• Journal of the Korean Electrochemical Society
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• v.3 no.2
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• pp.109-114
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• 2000

The relation between the phase-shift profile fur the intermediate frequencies and the Langmuir adsorption isotherm at the poly-Ir/0.1 M $H_2SO_4$ aqueous electrolyte interface has been studied using ac impedance measurements, i.e., the phase-shift methods. The simplified interfacial equivalent circuit consists of the serial connection of the electrolyte resistance $(R_s)$, the faradaic resistance $(R_F)$, and the equivalent circuit element $(C_P)$ of the adsorption pseudoca-pacitance $(C_\phi)$. The comparison of the change rates of the $\Delta(-\phi)/{\Delta}E\;and\;\Delta{\theta}/{\Delta}E$ are represented. The delayed phase shift $(\phi)$ depends on both the cathode potential (E) and frequency (f), and is given by $\phi=tan^{-1}[1/2{\pi}f(R_s+R_F)C_P]$. The phase-shift profile $(-\phi\;vs.\;E)$ for the intermediate frequency (ca. 1 Hz) can be used as an experimental method to determine the Langmuir adsorption isotherm $(\theta\;vs.\;E)$. The equilibrium constant (K) for H adsorption and the standard free energy $({\Delta}G_{ads})$ of H adsorption at the poly-Ir/0.1 M $H_2SO_4$ electrolyte interface are $2.0\times10^{-4}$ and 21.1kJ/mol, respectively. The H adsorption is attributed to the over-potentially deposited hydrogen (OPD H).

• Journal of the Korean Ceramic Society
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• v.32 no.1
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• pp.83-89
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• 1995

YBa2Cu3O7-$\delta$, Y2BaCuO5, and binary compounds in the Ba-Cu-O system with the nominal composition of Ba2CuO3, BaCuO2, Ba3Cu4O7, Ba3Cu5O8 were synthesized to investigate the heat evolutions and crystalline phases in the hydration reaction of orthorhombic YBa2Cu3O7-$\delta$ phase. The observed crystalline phases were YBa2Cu3O7-$\delta$, Y2BaCuO5, and BaCuO2, or Ba2Cu3O5＋x, and some amount of noncrystalline phase in the Ba-Cu system comounds. In contact with distilled water, YBa2Cu3O7-$\delta$ and Y2BaCuO5 did not have considerable heat liberation, but in the binary compounds of the Ba-Cu-O system, the amount of total heat liberation was increased with respect to the Cu content. It might be that the reaction of high temperature superconductor YBa2Cu3O7-$\delta$ with water and/or moisture originated from the unusual oxidation state of Cu ion and the presence of amorphous Ba-Cu oxide compound. The degradation of high Tc superconductor by moisture and water could be controlled by restricting the heterogeneous distribution of Tc comlposition and the formation of second phase, such as stable Y2BaCuO5, and the resulting unstable Ba-Cu oxide compound.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.38B no.10
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• pp.824-831
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• 2013

The delta driven GMSK is a modulation scheme to generate the gaussian pulse by the bipolar delta signal and to modulate the phase function with the differential gaussian pulse between $+T_b/2$ and $-T_b/2$. The demodulation of delta driven GMSK differs from conventional GMSK schemes. This paper proposed a demodulation with the differential phase detector at the end of each bit interval. A designed detector then finds the one of the possible region by hard decision, in which the phase difference lies. Finally the binary data can be recovered by state transition process. Through the BER simulation for AWGN channel, it was found that the proposed demodulation effected by the run length of binary data. The simulated BER degradation of about 2[dB] was analyzed, as compared to the theoretical coherent demodulation with $BT_b$=0.3.

