• Title/Summary/Keyword: $CO_2$ 주입

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The Pilot-scale Treatability Studies of Co-Composting for the Remediation of Diesel Contaminated Soil during the Winter (동절기 유류 오염토양 복원을 위한 Co-composting기술의 현장 적용성 연구)

  • 마정재;고형석;황종식;정민정;최상일;김국진
    • Journal of Korea Soil Environment Society
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    • v.4 no.2
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    • pp.193-201
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    • 1999
  • This study was conducted to check the applicability of pilot-scale co-composting for the remediation of diesel contaminated soil during the winter. Nutrients and microbes were added to enhance the efficiency of bioremediation and fermenting composts were also added to stimulate the microbial activities. As a result. the soil pile was kept at adequate temperature for the bioremediation during the test period of 30∼40 days and initial concentration(2,340mg TPH/kg dry soil) was reduced to 216mg TPH/kg dry soil (approximately 91% removal). During the initial 10∼30 days, it was found that the TPH concentration and the microbial population were rapidly reduced and increased. respectively. The co-composting technology studied can be effectively applied to remediate the diesel contaminated soil during the winter.

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A Study of Carbon Monoxide Oxidation on ZnO Single Crystal Surface (산화아연 단결정 면에서 일산화탄소의 산화반응에 대한 연구)

  • Jin Jun;Chong Soo Han
    • Journal of the Korean Chemical Society
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    • v.37 no.2
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    • pp.183-190
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    • 1993
  • The properties of oxidation reactions of carbon monoxide on ZnO (1010) were studied at the temperature range of 298∼573 K by measuring the capacitance and conductance in the insulating layer of two contacting crystal faces which vary with ZnO-gas interaction mechanisms. Exposure of the sample to CO resulted in an increase in the layer depth at 298∼373 K, while it decreased above 473 K. But the variation of the layer depth was very small in all measurements. When CO was admitted to the sample previously treated with $O_2$ at the same temperature, we observed the different features compared with the case of CO adsorption. From these results we discussed the mechanisms of CO oxidation in connection with the adsorbed oxygen species at each temperature.

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A Feasibility Study on Optimization System of Coagulant Dosing for Total Phosphorous Treatment (총인 처리를 위한 응집제 주입량 최적제어 시스템의 적용성 연구)

  • Seo, Jeong-Mi;Cho, Young-Beom;Choi, Ye-Mook;Park, Chul-Hwi
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.7
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    • pp.483-491
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    • 2014
  • In this study, we developed an M-COS (molit coagulant-dosing optimization system), which enables to apply the optimum coagulant dose determined in real time, in order to satisfy the total phosphorus (TP) regulation (0.5 mg/L), and then tested its field applicability. Field tests were conducted at three different periods in 2014 in a pilot plant where the M-COS was installed. Coagulant reduction rate by the M-COS was 10.4%, 15.3%, and 9.0% for each period (average 11.6%), when comparing with a control where coagulants were applied at a constant rate. Total cost for the M-COS or control was estimated by summing up the coagulant cost and sludge treatment cost, and then the resulting cost increase was predicted. Cost reduction rate by the M-COS was 13.8%, 20.0%, and 11.4% for each period (average 15.0%). This study indicates that the M-COS can be an alternative to a conventional system for TP treatment, with a better cost efficiency.

Development of Volume Modified Sorption Model and Prediction for Volumetric Strain of Coal Matrix (흡착에 의한 석탄암체의 부피변화가 고려된 흡착모델 개선 및 부피변형률 예측)

  • Kim, Sang-Jin;Sung, Won-Mo
    • Journal of the Korean Institute of Gas
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    • v.19 no.2
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    • pp.37-44
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    • 2015
  • We proposed the improved Langmuir adsorption relations considering volume change effect of coal matrix during primary production of CBM and Enhanced-CBM with injection of carbon dioxide or CCS in coalseam but also volumetric strain. To verify this model, experimental data of pure gas adsorption such as $CO_2$, $CH_4$, and $N_2$ on coals were used to compare conventional Langmuir model with this model. From the results, we obtained that the larger adsorption capacity of coal and the higher adsorption affinity of gas, the larger error occur with Langmuir model. Using this model, however, we found not only substantially better fit in all condition but also reasonable volumetric strain of the coal matrix. We also applied this volume modified pure gas adsorption model to the IAS model to describe gas adsorption and volumetric strain for mixed gas. This modified-IAS model fitting experimental data by Hall et al(1994) improved accuracy of mixed gas adsorption calculation compared with conventional model.

