 32 birds. The control(C) was fed a conventional single diet throughout the day and split diet group(T1) was offered high energy/protein-low Ca diets, and low energy/protein-high Ca diets in a.m.(04:00∼l5:00) and p.m.(15:00∼21:00), respectively. T2 group was fed the diet mixed (50:50) with the a.m. diets in mash and p.m. diet in pellet used T1 group. In T1 and T2 groups, daily feed intake and average egg weight were significantly reduced(P<0.05) compared to the C, while the hen-day egg production was not influenced by the feeding system. Daily ME and CP consumption, and feed cost were reduced(p.0.05), and the conversions of ME, CP and feed cost required per egg were also significantly improved(P<0.05) in T1 and T2, while the conversions of feed, ME, CP and feed cost required per kg egg mass were not different to the C. Eggshell qualities of T1 and T2 were improved(P<0.05) compared to the others. It was concluded the feed and nutrients consumption, feed cost per day or per kg egg mass could be reduced by introducing split diets for a.m. and p.m. and the feeding method of mixed diet of split diets were also convenient and effective for sparing feed cost and improvement of eggshell quality.

Aboveground Carbon Storage of Quercus acuta Stands by Thinning Intensity (붉가시나무 간벌강도에 따른 지상부 탄소고정량에 관한 연구)

  • Lee Sang-Tae;Son Yeong-Mo;Lee Kyung-Jae;Hwang Jaehong;Choi Jae-Chae;Shin Hyeon-Chul;Park Nam-Chang
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.4
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    • pp.282-288
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    • 2005
  • This study was carried out to estimate aboveground carbon contents associated with four years of thinning treatment of Quercus acuta stands in Wando Arboretum, Jeonnam. Stand thinning was conducted over four years using stand table projection for each thinning treatment. Ten sample trees were cut in the surveyed area. Estimation of aboveground biomass was made using the equation model $W=aD+bD^2$ where W is oven dry weight and D is DBH in cm. The total aboveground biomass for each intensity treatment area was : control (148.4 ton/ha), light (105.6 ton/ha), moderate (68.7 ton/ha) and heavy (39.1 ton/ha). Aboveground carbon storage for Quercus acuta stands was found by multiplying dry weigh t (ton/ha) by 0.5. Carbon storage and increment after four years was: control (74.2 tonC/ha), light (52.8 tonC/ha), moderate (34.3 tonC/ha) and heavy thinning intensity area (38.2tonC/ha).

Effect of Garlic on the Digestion of Beef Protein during Storage (쇠고기에 첨가한 마늘의 소화효과)

  • 류홍수;류홍수;이강호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.5
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    • pp.447-454
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    • 1991
  • Chopped garlic was added to beef to determine its effect on the protein digestion during storage and heat treatment. The digestibility of raw beef without garlic was not significantly changed during storage at $4^{\circ}C$, but increased as garlic added and aging time increased. The optimal aging time and amount of garlic added was varied with heating time. Trypsin inhibitor did not change the digestibility of beef due to its thermal inactivation. Gel chromatography revealed that the lower molecular weight peptides(2,200~6,150 dalton) were shown in beef-garlic mixture through aging and heating procedure. When aged beef with garlic was digested with four-enzyme system, the soluble portion was increased significantly in comparison with that from raw beef without garlic. Protein quality of beef, as measured by computed PER(C-PER), was improved from 2.14 of raw beef to 2.50 of aged beef with chopped garlic.

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Extraction of EPA and DHA from Tuna Oil Using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 참치유에서의 EPA 및 DHA 추출)

  • Yoon, Jung-Ro
    • Korean Journal of Food Science and Technology
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    • v.25 no.3
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    • pp.288-294
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    • 1993
  • Solubilities of urea-crystallized tuna oil methyl esters in supercritical carbon dioxide were determined by a flow through extraction reactor. Experimental results obtained under a quasi-equlibrium condition showed that at 150 bar, solubilities of the esters in supercritical $CO_2$ were 0.075, 0.028 and 0.006(w/w) at $40^{\circ}C,\;60^{\circ}C\;and\;80^{\circ}C$, respectively. In the pressure and temperature ranges $(100{\sim}200bar\;and\;40{\sim}80^{\circ}C)$, the solubility increased with the density of $CO_2$. However, selectivity of supercritical carbon dioxide on the extracted compounds was much better at low density than at high density. Supercritical fractionation with a temperature gradient $(50{\sim}75^{\circ}C)$ resulted in concentrates of EPA and DHA in purities of 12% and 85%, respectively.

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Application of a New Scaling Parameter to Chain Expansion in the Systems of Polystyrene/Mixed Solvents (폴리스티렌/혼합용매 계에서 사슬의 팽창에 대한 새로운 스케일링 파라미터의 적용)

  • Park, Il-Hyun;Lee, Dong-Il;Hwang, Mi-Ok;Yu, Young-Chol;Park, Ki-Sang
    • Polymer(Korea)
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    • v.31 no.2
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    • pp.98-104
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    • 2007
  • The expansion behavior of polystyrene (PS) chains with various molecular weights has been investigated above Flory $\Theta$temperature by viscometry after dissolving in the three different mixed solvents systems such as benzene/n-heptane, 1,4-dioxane/isopropanol, and 1,4-dioxane/n-heptane. Two different regimes are observed as increasing temperature: one regime is for the expansion of chain and the other is for the contraction. For the higher molecular weight sample of PS, the higher peak temperature showing its maximum expansion is obtained. Within a certain system of Ps/mixed solvents, the $\tau/\tau_c$ parameter shows universality for the variation of molecular weight. But while each system of Ps/mixed solvents has shown its own different slope, the universality breaks down in the overall system of mixed solvents. However after introducing a new empirical $b^{2/3}\tau/\tau_c$ parameter, all data points of three different systems have dropt on one master curve and the universality of chain expansion has recovered again. Here $\tau$ and $\tau_c$ are defined as $(T-\Theta)/\Theta$ and $(\Theta-T_c)/T_c$, respectively and $T_c$ is the critical solution temperature, and b of Schultz-Flory equation is corresponding to the effective slope in the plot of $1/T_c$ against $1/M_w^{1/2}$.