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Theoretical Estimation of Partial Miscibilities by the Extended Flory-Huggins Lattice Theory

  • Jung, Hae-Young (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Jhon, Mu-Shik (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • Published : 1985.06.20

Abstract

Four types of the phase diagrams indicating the partial miscibilities in polymer-polymer or polymer-solvent systems have been explained in terms of the extended Flory-Huggins lattice theory. In this article, the term $kT_{\chi}$ in the theory is expressed as a function of temperature. Using such $a_{\chi}$-parameter, the simplest forms of geometrical conditions are derived for each type of the four partial miscibilities in polymer systems. The calculated partial miscibilities are in good agreement with the experiment.

Keywords

References

  1. Principles of Polymer Chemistry P.J. Flory
  2. The Molecular Theory of Solutions I. Prigogine
  3. J. Phys. Chem. v.68 V.S. Nanda;R. Simha
  4. J. Amer. Chem. Soc. v.86 P.J. Flory
  5. Br. Polym. J. v.7 R. Koningsveld
  6. Polymer-Polymer Miscibility O. Olabisi;L.M. Robeson;M.T. Shaw
  7. The Scientific Papers of J. Willard Gibbs
  8. Polymer Blends v.1 T.K. Kwei;T.T. Wang;D.R. Paul(ed.);S. Newman(ed.)
  9. Macromolecules v.5 K.S. Siow;G. Delmas;D. Patterson
  10. Macromolec v.6 S. Saeki;N. Kuwahara;S. Konno;M. Kaneko
  11. Kunst Stoff v.53 G. Rehage