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A Study on the Development of Orchard Crop Security Equipment -Bark Remover of Apple Trees- (과수 관리기 개발에 관한 연구 -과수 박피기-)

  • Kim, T.H.;Jang, I.J.;Lee, J.T.
    • Journal of Biosystems Engineering
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    • v.19 no.4
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    • pp.311-317
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    • 1994
  • Warts and barks of apple trees were vector of White rot. Two devices removing warts and barks for the use of pest control on apple trees were developed and evaluated in this study, and their results are as follows ; 1. A total of 148 warts were examined to determine the average size. About 35 percent of the examined warts were 6~8mm long, 4~8mm wide and 4~6mm thick in size. About 30 percent of the examined warts were 4~6mm long, 2~4mm wide and 6~8mm thick in size. 2. Seventy-one percent of the examined barks removed were 4~8mm in thickness. 3. A blade with 30 degree of cutting angle required 3 to 22 percent less cutting energy than those with 15 and 45 degrees of cutting angles. 4. The cutting torque decreased from 31 N-cm to 12 N-cm with an increase of cutting speed from 26cm/s to 104cm/s for a feeding speed of 0.31 mm/s with the blade angle of 30 degrees. 5. The cutting torque increased from 6N-cm to 32N-cm with an increase of branch diameter from 6mm to 14mm for a feeding speed of 0.31 mm/s with the blade angle of 30 degrees. 6. Two devices mounted on a mower for removing warts and barks were evaluated and proved effective.

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Morecular Orbital Caculations for the Reactions of 2,5-dimethyl Pyrrole with Phenylsulfonyl Chloride

  • 서미경;김진범;성시열;심영기
    • Bulletin of the Korean Chemical Society
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    • v.20 no.8
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    • pp.948-952
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    • 1999
  • Electrophilic substitutions on β-position of 2,5-dimethyl pyrrole have been investigated theoretically. The electron donating methyl groups enrich electron densities on C-3, C-4 positions and π* interactions with methyl groups substituted on C-2 and C-5 positions pushed up the HOMO level of the pyrroles consequently induce rapid substitutions on C-3, C-4 sites. Substitution of phenylsulfonyl group on nitrogen stabilized LUMO levels through weak π bonding interactions. Unexpected deoxidation reaction underwent on the sulfonyl group substituted at C-3 position. The structures were solved by X-ray crystallography. Meanwhile, gas phase HF/6-31G* and density functional method (B3LYP/6-31G*) calculations gave favorable energies for 1-phenylsulfinyl pyrrole (6) over 3-phenylsulfinyl pyrrole (5) by 3.6-4.7 kcal/mol which is contrary to the experimental result. However the methods involve the effects of molecular polarizability and solvent, molecular dynamics (MD) and ab-initio self consistent reaction field (SCRF) calculations showed same trend as experiments. According to MD calculations, compound 5 is more stable than compound 6 by 4.15 kcal/mol and the SCRF, HF/6-31G* calculations gave more stable energy value for structure 5 than 6 by 0.03 kcal/mol.

Studies on the Biological Activities and Physicochemical Characteristics of Pigments Extracted from Korean Purple-Fleshed Potato (한국산 유색감자 색소의 이화학적 특성 및 생리 활성에 관한 연구)

  • Jeon, Tae-Woog;Cho, Yong-Sik;Lee, Sung-Hyeon;Cho, Soo-Muk;Cho, Hyeon-Mook;Chang, Kyu-Seob;Park, Hong-Ju
    • Korean Journal of Food Science and Technology
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    • v.37 no.2
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    • pp.247-254
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    • 2005
  • General composition, total anthocyan content, and antioxidative and antimicrobial activities of Korean purple. fleshed potatoes (varieties A-D based on coloring degree of cross sections) were investigated. Slight differences in composition content were observed among varieties. Color intensity analyzed by sensory evaluation test decreased in order of PL-14, 31, 28, 3, 17, and 6, Total anthocyanin contents differed significantly among varieties from 3 to 29 mg Per 100 g, and decreased in order of PL-28, 31, 14, 12, 5, and 3. PL-28, 31, and Jasim potatoes showed slightly higher antioxidant activities than ${\alpha}$-tocopherol. PL-28, 31, 6, and Jasim showed antimicrobial activities against three species each of Gram-positive and-negative bacteria, with highest activities observed against Bacillus subtilis and relatively high activities against E. coli.

