• Journal of the Korean Magnetic Resonance Society
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• v.21 no.4
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• pp.139-144
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• 2017

Ni(II) containing coenzyme F430 catalyzes the reduction of $CO_2$ in methanogen. Macrocyclic Ni(II) complexes with N,O shiff bases have been received a great attention since metal ions play an important role in the catalysis of reduction. The reducing power of metal complexes are supposed to be dependent on oxidoreduction state of metal ion and structural properties of macrocyclic ring moiety that can enhance electrochemical properties in catalytic process. Six different ${\alpha}$-oximinoketone compounds, precursor of macrocyclic ligands used in $CO_2$ reduction coenzyme F430 model complexes, were synthesized with yields over 90% and characterized by NMR. The molecular geometries of ${\alpha}$-oximinoketone analogues were fully optimized at Beck's-three-parameter hybrid (B3LYP) method in density functional theory (DFT) method with $6-31+G^*$ basis set using the ab initio program. In order to understand molecular planarity and substitutional effects that may enhance reducing power of metal ion are studied by computing the structure-dependent $^{13}C$-NMR chemical shift and comparing with experimental results.

• Korean Journal of Materials Research
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• v.20 no.10
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• pp.508-512
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• 2010

The optimum route to fabricate nano-sized Fe-50 wt% Co and hydrogen-reduction behavior of calcined Fe-/Conitrate was investigated. The powder mixture of metal oxides was prepared by solution mixing and calcination of Fe-/Co-nitrate. A DTA-TG and microstructural analysis revealed that the nitrates mixture by the calcination at $300^{\circ}C$ for 2 h was changed to Fe-oxide/$Co_3O_4$ composite powders with an average particle size of 100 nm. The reduction behavior of the calcined powders was analyzed by DTA-TG in a hydrogen atmosphere. The composite powders of Fe-oxide and Co3O4 changed to a Fe-Co phase with an average particle size of 40 nm in the temperature range of $260-420^{\circ}C$. In the TG analysis, a two-step reduction process relating to the presence of Fe3O4 and a CoO phase as the intermediate phase was observed. The hydrogen-reduction kinetics of the Fe-oxide/Co3O4 composite powders was evaluated by the amount of peak shift with heating rates in TG. The activation energies for the reduction, estimated by the slope of the Kissinger plot, were 96 kJ/mol in the peak temperature range of $231-297^{\circ}C$ and 83 kJ/mol of $290-390^{\circ}C$, respectively. The reported activation energy of 70.4-94.4 kJ/mol for the reduction of Fe- and Co-oxides is in reasonable agreement with the measured value in this study.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.949-955
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• 2000

Numerical study with detailed chemistry has been conducted to investigate the NOx formation and structure in $CH_4/Air-CO_2$ counterflow diffusion flames. The importance of radiation effect is identified and the role of $CO_2$ addition is addressed to thermal and chemical reaction effects, which can be precisely specified through the introduction of an imaginary species. Also NO separation technique is utilized to distinguish the contribution of thermal and prompt NO formation mechanisms. The results are as follows : The radiation effect is dominant at low strain rates and it is intensified by $CO_2$ addition. Thermal effect mainly contributes to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. It is noted that flame structure is changed considerably due to the addition of $CO_2$ in such a manner that the path of methane oxidation prefers to take $CH_4 {\rightarrow}CH_3{\rightarrow}C_2H_6{\rightarrow}C_2H_5$ instead of $CH_4 {\rightarrow}CH_3{\rightarrow}CH_2{\rightarrow}CH$. At low strain rate(a=10) the reduction of thermal NO is dominant with respect to reduction rate, but that of prompt NO is dominant with respect to total amount.

• Journal of Hydrogen and New Energy
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• v.23 no.1
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• pp.83-92
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• 2012

Syngas combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using simulated syngas and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction conditions and no NO emission at oxidation conditions. Moreover, OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration with temperature. However, fuel conversion and $CO_2$ selectivity increased and CO emission decreased as pressure and gas residence time increased.

• KIEAE Journal
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• v.11 no.4
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• pp.87-94
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• 2011

This study was suggested to develop sustainable durability design system and proposed the plan to evaluate design conditions that meet the intended service life and $LCCO_{2}$ reduction level of reinforced concrete structure easily from the early design stage. For that the W/B and covering depth of the concrete structure were calculated through calculation of service life based on standard specification expression and the quantitative reduction rate of the vertical member of reinforced concrete structure by the calculated W/B was applied. Life cycle of building classified into construction stage, operation stage, maintenance stage, and demolition/disposal stage and the method of $CO_{2}$ evaluation of each stage was proposed. For construction stage, the major construction materials that take up over 80% $CO_{2}$ emitting during building construction were selected and the $CO_{2}$ evaluation method for 5 standard apartment houses was proposed. Also, for operation stage, $CO_{2}$ emission was calculated through calculation of heating load by energy efficiency rating certification system. For maintenance stage, $CO_{2}$ emission was calculated using concept of re-construction by life and for demolition/disposal stage was calculated with the use of construction standard estimate. As a result of the case study by such evaluation methods, 80 years of service life and 17 specifications of sustainable durability design that meet the 40% intended $LCCO_{2}$ reduction level were deduced. The Maximum $LCCO_{2}$ reduction rate was analyzed by 47.2%.

