• Title/Summary/Keyword: $CH{_5}^+$

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Study on the Biloflocculant by Bacillus meagaterium (Bacillus megaterium이 생산하는 응집제어에 관하여)

  • 김교창;정준영
    • The Korean Journal of Food And Nutrition
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    • v.11 no.6
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    • pp.622-628
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    • 1998
  • Microorganisms isolated from soil were tested for their flocculating activity in kaolin suspension, Identification of the best producing CH-23 strain showed that the strain belonged to the Bacillus megaterium. The maximum production of the flocculating from Bacillus megaterium CH-23 was observed in the culture medium containing 2% sucrose, 3% NaNo3, 0.1% K2HPO4, 0.5% NaCl, 0.5% MgSO4.7H2O and 0.01% tryptone at initial pH 7.0 and 25~3$0^{\circ}C$. Flocculating activity was improved to 57% when the culture medium contained Mn2+(0.01% MnSo4). In the culture medium containing Mg2+(0.01% MgSO4.7H2O) and Ca2+(0.01% CaCO3), flocculating activity were reached to 48% and 33%, respectively.

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Near-IR Spectral Features of Haze Particles in the Atmosphere of Titan

  • Kim, Sang Joon
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.1
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    • pp.62.1-62.1
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    • 2013
  • The Cassini/Visual Infrared Mapping Spectrometer (VIMS) observed the sun through the atmosphere of Titan, and provided vertically-resolved 63 spectra from 49 km to 987 km for the 1 - 5 micron range (Bellucci, 2008). Bellucci et al. (2009) analyzed selected spectral ranges where the band absorptions of $CH_4$ and CO are strong by constructing synthetic spectra including $CH_4$ and CO lines, but without including haze absorptions in their synthetic spectra. Kim et al. (2011) and Sim et al. (2013) were able to extract detailed spectral features of fundamental (Dv = 1) and overtone (Dv = 2) bands of the haze from the VIMS spectra by excluding the adjacent influences of strong $CH_4$ absorptions using a radiative transfer program, which includes effects of absorption and emission of lines of these molecules, and absorption and scattering of haze particles. In this presentation, we extend our detailed analyses to other remaining wavelengths in order to provide the spectral characteristics of the Titanian haze for the entire 1 - 5 micron range and to identify any additional haze spectral features and an unidentified feature near 4.3 microns reported by Bellucci et al. (2009).

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TEXES자료를 이용한 목성 극지방의 분광선 연구

  • Seo, Haeng-Ja;Kim, Sang-Jun;Greathouse, Thomas K.;Park, Su-Jong
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.43.2-43.2
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    • 2011
  • 목성 극지방의 분광 관측 자료에는 $H_3+$, $H_2$, 탄화수소 분자들($CH_4,C_2H_2,C_2H_6$)이 방출선의 형태로 나타난다. 이 분자선들은 2 ~ 3 mm에서는 대부분 관측이 이루어졌지만, 7.8 mm 파장대에서는 탄화수소 분자들 중에서 $CH_4$가 hotspot 형태로 관측이 되었다. 본 연구에서는 마우나케아 천문대의 NASA IRTF (InfraRed Telescope Facility) 망원경 중에 중적외선 고분산 분광기 TEXES (Texas Echelon Cross Echelle Spectrograph)를 설치하여 $CH_4$와 함께 처음 발견된 $C_2H_2$의 특성을 분석하였다. 텍사스 주립대학에서 개발한 TEXES는 5 ~ 25 mm의 관측 파장대에서 저분산(R~3,000), 중 분산(R~15,000), 고분산(R~100,000)으로 관측할 수 있다 (Lacy et al., 2002). 본 연구에 사용된 자료는 2009년 5월 29일에 관측되었으며, 파장대는 7.8 mm 이다.

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The Studies on Substituent and Kinetic Solvent Isotope Effect in Solvolyses of Phenyl Chloroformates

  • 구인선;이지선;양기열;강금덕;이익춘
    • Bulletin of the Korean Chemical Society
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    • v.20 no.5
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    • pp.573-576
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    • 1999
  • The rate constants and kinetic solvent isotope effects (KSIE, KMeOH/kMeOD) for solvolyses of para-substituted phenylchloroformates in CH3OH, CH3OD, H2O, D2O, 50% D2O-CH3OD were determined at 15.0 and 25.0℃ using conductometric method. Kinetic solvent isotope effects for the solvolyses of para-substituted phenyl chloroformates were 2.39-2.51, 2.21-2.28, and 1.67-1.69 for methanol, 50% aqueous methanol, and water, respectively. The slopes of Hammett plot for solvolysis of para-substituted phenyl chloroformates in methanol, 50% aqueous methanol, and water were 1.49, 1.17 and 0.89, respectively. The Hammett type plot of KSIE, log (KSIE) versus p, can be a useful mechanistic tool for solvolytic reactions. The slopes of such straight lines for para-substituted phenyl chloroformates are almost zero in methanol, 50% aqueous methanol, and water. It was shown that the reaction proceeds via an associative SN2 and/or general base catalysis addition-elimination (SAN) mechanism based on activation parameters, Hammett p values, and slopes of Hammett type plot of KS-IE.