Study on a Carbon Dioxide Gasification for Wood Biomass using a Continuous Gasifier (연속식 가스화로를 이용한 목질계 바이오매스 이산화탄소 가스화 연구)

  • Park, Min Sung;Chang, Yu Woon;Jang, Yu Kyung;Chun, Young Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.10
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    • pp.704-710
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    • 2014
  • Biomass is considered an alternative energy which can solve an greenhouse gas problem like $CO_2$ which is a major contributor to global warming. The biomass can be converted to various energy sources through thermochemical conversion. In this study, a continuous gasifier was engineered for a wood biomass gasification. The biomass was used a waste wood. The experiments of $CO_2$ gasification were achieved as the gasification temperature, moisture content and input $CO_2$ concentration. The results showed that the yield of producer gas increased with an increasing the gasification temperature. The amount of the light tar increased due to the decomposition of gravimetric tar by the thermal cracking, and the char was confirmed pore development through the SEM analysis. The CO concentration was increased with an increased input $CO_2$ concentration from Boudouard reaction. Through the parametric screening studies, the hydrogen and carbon monoxide concentration were 32.91% and 48.33% at the optimal conditions of this test rig.

The Microcosm study for evaluating biobarrier application on sequential degradation of TCE products by Gasoline-Degradaing Mixed Culture

  • Lee, Jae-Sun;Lee, Si-Jin;Lee, Young-Kee;Chang, Soon-Woong
    • 한국생물공학회:학술대회논문집
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    • 2003.10a
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    • pp.440-444
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    • 2003
  • A new approach for ground water treatment combines a permeable Fe(0) barrier to breakdown higher chlorinated solvents like PCE and TCE with a down gradient aerobic biological treatment system to biotransform less chlorinated solvents, such as DCE and vinyl chloride (VC). The expected bacterial performance down gradient of an Fe(0) barrier was evaluated through laboratory batch experiments with a toluene-degrading mixed culture that cometabolically transforms cis-1,2-DCE and VC. The amount of cis-1,2-DCE (initially at 2,000 ppb) and VC (initially at 2,000 ppb) transformed was controlled by the initial toluene(20,000 ppb) concentration. VC was removed much more effectively than Cis-1,2-DCE, and a higher toluene concentration in comparison to the co-substrate concentrations was needed for complete co-substrate removal. Overall, the coupling of an Fe(0) barrier and subsequent biodegradation appears feasible for remediation of complex mixtures of chlorinated solvents and petroleum hydrocarbons in groundwater.

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Development of rapidly hardening seal material applicable to steel pipe multistage grouting (강관다단 그라우팅에 적용하는 속경성 실링재 개발)

  • Shin, Hyunkang;Jung, Hyuksang;Kim, Donghyun;Ryu, Yongsun;Kim, Donghoon
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.21 no.2
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    • pp.301-321
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    • 2019
  • The development of a rapidly hardening seal material applicable to steel pipe multistage grouting is described in this paper. In the multistage technique, seal materials are inserted to prevent the backflow of main grouting material. The grouting material must be inserted only after sufficient time has passed for the seal material to reach a gel state. Otherwise, the fluid seal material mixes with the main grouting material and a backflow of the grouting material occurs, thereby making its in situ insertion difficult. Furthermore, if the seal material remains in the gel state for too long a time, it solidifies; and the main grouting material will not be able to seep into the soil. The gel time, i.e., the time needed for the fluid seal material to turn into a gel state, determines the construction period of steel pipe multistage grouting. The gel time is one of the important factors in this technique, because it impacts the total tunnel construction period significantly. This study develops a rapidly hardening calcium aluminate material, which can reduce the gel time and shorten the construction period while retaining proper sealing function. It also presents a method to determine whether the seal material has reached the gel state as well as the quality standard and bleeding rate testing method for the seal material in the gel state.

