• 한국재료학회지
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• 제3권3호
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• pp.207-214
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• 1993

$Li_2O-Al_2O_3-SiO_3$계 결정화유리의 저온합성을 위하여 출방원료로서 각 해당 금속 알콕시드를 사용하였다. 알코올을 용매로 충분히 첨가하고, drying control chemical additive로 dimethy1 formamide를 적당량 첨가한 혼합용용액을 과잉의 물로 충분히 가수분해시킨 습윤겔을 저온으로 건고하여 균열이 없는 건조된 monolith겔을 합성하였다. 건조겔로부터 750-$950^{\circ}C$로 10시간 이상 소결하여 저열팽창성을 나타내는 ${\beta}$-eucrypytite(${\beta}$-quartz 고용체), $Li_2O\cdot Al_2O_3\cdot 3SiO_2$및 ${\beta}$-spodumene등의결정상을 석출시켰다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2007년도 제34회 KOSCO SYMPOSIUM 논문집
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• pp.37-44
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• 2007

A nickel foam, one of metal foams was seleced as a catalyst support instead of conventional ceramic materials. $Al_2O_3$ was coated on the surface of nickel foam to increase the surface area. $Al_2O_3$ coating process was based on sol-gel process. SEM image was obtained and $Al_2O_3$ coverage was confirmed. Combustion experiments were carried out using SUS combustor and $H_2$/air mixture. Temperatures were measured with different equivalence ratios and $H_2$ flow rates. $H_2$ conversion rates were calculated by the analysis of product gas using gas chromatography. Catalytic combustion of $H_2$ was complete and stable with Pt/$Al_2O_3$ coated nickel foam and influences of water vapor were confirmed during the beginning of combustion.

• 한국재료학회지
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• 제10권3호
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• pp.233-240
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• 2000

소결 촉진제 첨가없이 치밀한 코디어라이트 세라믹스를 얻기 위해 Mg-Al-Si계의 열적거동을 검토하였다. 수용액 매체에서 코디어라이트 현탁액의 분산안정성을 ESA를 이용하여 조사하였으며, 코디어라이트 졸의 응집 방지와 분산성을 부여하기 위해 2N $HNO_3$와 2N $NH_4OH$ 용액으로 pH 1.03과 pH 8.30로 조절하였다. pH 8.30인 코디어라이트 졸을 $150^{\circ}C$에서 12시간 건조한 시료에서 magnesium-aluminum-silicate 복합 겔이 존재하였다. 평형상태의 코디어라이트 겔의 결정화는 $1300^{\circ}C$ 이상의 소결 온도에서 존재하였으며, $1300^{\circ}C$ 이하의 조건에서는 ${\mu}-cordierite(Mg_2Al_4Si_5O_18)$, spine($MgAl_2O_4$) 및 mullite($Al_6Si_2O_{13}$)와 같은 다양한 준안정상이 복합적으로 혼재하였다. pH 1.03과 pH 8.30로 조절된 현탁액에서 코디어라이트 겔의 핵반응은 유사하게 일어났으나, 치말화거동은 졸의 pH에 상당한 차이를 보였다. pH 1.03인 졸 보다 pH 8.30인 졸의 치밀화가 더욱 진전되었다.

• 한국세라믹학회지
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• 제34권11호
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• pp.1187-1197
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• 1997

Dry gel composed of primary particles more homogeneous than starting boehmite powder was prepared by dispersing and gelling the boehmite powder. The transformation temperatures of boehmite powder, dry gel seeded with 0, 1, 3, 5 wt% $\alpha$-Al2O3, and ball milled gel were 1192$^{\circ}C$, 1184$^{\circ}C$, 1141$^{\circ}C$, 1119$^{\circ}C$, 1117$^{\circ}C$, and 1106$^{\circ}C$, respectively. Sintering behavior of dry gel without seed was similar to that of boehmite powder, but the sintered density of dry gel was improved as much as 10%~15% than boehmite powder. In the case of dry gel seeded with 5 wt% $\alpha$-Al2O3, sintering behavior was much improved. The relative density of the gel seeded with 5 wt% $\alpha$-Al2O3 was 96% when sintered at 140$0^{\circ}C$ for 1h. On the other hand, ball milling of the non-seeded sol for 48h resulted in the relative density of 97% when sintered at 130$0^{\circ}C$ for 1h. The size and amount of $\alpha$-Al2O3 particles added by ball milling were 0.107 ${\mu}{\textrm}{m}$ and 0.5 wt%.