Clinical genetics of defects in thyroid hormone synthesis

  • Kwak, Min Jung
    • Annals of Pediatric Endocrinology and Metabolism
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    • v.23 no.4
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    • pp.169-175
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    • 2018
  • Thyroid dyshormonogenesis is characterized by impairment in one of the several stages of thyroid hormone synthesis and accounts for 10%-15% of congenital hypothyroidism (CH). Seven genes are known to be associated with thyroid dyshormonogenesis: SLC5A5 (NIS), SCL26A4 (PDS), TG, TPO, DUOX2, DUOXA2, and IYD (DHEAL1). Depending on the underlying mechanism, CH can be permanent or transient. Inheritance is usually autosomal recessive, but there are also cases of autosomal dominant inheritance. In this review, we describe the molecular basis, clinical presentation, and genetic diagnosis of CH due to thyroid dyshormonogenesis, with an emphasis on the benefits of targeted exome sequencing as an updated diagnostic approach.

Theoretical Studies on the Base-Catalyzed Deprotonation of 4-Phenacylpyridinium Cations

  • 김왕기;전영이;손창국;김창곤;이익준
    • Bulletin of the Korean Chemical Society
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    • v.18 no.2
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    • pp.193-197
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    • 1997
  • Theoretical studies on the base-catalyzed deprotonation of 4-phenacylpyridinium cations, R1-CO-CH2-C5H4N-R2, I (R1=YC6H4 -and R2=CH3), and II (R1=C6H5 and R2=CH2C6H4Y) have been carried out with bases, NH3 and XC6H4NH2 using AM1 MO method. The Brψnsted α values are 0.20 and 0.22 and the βB values are 0.62 and 0.61, respectively for cations I and II. The negative Ⅰ (=α-βB) values obtained are in accord with the experimental results in aqueous solution, although the theoretical gas-phase α values for I are somewhat smaller than the experimental values in water due to neglect of solvation effect. It has been stressed that the Brψnsted α is distorted not only by the lag in the resonance and solvation development in the carbanion, but also by the difference in the distance between the anionic center and substituents in the TS and in the product anion.

Fumarate Reductase-Producing Enterococci Reduce Methane Production in Rumen Fermentation In Vitro

  • Kim, Seon-Ho;Mamuad, Lovelia L.;Kim, Dong-Woon;Kim, Soo-Ki;Lee, Sang-Suk
    • Journal of Microbiology and Biotechnology
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    • v.26 no.3
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    • pp.558-566
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    • 2016
  • Biotic agents such as fumarate-reducing bacteria can be used for controlling methane (CH4) production in the rumen. Fumarate-reducing bacteria convert fumarate to succinate by fumarate reductase, ultimately leading to the production of propionate. Fumarate-reducing bacteria in the genus Enterococcus were isolated from rumen fluid samples from slaughtered Korean native goats. The enterococci were identified as Enterococcus faecalis SROD5 and E. faecium SROD by phylogenetic analyses of 16S rRNA gene sequences. The fumarate reductase activities of the SROD5 and SROD strains were 42.13 and 37.05 mM NADH oxidized/min/mg of cellular nitrogen (N), respectively. Supplementation of rumen fermentation in vitro with the SROD5 and SROD strains produced significantly higher propionate, butyrate, and total volatile fatty acid (VFA) concentrations than controls at 12 h; VFA concentrations tended to increase after 24 h of incubation. The generated CH4 concentration was significantly lower in the SROD5 and SROD treatment groups after 24 h of incubation. These findings indicate that E. faecium SROD has potential as a direct-fed microbial additive for increasing total VFAs while decreasing CH4 production in rumen fermentation in vitro.

Characteristics of Incheon Aerosol during Asian Dust Period in 2004 using Optical Particle Counter (OPC) (광학적 입자계수기를 이용한 2004년 황사기간 인천지역 에어로졸 특성)

  • Jung Chang-Hoon;Cho Yong-Sung;Lee Jong-Tae
    • Journal of Environmental Science International
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    • v.14 no.6
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    • pp.565-575
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    • 2005
  • The characteristics for the aerosol number distribution was studied during spring, 2004 in Incheon. Optical Particle Counter (OPC, HIAC/ROYCO 5230) was used in order to measure the number concentration of aerosol in the range of $0.3\~25{\mu}m.$. The obtained results were compared with $PM_{2.5}\;and\;PM_{10}$ data during Asian dust events. The results show that the size resolved aerosol number concentration from OPC measurement has a similar tendency with $PM_{10}\;and\;PM_{2.5}$ mass concentration. During Asian dust periods, the number concentrations in large particle $(CH5\~CH8)$ increase more than small particles which diameter is less than $2.23{\mu}m(CH5)$ and the same results were shown when $PM_{10}$ was compared with $PM_{2.5}$ data compared with non-dust days, Consequently, this study shows that size resolved aerosol number concentration from OPC measurement can be used as a useful tool in comparison of mass concentration data.

