• Journal of Conservation Science
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• v.31 no.4
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• pp.403-409
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• 2015

Malachite and Azurite are the typical copper system pigments which used the mural paintings since ancient times. The mural painting is at risk for damages of the painting layer by atmosphere gas because it is exposed at external environment. In this study, it did experiment about an effect to Malachite and Azurite by environmental pollution gas($NO_2$, $CO_2$, $SO_2$) then analysis and estimate about test for pieces using mural painting colored that two pigments. As a result, Malachite and Azurite were changed on $NO_2$ but not changed $CO_2$ and $SO_2$. Especially as the concentration of $NO_2$ is increased, exfoliation of the pigment layer weave remarkably formed pores on the pigment particles on SEM, the phenomenon to be pieces were observed together with smaller particles. In the case of Malachite that were exposed to $NO_2$ gas, new compounds(Rouaite : dicopper (nitrate(V) trihydroxide, $Cu_2(NO_3)(OH)_3$)) was appeared by XRD analysis. Therefore, there had been able to verify the fact that the cause exfoliation and discoloration phenomena accompanied by chemical changes for Malachite and Azurite.

• Journal of Animal Environmental Science
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• v.17 no.sup
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• pp.1-6
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• 2011

Korean Government announced 'The Roadmap to realize a low carbon green society on year 2020' on July 12, 2011 in order to mitigate greenhouse gas (GHG) emissions. Non-energy category of Food, Agriculture, Forestry and Fishery (FAFF) should mitigate 1,349 kilo $CO_2$-equivalent ($CO_2$-eq.) tonnes which is 7.1% of Business-As-Usual on year 2020. The mitigation from animal manure treatment system (AMTS) comprises ca. 45% of the total mitigated amount of Non-energy category of FAFF. Hence, the precise evaluation of GHG emissions from AMTS is important to find effective mitigation measures. Life cycle assessment was used to evaluate GHG emissions from AMTS. The most GHG emitter was a composting/liquid fertilizer/activated sludge system (1,649.45 kg $CO_2$-eq./head/year) and the least GHG emitter was a activated liquid fertilizer system (1,024.46 kg $CO_2$-eq./head/year). Thermophilic oxic process showed the highest ratio (34.9%) of GHG emissions by the use of electricity to total GHG emissions from systems. Energy efficiency should be considered to mitigate GHG emissions from AMTS.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.7 no.3
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• pp.465-472
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• 1997

An extension of new test methods for surfaces with an apparatus based on photon-induced desorption and ionisation in the electric field, is constructed and tested, It also investigates how to show the efficiency of the arrangement adsorbates $H_2$ and He on W(110). The field emitter temperature was 80 K. The wavelength of light used was 193 nm with field strengths between 10 and 50 V/nm. Many ion fragments($CO^+, He^+, H_2^^+, H_2O^+, W^{3+}\; and\; W^{2+}$) were produced by an electronic stimulation of the adsorbate with the help of a photon energy of 6.4 eV at He and $H_2$/W(110). A transient recorder enables the registration of the entire mass spectrum.

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.255-257
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• 2014

The installation of light oil facilities or delayed cokers seems to be inevitable in the oil refinery industry due to the heavy crude oil reserves and the increased use of light fuels as petroleum products. Petroleum coke is a byproduct of oil refineries and it has higher fixed carbon content, higher calorific value, and lower ash content than coal. However, its sulfur content and heavy metal content are higher than coal. In spite of disadvantages, petroleum coke might be one of promising resources due to gasification processes. The gasification of petroleum coke can improve economic value of oil refinery industries by handling cheap, toxic wastes in an environment-friendly way. In this study, $CO_2$ gasification reaction kinetics of petroleum coke, various coals and mixing coal with petroleum coke have investigated and been compared by using TGA. The kinetics of $CO_2$ gasification has been performed with petroleum coke, 3 kinds of bituminous coal [BENGALLA, White Haven, TALDINSKY], and 3 kinds of sub-bituminous coal [KPU, LG, MSJ] at various temperature[$1100-1400^{\circ}C$].

• Journal of Hydrogen and New Energy
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• v.26 no.1
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• pp.8-14
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• 2015

In this study, the model biomass was used for hydrogen production by supercritical water gasification (SCWG). Model biomasses were glycerol, glycine, lignin and cellulose. The feed concentration was set to 1 wt%. Experiments were conducted in a reactor at $440^{\circ}C$ and above 26.3 MPa for 30 min. The effects of catalysts such as alkali metal salt ($K_2CO_3$ and $Na_2CO_3$) and transition metal salts ($Ni(NO_3)_2$, $Fe(NO_3)_3$ and $Mn(NO_3)_2$) on the gasification were systematically investigated. No tar or coke was observed in all experiments. The results showed that the gasification efficiency increased with various catalysts. For the cellulose and glycerol, all catalysts were effective for the promoted $H_2$ production compared with no catalyst. The significant decrease of $H_2$ production compared with no catalyst was observed with $Na_2CO_3$ and $Fe(NO_3)_3$ for glycine and lignin. respectively. The highest H2 production, 1.24 mmol was obtained for glycerol-SCWG with $Mn(NO_3)_2$. Conclusively, the addition of $Mn(NO_3)_2$ enhanced all model biomass gasification efficiency and increased the hydrogen production promoting the supercritical water reaction.