• Journal of the Korean Applied Science and Technology
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• v.20 no.1
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• pp.33-43
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• 2003

$LiMn_2O_4$ catalyst for $CO_2$ decomposition was synthesized by oxidation method for 30 min at 600$^{\circ}C$ in an electric furnace under air condition using manganese(II) nitrate $(Mn(NO_3)_2{\cdot}6H_2O)$, Lithium nitrate ($LiNO_3$) and Urea $(CO(NH_2)_2)$. The synthesized catalyst was reduced by $H_2$ at various temperatures for 3 hr. The reduction degree of the reduced catalysts were measured using the TGA. And then $CO_2$ decomposition rate was measured using the reduced catalysts. Phase-transitions of the catalysts were observed after $CO_2$ decomposition reaction at an optimal decomposition temperature. As the result of X-ray powder diffraction analysis, the synthesized catalyst was confirmed that the catalyst has the spinel structure, and also confirmed that when it was reduced by $H_2$, the phase of $LiMn_2O_4$ catalyst was transformed into $Li_2MnO_3$ and $Li_{1-2{\delta}}Mn_{2-{\delta}}O_{4-3{\delta}-{\delta}'}$ of tetragonal spinel phase. After $CO_2$ decomposition reaction, it was confirmed that the peak of $LiMn_2O_4$ of spinel phase. The optimal reduction temperature of the catalyst with $H_2$ was confirmed to be 450$^{\circ}C$(maximum weight-increasing ratio 9.47%) in the case of $LiMn_2O_4$ through the TGA analysis. Decomposition rate(%) using the $LiMn_2O_4$ catalyst showed the 67%. The crystal structure of the synthesized $LiMn_2O_4$ observed with a scanning electron microscope(SEM) shows cubic form. After reduction, $LiMn_2O_4$ catalyst became condensed each other to form interface. It was confirmed that after $CO_2$ decomposition, crystal structure of $LiMn_2O_4$ catalyst showed that its particle grew up more than that of reduction. Phase-transition by reduction and $CO_2$ decomposition ; $Li_2MnO_3$ and $Li_{1-2{\delta}}Mn_{2-{\delta}}O_{4-3{\delta}-{\delta}'}$ of tetragonal spinel phase at the first time of $CO_2$ decomposition appear like the same as the above contents. Phase-transition at $2{\sim}5$ time ; $Li_2MnO_3$ and $Li_{1-2{\delta}}Mn_{2-{\delta}}O_{4-3{\delta}-{\delta}'}$ of tetragonal spinel phase by reduction and $LiMn_2O_4$ of spinel phase after $CO_2$ decomposition appear like the same as the first time case. The result of the TGA analysis by catalyst reduction ; The first time, weight of reduced catalyst increased by 9.47%, for 2${\sim}$5 times, weight of reduced catalyst increased by average 2.3% But, in any time, there is little difference in the decomposition ratio of $CO_2$. That is to say, at the first time, it showed 67% in $CO_2$ decomposition rate and after 5 times reaction of $CO_2$ decomposition, it showed 67% nearly the same as the first time.

• Journal of the Korean Ceramic Society
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• v.31 no.12
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• pp.1491-1500
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• 1994

Nonstoichiometry($\delta$) and the phase stability region of a ferrite spinel (Mg0.29Fe0.71)3-$\delta$O4 have been investigated by a coulometric titration method as a function of temperature(T) and oxygen partial pressure(Po2). It has been found that the spinel is thermodynamically stable in the ranges -8.0$\leq$log(PO2/atm)$\leq$-2.4, -7.0$\leq$log(PO2/atm)$\leq$-1.7 respectvely at 100$0^{\circ}C$. The nonstoichiometry extends over the ranges of -0.004$\leq$$\delta$$\leq$0.007, -0.008$\leq$$\delta$$\leq$0.006, -0.033$\leq$$\delta$$\leq$0.004 at 100$0^{\circ}C$, 120$0^{\circ}C$, respectvely. The observed PO2-dependence of $\delta$ suggests that the majority ionic defects are cation interstitials in the low PO2 region and cation vacancies in the high PO2 region.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.11 no.8
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• pp.1558-1563
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• 2007

In this paper, phase-locked loop (PLL) of a combinational architecture consisting of an adaptive bandwidth and fractional-N is presented to improve performances and reduce the order of ${\Delta}{\Sigma}$ modulator while maintaining equivalent or better performance with fast locking. The architecture of adaptive bandwidth PLL was simulated by HSPICE using 0.35m CMOS parameters. The behavioral simulation of the proposed adaptive bandwidth fractional-N PLL with a ${\Delta}{\Sigma}$ modulator was carried out by using MatLab to determine if the architecture could achieve the objectives. The HSPICE simulation showed that this type of PLL was able to fast locking, and reduce fractional spurs about 20dB.

