• 제목/요약/키워드: ${\chi}$ phase

검색결과 391건 처리시간 0.026초

강유전 고분자 박막의 상전이 특성 (Phase Transition Properties of Ferroelectric Polymer Films)

  • 박철우;정치섭
    • 한국전기전자재료학회논문지
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    • 제27권2호
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    • pp.97-103
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    • 2014
  • Phase transition properties of the copolymer films of polyvinylidene fluoride (PVDF) and trifluoroethylene(TrFE), P(VDF-TrFE), were studied with X-ray diffraction (XRD) and polarization modulated ellipsometry (PME). XRD studies on both Langmuir-Blodgett (LB) films and spin coated films exhibit conversions from ferroelectric phase to paraelectric phase at $108{\pm}2^{\circ}C$ on heating and paraelectric phase to ferroelectric phase at $78{\pm}2^{\circ}C$ on cooling. The presence of the ferroelectric-paraelectric phase transition is also confirmed by the PME technique for the first time in this study. PME was proved to be a very sensitive tool in the measurement of the structural changes at the nano-thickness films.

효율적인 로그와 지수 연산을 위한 듀얼 페이즈 명령어 설계 (A Design of Dual-Phase Instructions for a effective Logarithm and Exponent Arithmetic)

  • 김치용;이광엽
    • 전기전자학회논문지
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    • 제14권2호
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    • pp.64-68
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    • 2010
  • 본 논문은 작은 사이즈가 요구되는 제한적인 모바일 환경의 프로세서에서 별도의 연산기 없이 제안된 Dual Phase 명령어 구조를 이용해 효율적인 로그와 지수 연산이 가능한 방법을 제안한다. Floating Point 자료형의 지수부와 실수부를 추출하는 명령어 세트와 테일러 급수 전개를 이용해 로그의 근사치를 계산하여 24비트 단정도 부동 소수점을 연산하고, Dual Phase 명령어 구조를 활용해 명령어 실행 사이클을 줄였다. 제안된 구조는 별도의 연산기를 두는 구조보다 작은 사이즈를 유지하면서 성능저하를 33%까지 최소화 할 수 있는 구조이다.

A Study on the Analytical Methods Using Solid-phase Extraction for the Determination of Phenols in Water

  • Jeon, Chi-Wan;Lee, Jung-Hwa;Lee, Sang-Hak
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2003년도 International Symposium on Clean Environment
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    • pp.135-138
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    • 2003
  • Based on solid phase extraction, gas chromatography and mass spectrometry procedure for determining phenol and its derivatives in natural water was presented. In solid phase extraction, three types of techniques using solid phase adsorption material were treated with acid and salt, and converted second portion of acetyl derivatives. Under the these condition, extraction efficiency and detection ability dependent on extraction methods were discussed. Obtained results using optimized solid phase extraction techniques showed more convenience, simplifier and lower cost than the conventional analytical methods with holding wide dynamic range and lower detection limits.

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Theoretical Estimation of Partial Miscibilities by the Extended Flory-Huggins Lattice Theory

  • Jung, Hae-Young;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • 제6권3호
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    • pp.132-135
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    • 1985
  • Four types of the phase diagrams indicating the partial miscibilities in polymer-polymer or polymer-solvent systems have been explained in terms of the extended Flory-Huggins lattice theory. In this article, the term $kT_{\chi}$ in the theory is expressed as a function of temperature. Using such $a_{\chi}$-parameter, the simplest forms of geometrical conditions are derived for each type of the four partial miscibilities in polymer systems. The calculated partial miscibilities are in good agreement with the experiment.

Preparation of PVDF Membrane by Thermally-Induced Phase Separation

  • Heo, Chi-Haeng;Lee, Kyung-Mo;Kim, Jin-Ho;Kim, Sung-Soo
    • Korean Membrane Journal
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    • 제9권1호
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    • pp.27-33
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    • 2007
  • PVDF membrane formation via TIPS was performed for PVDF/DBP and PVDF/DMP systems. PVDF/DBP system showed solid-liquid phase separation behavior, while PVDF/DMP system has liquid-liquid phase separation characteristic as well as solid-liquid phase separation characteristic. PVDF contents and cooling conditions had great influence on structure, and the effects of each parameter were examined. Spherulitic structure was obtained due to the dominant PVDF crystallization. Diluent rejected to the outside of spherulite occupied the surface of the PVDF spherulites to result in the microporous spherulite formation and micro-void between spherulites. PVDF/DMP system had competitive solid-liquid and liquid-liquid phase separation depending on the cooling path.

송 『영조법식』의 건축계획 치수 단위에 대한 이론적 고찰 - 자(尺) 단위 계획설과 분(分°) 단위 계획설 간의 논쟁을 중심으로 - (A study on the dimension unit of framework on Yingzaofashi - Confrontation between Chi(尺) hypothesis and Fen(分°) hypothesis -)

  • 백소훈
    • 건축역사연구
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    • 제31권3호
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    • pp.7-16
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    • 2022
  • Fen(分°) is the proportional dimension unit of the standard timber section on Yingzaofashi(營造法式), and there is a phrase that not only structural members but the whole structural design of a building also use Fen as the dimension unit on the book. But in fact only the section dimensions of structural members are recorded by Fen, but the design dimensions are recorded by Chi(尺) on the book. Other historical records also described the building size by Chi. So there has been long-standing debate on the phase in Chinese architectural history society, including the recent confrontation on the analysis of survey figures of the east great hall of Foguangsi temple(佛光寺 東大殿). This paper analyzes all the records about the size of structural members and section planning on the book to make various calculation and evaluation. And it makes a survey of Cai(材) as the dimension and design unit between Chi and Fen through geometric analysis. Cai might be a rough unit of measurement in terms of structural and proportional scheming on Yingzaofashi, and the full size Cai(足材) had been a building scheming module before the Song dynasty.

