• Progress in Superconductivity
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• v.1 no.2
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• pp.85-88
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• 2000

The temperature dependent Josephson critical current $J_c(T)/J_c(0)$ between high $T_c$ superconductors along the a-axis is theoretically studied. The interface influence on the wave functions of quasi-particles is included in the theory within the framework of the two-dimensional t-J model. It is found that the experimental results can be satisfactorily explained by the present model with d wave pairing symmetry.

• Bulletin of the Korean Chemical Society
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• v.8 no.2
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• pp.115-118
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• 1987

The angular dependence of polarization of the A-band emission from RbCl:$Pb^{2+}$ is measured at 13.4 K to determine the symmetry axes of the $Pb^{2+}-v^-_c$ dipoles. The results indicate that these centers posess tetragonal symmetry. This implies that $v^-_c$ is situated in the next-nearest-neighbor (nnn) position to the $Pb^{2+}$ ion. The polarization ratio of the A-band emission measured at various temperatures is found to be independent of the temperature. The temperature independence of polarization confirms that, for the ion, the Jahn-Teller effect reduced by strong spin-orbit interaction does not give rise to thermal depolarization.

• Journal of the Korean Chemical Society
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• v.36 no.4
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• pp.536-539
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• 1992

Eight-membered ring spiro orthocarbonate (C$_{25}H_{20}O_4$, M$_r$ = 384) is monoclinic, space group C2/c, with a = 15.319(4), b = 9.057(3), c = 13.168(3)${\AA}$, ${\beta}$ = 98.53(3)$^{\circ}$, Z = 4, F(000) = 808, T = 290 K, ${\mu}$(Mo-K${\alpha}$) = 0.55 cm$_1$, D$_c$ = 1.36 g/cm$^3$ and D$_m$ = 1.40 g/cm$^3$. The intensity data were collected with Mo-K${\alpha}$ radiation (${\lambda}$ = 0.7107 ${\AA}$) on an automatic four-circle diffractometer with a graphite monochromater. The structure was solved by direct methods and refined by full matrix least-squares methods. The final R value was 0.052 for 1412 observed reflections. The molecule has C$_2$point symmetry. The eight-membered ring has a chair conformation with pseudo-C$_s$ symmetry. The naphthyl ring is planar with the C-C bond lengths being in the range of 1.352∼1.444${\AA}$ and bond angles of 117.2∼123.5$^{\circ}$. The bond lengths of C(1)-C(9), C(8)-C(9) and C(9)-C(10) are somewhat longer than those of the other C-C bonds.

• Bulletin of the Korean Chemical Society
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• v.22 no.7
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• pp.703-708
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• 2001

K2NiF4-type organic-based perovskites of the (C4H9NH3)2FexPb1-xCl4 (x=0.00, 0.25, 0.50, and 0.75) system have been synthesized using a low-temperatu re solution method under a flowing argon gas. When stoichiometric butylamine, iron chloride, and lead chloride are mixed, a yellow solution are obtained from slow cooling of 90 to -10 $^{\circ}C.$ The final product is a plate-like yellow crystal. The X-ray crystallographic analysis has been carried out using XRD in the range of $5^{\circ}{\leq}$ 2${\theta}$ ${\leq}80^{\circ}.$ The local symmetry around the absorbing Pb atom of the samples has been determined by the EXAFS spectroscopic study. The crystals assign to orthorhombic system by the XRD analysis. The FT-IR spectra are analyzed in the range of 600 to 3300 cm-1 . DSC and TGA are measured to detect thermal stability between 30 and 300 $^{\circ}C.$ Two endothermic peaks are detected in all samples. The electrical conductivity has been measured using the four-probes technique for the (C4H9NH3)2FexPb1-xCl4 system in 300-460 K. Photoluminescence phenomenon was also investigated at room-temperature.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.7 no.4
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• pp.21-27
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• 1998

In the case of existing in free-edge delaminations of composite laminates which are symmetry with respect to mid-plane in laminates also, in the case of asymmetry and anti-symmetry, the generalized quasi-three dimensional displacement field equations developed from quasi-three dimensional displacement field equations can be applied to solve above cases. We introduce three paramenters in this paper, which have not been used in quasi-three dimensional displacement field equations until now. To the laminate subjected to the axial extension strain $\varepsilon$0(C1) in $\chi$-direction, the bending deformation $\chi$$\chi$(C$_2$) around у-direction, the bending deformation w$\chi$(C$_4$) around z-direction and the twisting deformation $\chi$$\chi$y(C$_3$) around $\chi$-direction .The generalized quasi-three dimensional displacement field equations are able to be analyzed efectively.

• Bulletin of the Korean Chemical Society
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• v.30 no.1
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• pp.23-24
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• 2009

• Bulletin of the Korean Chemical Society
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• v.24 no.5
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• pp.605-609
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• 2003

The lower-order lithium organocyanocuprate compound, (THF)₃Li(NC)Cu($C_6$H₃-2,6-Mes₂) (1), and the bulky terphenyl Grignard reagent, Br(THF)₂Mg($C_6$H₃-2,6-Trip₂) (2), have been synthesized and structurally characterized both in the solid state by single crystal x-ray crystallography and in solution by multi-nuclear NMR and IR spectroscopy. The compound (1) was isolated as a monomeric contact ion-pair in which the C (organic ipso)-Cu-CN-Li atoms are coordinated linearly. The lithium has a tetrahedral geometry as a result of solvation by three THF molecules. The compound (1) is the first example of fully characterized monomeric lower order lithium organocyanocuprate. The bulky Grignard reagent (2) was also isolated as a monomer in which the magnesium, solvated by two THF molecules, has a distorted tetrahedral geometry. The crystals of (1) possess triclinic symmetry with the space group $P{\={1}}$, Z = 2, with a = 12.456(3) Å, b = 12.508(3) Å, c = 13.904(3) Å, α = 99.81°, β = 103.72(3)°, and γ = 119.44(3)°. The crystals (2) have a monoclinic symmetry of space group $P2_{1/C}$, Z = 4, with a = 13.071(3) Å, b = 14.967(3) Å, c = 22.070(4) Å, and β = 98.95(3)°.

• Journal of Photoscience
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• v.2 no.2
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• pp.95-98
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• 1995

The photodimers with cyclobutane rings and C$_2$ symmetry, derived from coumarin (syn, head to tail and anti, head to head) have been calculated by PM3-UHF-CI and Molecular Mechanics force field. The photocycloaddition to coumarin and 5,7-dimethoxycoumarin(DMC) dimers were deduced to be formed by their preferable frontier orbital interactions and via more stable cycloaddition by the C$_3$, C$_4$ bond. These results are consistent with the coumarin dimer model that the theoretical C$_4$-photocyclodimer of coumarin is predicted much more than the experimental C$_4$-photocyclodimer.

• Communications of the Korean Mathematical Society
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• v.38 no.4
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• pp.1271-1280
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• 2023

The object of the present paper is to introduce a type of non-flat Riemannian manifold, called a weakly cyclic generalized B-symmetric manifold (W CGBS)_n. We obtain a sufficient condition for a weakly cyclic generalized B-symmetric manifold to be a generalized quasi Einstein manifold. Next we consider conformally flat weakly cyclic generalized B-symmetric manifolds. Then we study Einstein (W CGBS)_n (n > 2). Finally, it is shown that the semi-symmetry and Weyl semi-symmetry are equivalent in such a manifold.

• The Bulletin of The Korean Astronomical Society
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• v.26 no.2
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• pp.34-34
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• 2001