Electrical properties of Ultra-Shallow Junction formed by using Epitaxial $CoSi_{2}$ Thin Film as Diffusion Source ($CoSi_{2}$ 에피박막을 확산원으로 이용하여 형성한 매우 얇은 접합의 전기적 특성)

  • Koo, Bon-Cheol;Shim, Hyun-Sang;Jung, Yun-Sil;Bae, Kyoo-Sik
    • Korean Journal of Materials Research
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    • v.8 no.5
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    • pp.470-473
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    • 1998
  • $As^+$ was ion-implanted onto $CoSi_{2}$ thin films formed by rapidly thermal-annealed Co/Ti bilayers. Then the specimens were drive-in annealed at 500~100$0^{\circ}C$ to form ultra-shallow $n^+$p junction diodes and to measure their 1- V characteristics. When drive-in annealed at 50$0^{\circ}C$ for 280 sec., 50 nm thick ultra-shallow junctions were formed and di¬odes showed the best 1- V characteristics with low leakage current. In particular. the leakage current was 2 orders lower than that of diodes formed by using Co monolayer. It was attributed to uniform $CoSi_{2}$/Si interfaces.

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A Study on the Reaction Characteristics of $CO_2$ Mineral Carbonation by Using Serpentine (Serpentine을 이용한 $CO_2$ 미네랄 탄산염화 반응 특성에 관한 연구)

  • 이대환;김형택;최병철;최봉국
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2003.05a
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    • pp.679-684
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    • 2003
  • 급속한 경제성장과 산업발달로 인해 국내외 에너지 소비량은 매년 크게 증가하고 있으며 이에 따라 화석연료의 사용도 증가하는 추세이다. 연소반응을 통한 화석연료의 사용은 GHG 중 가장 큰 요인인 $CO_2$를 배출한다. 따라서 막대한 양으로 배출되고 있는 $CO_2$ 발생을 억제하기 위하여 다양한 이산화탄소 고정화 기술이 연구 중에 있다. 그 중에서 경제성이 있고, 환경친화적이며 대량의 $CO_2$를 안정적이고 영구적으로 처리할 수 있는 기술로 주목되고 있는 연구가 광물질을 이용한 $CO_2$ 미네랄 Carbonation 처리기술에 대하여 반응특성을 고찰하였다. 대상 광물질로 Ca 보다 $CO_2$ 처리 시 친화적인 것으로 알려진 Mg가 많이 함유된 Silicate 계열의 사문석(Serpentine[Mg$_3$Si$_2$O$_{5}$(OH)$_4$])을 대상으로 Carbonation 반응특성을 실험을 통하여 고찰하였다. 실험은 TGA를 이용한 분석실험과 200cc 급 Autoclave를 이용한 $CO_2$의 직접주입실험을 수행하였다. TGA분석과 200cc 급 Autoclave를 이용한 실험을 통해서 Serpentine 의 경우 실험에서 정한 운전조건에서 $CO_2$와의 Carbonation 반응에 적합한 물질로 판단된다는 결론을 도출하였다.

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A Study on Characteristics of column fails in DDI DRAM (DDI DRAM에서의 Column 불량 특성에 관한 연구)

  • Chang, Sung-Keun;Kim, Youn-Jang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1581-1584
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    • 2008
  • In dual-polycide-gate structure with butting contact, net doping concentration of polysilicon was decreased due to overlap between $n^+$ and $p^+$ and lateral dopant diffusion in silicide/polysilicon layers. The generation of parasitic Schottky diode in butting contact region is attributed both to the $CoSi_2$-loss due to $CoSi_2$ agglomeration and to the decrease in net doping concentration of polysilicon layer. Parasitic Schottky diode reduces noise margin of sense amplifier in DDI DRAM, which causes column fail. The column fail could be reduced by physical isolation of $n^+/p^+$ polysilicon junction or suppressing $CoSi_2$ agglomeration by using nitrogen implantation into $p^+$ polysilicon before $CoSi_2$ formation.