• 한국세라믹학회지
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• 제28권5호
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• pp.399-405
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• 1991

Mullite-PSZ powders were synthesized by the sol-gel process using Al(sec-OC4H9)3, Si(OC2H5)4, ZrOCl2$.$8H2O and YCl3 solution and the characteristics of synthesized powders were studied. The sinterability and mechanical properties of powder compacts sintered at 1670$^{\circ}C$ for 4hr were also studied for various PSZ contents. ${\gamma}$-Al2O3(Al-Si spinel) formed at 980$^{\circ}C$ from amorphous dried gel, and mullite as well as ZrO2 formed above 1200$^{\circ}C$. At the room temperature, ZrO2 was a mixture of tetragonal and monoclinic phases. The specimens were densified to 97∼98% except the specimen containing 25 vol% PSZ which showed the relative density of 94%. The K1c value increased with the PSZ content and showed a maximum value of 4.1 MN/m3/2 at 25 vol% PSZ; this value was about 50% higher than that of the mullite without PSZ. Flexural strength had a maximum value of 280 Mn/㎡ at 20 vol% PSZ. In contrast, at 25 vol%, the flexural strength was even lower than that of the mullite possibly due to higher porosity of 6%.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.424-424
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• 2013

Ce3+, Sm3+, Eu3+, Tb3+ 등 희토류를 도핑한 여러 종류의 형광체는 백색 LED (white light-emitting diode), 전계방출표시소자(field emission display), 플라즈마디스플레이패널(plasma display panel), 약물 운송(drug delivery) 등 다양한 분야에서 응용되고 있다. 최근에는 졸-겔 방법(sol-gel method)을 이용하여Y2SiO5, Y3-XGdxAl5O12, SrAl2O4 등 여러 종류의 호스트 물질을 합성하여 형광체의 특성을 분석하는 연구가 활발히 진행되고 있다. 이러한 졸-겔 방법은 비교적 낮은 온도에서 간단한 공정으로 좋은 균질성과 높은 생산성을 갖도록 형광체를 제작할 수 있는 장점을 가지고 있다. 이에 본 연구에서는 졸-겔 방법을 이용하여 BaGd2TiO13구조를 제작하였고, 이러한 구조적, 광학적 특성을 분석하기 위하여 열분석기(thermal analyzer), 전계방출형주사전자현미경(field emission scanning electron microscopy), 투과전자현미경(field emission transmission electron microscopy)을 이용하였다. 이러한 졸-겔 방법을 이용하여 제작한 BaGd2TiO13 구조의 형광체 적용 연구를 통한 디스플레이 및 백색 LED 응용에 유용할 것으로 기대된다.

• Bulletin of the Korean Chemical Society
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• 제28권4호
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• pp.647-651
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• 2007

In order to investigate the excited-state intramolecular proton transfer (ESIPT) process of dihydroxyanthraquinones (DHAQ; 1,5-DHAQ and 1,8-DHAQ) in organic-inorganic hybrid matrices, transparent SiO2, SiO2- Al2O3, and Al2O3 matrices chemically bonded with DHAQ were prepared using a sol-gel technique. The absorption maxima of 1,5- and 1,8-DHAQ in SiO2 matrices are observed at around 420 nm, whereas those of DHAQ in both SiO2-Al2O3 and Al2O3 matrices are markedly shifted to longer wavelength compared with those in SiO2 matrix. This indicates that DAHQ forms a chemical bond with an Al atom of Al2O3. The DHAQ in SiO2 matrix shows a markedly Stokes-shifted emission which is originated from the ESIPT in DHAQ. Based on the emission lifetimes of DHAQ, the ESIPT of DHAQ was found to be strongly affected by the chemical interaction with Al atom in the Al2O3-related matrices.

• 한국응용과학기술학회지
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• 제23권3호
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• pp.243-251
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• 2006

Field emission display(FED) is actively investigated in view of the development of full color flat-panel display, which can replace some cathode-ray tube(CRT). Thus, the development of new phosphors appropriate for FED is urgently needed and has been actively investigated. In this work, $SrTiO_3:Pr^{3+}$ phosphor was prepared by sol-gel method and the coating was applied by sol-gel method combined with sonication on these phosphor's surface into diluted precursor solution. It was found that very fine particles of coating material were formed on phosphor's surface. The luminescent intensity of $SrTiO_3:Pr^{3+}$ phosphor coated with $SiO_2$ and $Al_2O_3$ was considerably increased without any noticeable change in color chromaticity. The optimum concentration of coating material was found to be 1wt% and the optimum pH value of the solution was 10.

• 한국세라믹학회지
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• 제30권8호
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• pp.651-656
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• 1993

Granulated Y-TZP powders were coated by using Sol-Gel method and the coating effect of Al2O3 on the isothermal phase transformation in Al2O3 coated Y-TZP powders was investigated. During aging, tetragonal phase in Y-TZP powder were isothermally transformed to monoclinic, but the tetragonal phase in Al2O3 coated Y-TZP powders was continuously retained in spite of long aging. It can be considered that the improvement of thermal stability of tetragonal phase in Al2O3 coated Y-TZP powders may be due to the increase of constraint effect near tetragonal phase, and the suppression of surface transformation by obstructing the reaction between the surface of Y-TZP and H2O.

• 한국수소및신에너지학회논문집
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• 제19권3호
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• pp.226-231
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• 2008

Cu/Fe/$Al_2O_3$ granules with various sizes have been prepared by a combination of sol-gel and oil drop method for the use in sulfur trioxide decomposition, a subcycle in thermochemical sulfur-iodine cycle to split water in the hydrogen and oxygen. The size of composite granules have been mainly changed by the flow-rate of the gel mixture before dropping in the synthesis. The structural properties of the samples were comparable with granule size. In the reaction, the catalytic activity was enhanced by decreasing size in the entire reaction temperature ranges.