• Journal of Power Electronics
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• v.18 no.6
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• pp.1920-1929
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• 2018

In order to provide a source for nine phases suitable for 18-pulse ac to dc power, this paper proposes a new structure for a step-up asymmetrical delta-connected transformer for converting three-phase ac power to nine-phase ac power. The design allows for symmetry between the nine output voltages to improve the power quality of the supply current and to minimize the THD. The results show that this new structure proves the equality between the output voltages with $40^{\circ}-{\alpha}$ and $40^{\circ}+{\alpha}$ phase shifting and produces symmetrical output currents. This result in the elimination of harmonics in the network current and provides a simulated THD that is equal to 5.12 %. An experimental prototype of the step-up asymmetrical delta-autotransformer is developed in the laboratory and the obtained results give a network current with a THD that is equal to 5.35%. Furthermore, a finite element analysis with a 3D magnetic field model is made based on the dimensions of the 4kVA, 400 V laboratory prototype three-phase with three-limb delta-autotransformer with a six-stacked-core in each limb. The magnetic distribution flux, field intensity and magnetic energy are carried out under open-circuit operation or load-loss.

• Proceedings of the KIEE Conference
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• 2008.04c
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• pp.9-12
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• 2008

Mathematical singularities of circuit equations with three-phase ideal transformer connections are studied. Three-wired wye-wye connections, delta-delta connections, and primary four-wired wye-delta connections are singular. The matrices of their circuit equations have zeros in their eigenvalues. Three-wired wye-delta connections, wye-wye-delta connections, and primary four-wired wye-wye connections are not singular. The physical meaning of their singularities is that they are sensitive and prone to be ill-conditioned. Equivalent shunt admittances representing ion losses and magnetizing inductances make the singular matrices non-singular in wye-connected circuits. And, equivalent series impedances representing copper losses and leakage inductances make the singular matrices non-singular in delta-connected circuits. The tableau analysis is used for the study.

• Journal of Power Electronics
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• v.8 no.3
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• pp.259-267
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• 2008

Power quality improvement in a three-phase four-wire system is achieved using a new topology of DSTATCOM (distribution static compensator) consisting of a star/delta transformer with a tertiary winding and a three-leg VSC (voltage source converter). This new topology of DSTATCOM is proposed for power factor correction or voltage regulation along with harmonic elimination, load balancing and neutral current compensation. A tertiary winding is introduced in each phase for a delta connected secondary in addition to the star-star windings and this delta connected winding is responsible for neutral current compensation. The dynamic performance of the proposed DSTATCOM system is demonstrated using MATLAB with its Simulink and Power System Blockset (PSB) toolboxes under varying loads. The capacitor supported DC bus of the DSTATCOM is regulated to the reference voltage under varying loads.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.64 no.11
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• pp.1543-1550
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• 2015

Ferroresonance is a non-linear vibrational phenomenon that is generated by the electrical interaction of the inductance component with the capacitor component of a certain capacitance as the device of the inductance component such as a transformer is saturated due to the degradation, the waveform distortion of current and voltage, and the oscillation of overcurrent and overvoltage in a system. Recently, ferroresonance was generated from the waveform distortion of current and voltage, or the overvoltage or undervoltage phenomenon caused by the nature of an electrical power system and design technology of the transformer in the three phase transformer system. Hence, in general, ferroresonance analyzed by converting to the LC equivalent circuit. However, in general, the aforementioned analytical method only applies to the resonance phenomenon that is generated by the interaction of the capacitance of bussbar and grounding, and switching as the capacitor component with PT and the transformer as the inductance component in a system. Subsequently, the condition where ferroresonance was generated since overvoltage was supplied as line voltage to the phase voltage and thus the iron core is saturated due to the interconnection between grounded and ungrounded systems could not be analyzed when single phase PT was connected in a ${\Delta}$/Y connection system. In this study, voltage swell in the configuration of grounded circuit of a step-up transformer with the ${\Delta}-{\Delta}$ connection linked to PT for control power and the ferroresonance generated by overvoltage when the line voltage of the ${\Delta}-{\Delta}$ connection was connected to the phase voltage of the grounded Y-Y connection were analyzed using PSCAD / EMTDC through the failure case of the transformer caused by ferroresonance in the system with the ${\Delta}-{\Delta}$/Y-Y connection, and subsequently, the preventive measure of ferroresonance was proposed.