A Study on Performance and Simultaneous Reduction of Smoke and NOx Emission by an DMM Addition and Application of EGR Method in a Diesel Engine (디젤기관에세 DMM 첨가와 EGR 방법 적용에 의한 기관성능 및 매연과 NOx의 동시저감 연구)

  • Oh Young-Taig;Choi Seung-Hun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.3 s.246
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    • pp.208-214
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    • 2006
  • Dimethoxy methane$(CH_3-O-CH_2-O-CH_3)$, also known as methylal or DMM, is an oxygenated additive that contains 42.5% oxygen by weight and is soluble in diesel fuel. It is a colorless liquid and a gas-to-liquid chemical 방tat has been evaluated for use as a diesel fuel component. Experiments were conducted by using the five blends with different volumetric percentage of DMM(2.5, 5, 7.5, 10, and 12.5%) in baseline diesel fuel. The test engine was single cylinder, four stroke, DI diesel engine unmodified. Also, data was collected for steady state operation at 24 engine speed-load conditions. The focus of this study was to investigate the effects of the addition of oxygenated fuel to diesel fuel on the engine-out emissions and the performance. Smoke emissions of all DMM blends were reduced substantially in comparison with conventional diesel fuel. These results indicate that DMM may be an effective blendstock for diesel fuel as an environment-friendly alternative fuel. Besides, this study showed that simultaneous reduction of smoke and NOx emissions could be achieved by oxygenated fuel and EGR method that was applied to decrease NOx emissions increasing with smoke emissions reduction.

Characterization of the drug receptors responsible for intestinal contraction in Israeli carp (이스라엘잉어 장관 수축에 관여하는 약물수용체에 관한 연구)

  • Yun, Hyo-in;Han, Kyong-oh;Park, Seung-chun;Cho, Joon-hyoung;Oh, Tae-kwang
    • Korean Journal of Veterinary Research
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    • v.34 no.3
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    • pp.447-456
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    • 1994
  • In order to elucidate the characterization of receptors involved in inestinal motility of Israeli carp, spontaneously contracting Israeli carp intestinal preperations were prepared and mounted in the organ chambers for contraction traicings using a polygraph. Various contractile agonists were treated and their dose-response curves were constructed. $EC_{50}$ values$(pD_2)$ of each agonist on specific receptors, $pA_2$ values of competitive antagonists against some agonists, and $K_1$, values of noncompetitive antagonists against some agonists were analyzed for characterization of receptors related with the intestinal contraction. Results obtained through the experiments were summarized as follows: 1. Acetylcholine(ACh) exhibited biphasic dose-response curves: initial ACh-induced dose dependent contractions were observed in pM levels but followed by decreased response in in-between concentration levels. Dose dependent contractions reappeared in ${\mu}M$ level. The peaks in pM and ${\mu}M$ levels appeared in $10^{-13}M$ and $3{\times}10^{-5}M$, respectvely. 2. Carbachol(CaCh) exhibited dose dependent contractions from $10^{-9}M$ to $10^{-5}M$, and its $pD_2$ values were higher than those of ACh($5.60{\pm}0.11$). ACh and CaCh exhibited equiactive contractions. Nicotine had no effects on contractile responses of Israeli carp intestine. 3. ACh-induced responses were inhibited by atropine($K_1:7{\times}10^{-8}M$), a muscarinic antagonist, in a non-competitive manner. But CaCh-induced responses were inhibited by both antimuscarinic atropine($pA_2:9.52{\pm}0.14$) and selective $M_2$ antagonistic 4-DAMP($pA_2:8.16{\pm}0.09$), in competitive manners. Nicotine receptor antagonistic decamethonium and hexamethonium had no effects on ACh-and CaCh-induced contractions. Therefore, the cholinergic receptor related to intestinal motility of Israeli carp was assumed as $M_2$ type. 4. In Israeli carp intestine, 5-HT (serotonin) exhibited dose dependent contractions in concentration range from $10^{-8}M$ to $10^{-5}M$. The maximal responses, however, were corresponded to about 50% of those of ACh or CaCh. 5-HT induced contractions were inhibited by $5-HT_2$ antagonistic ketanserin ($K_1: 7.8{\times}10^{-4}M$) in a non-competitive manner, but not by both of anti $5-HT_1$, spiperone and anti $5-HT_3$, MDL-72222. Hence, $5-HT_2$ receptors are suggested to be existed in Isreli carp intestine.

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