Theoretical and Experimental 31P NMR and ESI-MS Study of Hg2+ Binding to Fenitrothion

  • Koo, In-Sun;Ali, Dildar;Yang, Ki-Yull;vanLoon, Gary W.;Buncel, Erwin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1257-1261
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    • 2009
  • We present the theoretical and experimental results of $^{31}P$ NMR and low energy CID MS/MS study of $Hg^{2+}$ binding to fenitrothion (FN). The calculated $^{31}P$ NMR chemical shifts order for FN with $Hg^{2+}$ complex is in good agreement with experimental $^{31}P$ NMR chemical shifts order. The experimental and theoretical $^{31}P$ NMR study of organophosphorus pesticide with $Hg^{2+}$ gives to important information for organophosphorus pesticide metal complexes. ESI-MS and low energy CID MS/MS experiments of $Hg^{2+}$-FN complexes combined with accurate mass measurements give insight into the metal localization and allow unambiguous identification of fragments and hydrolysis products.

Floral Visitors and Nectar Secretion of the Japanese Camellia, Camellia Japonica L.

  • Rho, Jeong-Rae;Choe, Chun-Choe
    • Animal cells and systems
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    • v.7 no.2
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    • pp.123-125
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    • 2003
  • We studied the nectar secretion of the Japanese Camellia (Camellia japonica L.), an evergreen tree and observed its floral visitors during the day. The mean volume of nectar secreted, during daylight (08:31 to 16:30 h) was 30.26$\pm8,29ml$ (SD) (n = 27). During the late afternoon and overnight (16:31 to 08:30 following day), 100.54$\pm54.85$(n = 27) of nectar was secreted. Total volume measured when flowers were sampled once every two hours for an eight-hour period was approximately one-half the volume which was measured when the flowers were sampled only once after eight hours. The mean nectar volume secreted was 8.55$\pm8.3ml$(n = 30) between 08:31 to 10:30, 4.38$\pm$6.1 ml (n = 30) between 10:31 to 12:30, 4.6$\pm5.4ml$(n = 30) between 12;31 to 14:30, and 4.02$\pm3.5ml$(n = 30) between 14:31 to 16:30 hours. During the day, Japanese Camellia flowers were principally visited by the Japanese white-eye (Zosterops erythropleura erythropleura 5.), a native bird, although insects and squirrels also visited to a lesser degree.

Adhesion and Corrosion Resistance of Electrophoretic Paint on "Electroless" Paint Coated AZ31 Mg Alloy

  • Phuong, Nguyen Van;Kim, Donghuyn;Moon, Sungmo
    • Journal of the Korean institute of surface engineering
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    • v.51 no.6
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    • pp.405-414
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    • 2018
  • The present study investigated the adhesion and corrosion resistance of subsequent electrophoretic paint (E-paint) on "electroless" paint coated AZ31 Mg alloy, which was formed by immersion of AZ31 Mg alloy in E-painting solution. It was found that with increasing immersion time of AZ31 in E-painting solution, the amount of paint deposited by electroless process increased but it decreased the electrochemical equivalent of E-painting process and the adhesion of the subsequent E-paint layer. The E-paint on electroless paint coated AZ31 contained pores with the highest pore density and the largest pore size was obtained on the samples with electroless times of 2 and 5 minutes, respectively. Results of the salt-spray test showed an accelerated growth of blisters over the entire surface of the sample immersed for less than 5 minutes whereas blisters were observed only in the vicinity of the scratch in case of samples treated for 15 and 30 minutes. The E-paint on AZ31 with shorter electroless immersion time in E-painting solution was found to have good adhesion and better corrosion resistance.

A study of weld monitoring using light emission in Aluminum 6K31 laser welding (알루미늄 6K31의 레이저 용접에서 Light Emission을 이용한 용접부 모니터링에 관한 연구)

  • 박영환;이세헌;박현성;신현일
    • Proceedings of the KWS Conference
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    • 2003.11a
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    • pp.52-54
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    • 2003
  • In automotive industry, light weight vehicle is one of issues because of air pollution. Therefore, automotive manufacturers have tried to apply light materials such as aluminum to car body. Welding aluminum using laser has some advantages good weld quality and high productivity. In this study, light emission which is generated in aluminum 6k21 welding with laser is measured using photodiodes. Analysis of relationship between sensor signals of welding variables and formation of keyhole and plasma is performed.

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