역상 액체크로마토그래피에서 벤젠 일치환체들의 머무름 메카니즘에 관한 연구 (제 2 보) (A Study of the Retention Mechanism of the Monosubstituted Benzenes in Reversed-phase Liquid Chromatography (II))

  • 이대운;최용욱;이완
    • 대한화학회지
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    • 제32권2호
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    • pp.135-143
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    • 1988
  • 역상 액체크로마토그래피에서 벤젠 일치환체들의 머무름 메카니즘과 머무름예측을 연구하기 위하여 크로마토 그래피 파라미터로 극성지표(P') 분자량(MW), 치환기 상수(${\pi}$ ) 및 분자간 연결지수$(^1{\chi}^{\nu})$를 머무름 데이터와 관련지어 상관관계를 조사하였다. 벤젠을 기존으로 하여 각 치환체의 크기인자와 비인 상대적 머무름$(log k'_S/k'_B)$과 각 치환체의 극성의비 $(P'_S/P'_B)$ 사이에는 상관관계가 있다. 치환기가 극성인 치환체들은 상관관계가 비교적 좋았으나 비극성 치환기를 갖는 치환체들은 분자량을 함께 고려함으로써 좋은 상관관계를 얻을 수 있다. 또한 상대적 머무름과 극성인자 및 분자량의 상관관계를 다변수 회귀분석으로 구하였다. 문헌적 머무름 자료와 소수성 파라미터로부터 유도된 치환기 상수(${\pi}$)와 분자간 연결지수$(^1{\chi}^{\nu})$ 간에는 메탄올의 이동상에서 가장 좋은 상관관계를 얻었다. $C_{18}$ 컬럼의 미반응된 실란올 기를 끝막음(end capping) 시키지 않은 컬럼에서는 이러한 상관관계가 감소되었다. 벤젠 일치환체들의 머무름과 관련지어 고려할 수 있는 파라미터는${\pi}$, P', $(^1{\chi}^{\nu})$ 및 MW 순으로 그 관련성이 감소됨을 알았다.

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Effects of Tungsten on the Precipitation Kinetics of Secondary Phases and the Associated Susceptibility to Pitting Corrosion in Duplex Stainless Steels

  • Park, Chan-Jin;Kwon, Hyuk-Sang
    • Corrosion Science and Technology
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    • 제5권6호
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    • pp.189-195
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    • 2006
  • Effects of tungsten (W) on the precipitation kinetics of secondary phases and the associated resistance to pitting corrosion of 25%Cr duplex stainless steels were investigated through microstructural and electrochemical noise analyses. With the partial substitution of W for Mo in duplex stainless steel, the potential and current noises of the alloy were significantly decreased in chloride solution due to retardation of the ${\sigma}$ phase precipitation. The preferential precipitation of the $\chi$ phase in the W-containing alloy during the early period of aging contributed to retarding the precipitation of the $\sigma$ phase by depleting W and Mo along grain boundaries. In addition, the retardation of the nucleation and growth of the $\sigma$ phase in the W-containing alloy appears to be attributed to the inherently low diffusivity of W compared with that of Mo.

슈퍼 듀플렉스 스테인리스강의 응고·냉각 시 상석출에 미치는 냉각속도의 영향 (Influence of the Cooling Rate on the Phase Precipitation of Super Duplex Stainless Steel)

  • 장은석;김기영;김석준
    • 한국주조공학회지
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    • 제35권2호
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    • pp.23-28
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    • 2015
  • This work presents the effect of the cooling rate on the precipitation of super duplex stainless steel. Specimens of super duplex stainless steel with a specific composition were cooled at various cooling rates after being melted at $1550^{\circ}C$ in a directional solidification furnace. Ferrite (${\delta}$), Austenite (${\gamma}$), Sigma (${\sigma}$), and Chi (${\chi}$) phases were precipitated when the cooling rate was lower than 0.22 K/s. When the cooling rate was 0.22 K/s or faster, ${\sigma}$ and ${\chi}$ phases were not precipitated.

Project Cost Management in Construction Industry in Ho Chi Minh City

  • Kim, Soo-Yong;Tuan, Kiet Nguyen;Luu, Van Truong;Le, Tam Thuong
    • 국제학술발표논문집
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    • The 6th International Conference on Construction Engineering and Project Management
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    • pp.70-71
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    • 2015
  • Cost management always being the matters for project manager as well as other entities involved the construction projects. Vietnam is emerging country, many construction works were carried out and lot of construction projects will be developed in the near future with a huge investment capital come from outside and inside Vietnam. In recent years, international project management firms enter the Vietnam construction market, some issues emerged need to be solved. In which cost and schedule of the construction project was put in a thoroughly consider of not only project management team but also stakeholders. The research attempts to identify and assess the relationship of factors affecting the construction cost in construction phase in Ho Chi Minh City, Vietnam. Five main factor groups Owners/clients; Consultants; Contractors; Resource and Other were identified to propose the solution for cost management.

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