• Proceedings of the KSR Conference
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• 2011.05a
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• pp.1750-1756
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• 2011

After Kyoto Protocol was adopted for green gas reduction, each nations are stepping up efforts to reduce $CO_2$ of a typical green gas. Construction industry also is trying $CO_2$ reduction with the techniques of two types which are software and hardware techniques. The software technique are Passive Design considered green gas emission and the environment impact assessment by LCA. The hardware techniques are adjustment of equipment system and development of eco- friendly material. But, it is nonexistent that a study related to $CO_2$ emission considered detail process in construction industry. This study analyzed the relativeness of equipment combination and $CO_2$ emission by calculate $CO_2$ emission follow to equipment combination on earth-work which is the process emitted most $CO_2$ among railway bedding construction.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.821-824
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• 2009

LFG-MGT CHP system development project with $CO_2$ enrichment in greenhouses was introduced. LFG is produced from the anaerobic digestion of landfilled waste and it has been utilized for power/heat generation since it contains around 50% of $CH_4$. Utilization of LFG from small scale landfill is also needed as well as large scale landfill. However, due to economy of scale, it is very difficult to develop business model. In this context, combining CHP system with greenhouses is considered as feasible option for LFG utilization. LFG-MGT CHP system with $CO_2$ fixation in greenhouses has been derived as an active greenhouse gas reduction strategy, The focus of the system is beyond carbon neutral LFG utilization to neutral carbon absorption. The system is feasible in terms of direct and indirect $CO_2$ emission reduction with more economical way.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.35-36
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• 2018

According to the nation's greenhouse gas emission statistics, greenhouse gas emissions have been stiffly increasing. Accordingly, the importance of CO₂ reduction is more getting focused over the world. This trend makes the construction equipment be considered as a major target of reduction due to the large volume of emission. This study suggests the feasible methodology for estimating CO₂ emission from construction equipment and for being easily applied on the job sites. The methodology is based on the collection from the segmented CO₂ emission information of construction equipment. This study allows site personnels to estimate the total amount of CO₂ and to take appropriate actions for reasching the environmental regulations.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.4
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• pp.280-287
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• 2012

The sources of greenhouse gases (GHG) at Hanyang University Ansan campus, including direct sources, indirect sources, and others, were investigated in order to establish the GHG inventory. Emission of GHG was calculated with the energy use from each source from 2007 and 2009. The indirect emission (56.7%) due to the electricity significantly contributed to total GHG emission. The scenario for the GHG reduction was designed for both campus administration and members. The reduction potential of GHG was simulated from 2007 to 2020 using Long-range Energy Alternatives Planning (LEAP) model. In case of GHG reduction scenario by campus administration, the GHG can be reduced by 63.34 ton $CO_{2eq}/yr$ for stationary combustion in the direct source, by 221.1 ton $CO_{2eq}/yr$ for mobile combustion in the direct source, and by 4,637.34 ton $CO_{2eq}/yr$ for lighting in the indirect source, compared to 2020 Business As Usual (BAU). In case of GHG reduction action scenario by campus members, the reduction potential of GHG was 1293.76 ton $CO_{2eq}/yr$. Overall, the total GHG emissions in 2020 by the both scenarios can be decreased by 24% compared to 2020 BAU.

• Korean Journal of Materials Research
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• v.30 no.11
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• pp.581-588
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• 2020

Reducing CO₂ into high value fuels and chemicals is considered a great challenge in the 21st century. Efficiently activating CO₂ will lead to an important way to utilize it as a resource. This article reviews the latest progress of g-C₃N₄ based catalysts for CO₂ reduction. The different synthetic methods of g-C₃N₄ are briefly discussed. Article mainly introduces methods of g-C₃N₄ shape control, element doping, and use of oxide compounds to modify g-C₃N₄. Modified g-C₃N₄ has more reactive sites, which can significantly reduce the probability of photogenerated electron hole recombination and improve the performance of photocatalytic CO₂ reduction. Considering the literature, the hydrothermal method is widely used because of its simple equipment and process and easy control of reaction conditions. It is foreseeable that hydrothermal technology will continue to innovate and usher in a new period of development. Finally, the prospect of a future reduction of CO₂ by g-C₃N₄-based catalysts is predicted.