• Clean Technology
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• v.19 no.2
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• pp.165-172
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• 2013

In this study, the hydrogen chloride removal using K-based dry sorbents ($K_2CO_3/Al_2O_3$, KEPRI, Korea) was studied with varying the pressure in a fixed bed reactor (15 cm tall bed with 0.5 cm I.d.). Working temperature was $400^{\circ}C$ and feed gas concentration was 750 ppm (HCl vol%, $N_2$ balance). The chloride sorption capacity of sorbent increases with increasing pressure (1, 5, 10, 15 and 20 bar). Also, after forming KCl crystal by reaction with $K_2CO_3$ and HCl, owing to the strong bonding energy, sorbent regeneration was practically impossible. Its optical, physical and chemical characterizations were evaluated by SEM, EDAX, BET, TGA and XRD. At $400^{\circ}C$ and 20 bar condition, working condition for the dehalogenation process after gasification, K-based dry sorbent showed high HCl sorption capacity and HCl/$N_2$ separation performances comparing with Ca-based and Mg-based dry sorbents.

• The Journal of Society for e-Business Studies
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• v.15 no.3
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• pp.163-181
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• 2010

As a part of efforts to reduce the global emissions of greenhouse gases, the Kyoto Protocol was signed by major developed countries ("Annex I" countries). According to the Kyoto protocol, the Emission Trading Scheme that derives a trading market of the $CO_2$ emission rights is appeared. It causes that business institutions give lots of efforts to reduce $CO_2$ by using new environmentally sound technologies or increasing efficiency in production. On the while there have been several studies trying to develop a methodology to measure the effect of $CO_2$ reduction and its monetary value. In this research we suggest ECRE (Evaluation of $CO_2$ Reduction in E-transformation) model which can measure the $CO_2$ reduction effect through the introduction of G2B system. ECRC model was developed based on the IPCC methodology. ECRC model measures the two major effects of the $CO_2$ reduction which are '$CO_2$ reduction effect from transportation' and '$CO_2$ reduction effect from the decrease of paper use'. In this paper, we calculate the economic effect of $CO_2$ reduction with the case of the G2B system in Korea. This research suggests a basic methodology to measure the $CO_2$ reduction performance for the e-transformed institution.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1185-1194
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• 2011

This study was carried out to estimate carbon emission using LCA (Life Cycle Assessment) and to establish LCI (Life Cycle inventory) DB for lettuce production system in protected cultivation. The results of data collection for establishing LCI DB showed that the amount of fertilizer input for 1 kg lettuce production was the highest. The amounts of organic and chemical fertilizer input for 1 kg lettuce production were 7.85E-01 kg and 4.42E-02 kg, respectively. Both inputs of fertilizer and energy accounted for the largest share. The amount of field emission for $CO_2$, $CH_4$ and $N_2O$ for 1 kg lettuce production was 3.23E-02 kg. The result of LCI analysis focused on GHG (Greenhouse gas) showed that the emission value to produce 1 kg of lettuce was 8.65E-01 kg $CO_2$. The emission values of $CH_4$ and $N_2O$ to produce 1 kg of lettuce were 8.59E-03 kg $CH_4$ and 2.90E-04 kg $N_2O$, respectively. Fertilizer production process contributed most to GHG emission. Whereas, the amount of emitted nitrous oxide was the most during lettuce cropping stage due to nitrogen fertilization. When GHG was calculated in $CO_2$-equivalents, the carbon footprint from GHG was 1.14E-+00 kg $CO_2$-eq. $kg^{-1}$. Here, $CO_2$ accounted for 76% of the total GHG emissions from lettuce production system. Methane and nitrous oxide held 16%, 8% of it, respectively. The results of LCIA (Life Cycle Impact assessment) showed that GWP (Global Warming Potential) and POCP (Photochemical Ozon Creation Potential) were 1.14E+00 kg $CO_2$-eq. $kg^{-1}$ and 9.45E-05 kg $C_2H_4$-eq. $kg^{-1}$, respectively. Fertilizer production is the greatest contributor to the environmental impact, followed by energy production and agricultural material production.

• Journal of Energy Engineering
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• v.4 no.3
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• pp.372-378
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• 1995

분류층 석탄가스 반응온도에서 slag의 배출 조건을 원활하게 유지하기 위하여 CaCO3를 flux로 사용한 용융특성을 파악하였다. 첨가에 의한 용융온도는 flux 주입량에 따라 감소하다가 증가하였다. 최저 용융온도의 범위는 ash중 CaO 농도기준 30-40%의 범위에서 나타났으며, Base/Acid ratio에 따라 최소 용융온도는 ash중 무기물간의 eutetic effect가 작용함을 알 수 있었다. 고온에서의 slag 조성은 ash의 조성과 비교시 알카리 산화물의 휘발화와 SO2의 감소를 보여주고 있으며, salg중 환원성 가스가 증가함에 따라 금속 산화물의 환원에 의해 SiO2 조성은 증가하였다. CaCO3를 혼합한 시료를 질소분위기하에서 조제하여 점도를 측정한 결과, low silica ash의 경우 낮은 점도치를 보여주나, 250 poise 이하의 범위에서 고화되는 현상이 발생하였다. high silica ash에서는 CaCO3 투입에 의해 slag 점도는 감소하였는데, slag 분석 결과 CaO가 산소 제공물질(oxide doner)로 작용하여 silicate의 응집현상을 억제하는 것으로 나타났다.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.71-72
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• 2012

The purpose of this study is not only fixation of carbon dioxide using the cement-Paste solution's calcium ion by wet carbonating reaction but also quantitatively evaluate the possibility of storage technology of Carbon dioxide. wet carbonation is reaction of CO₂ injection by CO₂ reactor. As a result of experiment, the carbon dioxide is fixed, and high-purity Calcium Carbonate is eluted.