• Title/Summary/Keyword: ${\alpha}$ ray

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Differential Modulation of Volatile Constituents in Artemisia princeps and Artemisia argyi Plants after Gamma Ray or Electron Beam Irradiation

  • Kim, Ji Hong;Cho, Eun Ju;Lee, Min Hee;Kim, Ji Eun;Chung, Byung Yeoup;Kim, Tae Hoon;Kim, Jin-Hong
    • Journal of Radiation Industry
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    • v.6 no.1
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    • pp.17-21
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    • 2012
  • The effects of gamma ray or electron beam irradiation on herbaceous medicinal plants were investigated in terms of the composition of volatile constituents using the aerial parts or leaves of Artemisia princeps Pamp. cv. Ganghwayakssuk and Artemisia argyi cvs. Namhaeyakssuk and Hwanghaessuk. The composition of volatile constituents in leaves was clearly distinguishable among the three Artemisia cultivars. However, the relative proportions of the major volatile constituents such as 1,8-cineole, ${\alpha}$-pinene, camphene, santolina triene, and artemesia triene, were similarly changed in two or three cultivars by gamma ray or electron beam irradiation. In particular, the proportion of 1,8-cineole was increased up to 1.29- to 1.71-fold in the three cultivars after irradiation with gamma ray. These results suggest that gamma ray or electron beam irradiation can be applied to modulate the composition of volatile constituents in the leaves of Artemisia plants.

Determination of Air-dry Density of Wood with Polychromatic X-ray and Digital Detector

  • Kim, Chul-Ki;Kim, Kwang-Mo;Lee, Sang-Joon;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.6
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    • pp.836-845
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    • 2017
  • Gravimetric method is usually used to evaluate air-dry density, which is governing physical or mechanical properties of wood. Although it had high evaluation accuracy, the method is time consuming process. Thus, this study was conducted to estimate air-dry density of wood with high accuracy by using polychromatic X-ray and digital detector as alternative of gravimetric method. To quantify polychromatic X-ray projection for evaluating air-dry density, Lambert-Beer's law with the integral value of probability function was used. The integral value was used as weighting factor in the law, and it was determined by conducting simple test at various penetration depths and tube voltage. Mass attenuation coefficient (MAC) of wood also calculated by investigating polychromatic X-ray projection according to species, penetration depth and tube voltage. The species had not an effect on change of MAC. Finally, an air-dry density of wood was estimated by applying the integral value, MAC and Lambert-Beer's law to polychromatic X-ray projection. As an example, the relation of the integral value (${\alpha}$) according to penetration depth (t, cm) at tube voltage of 35 kV was ${\alpha}=-0.00091t{\times}0.0184$ while the regression of the MAC (${\mu}$, $cm^2/g$) was ${\mu}=0.5414{\exp}(-0.0734t)$. When calculation of root mean squared error (RMSE) was performed to check the estimation accuracy, RMSE at 35, 45 and 55 kV was 0.010, 0.013 and $0.009g/cm^3$, respectively. However, partial RMSE in relation to air-dry density was varied according to tube voltage. The partial RMSE below air-dry density of $0.41g/cm^3$ was $0.008g/cm^3$ when tube voltage of 35 kV was used. Meanwhile, the partial RMSE above air-dry density of $0.41g/cm^3$ decreased as tube voltage increased. It was conclude that the accuracy of estimation with polychromatic X-ray and digital detector was quite high if the integral value and MAC of wood were determined precisely or a condition of examination was chosen properly. It was seemed that the estimation of air-dry density by using polychromatic X-ray system can supplant the gravimetric method.

In Situ X-ray Photoemission Spectroscopy Study of Atomic Layer Deposition of $TiO_2$ on Silicon Substrate

  • Lee, Seung-Youb;Jeon, Cheol-ho;Kim, Yoo-Seok;Kim, Seok-Hwan;An, Ki-Seok;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.222-222
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    • 2011
  • Titanium dioxide (TiO2) has a number of applications in optics and electronics due to its superior properties, such as physical and chemical stability, high refractive index, good transmission in vis and NIR regions, and high dielectric constant. Atomic layer deposition (ALD), also called atomic layer epitaxy, can be regarded as a special modification of the chemical vapor deposition method. ALD is a pulsed method in which the reactant vapors are alternately supplied onto the substrate. During each pulse, the precursors chemisorb or react with the surface groups. When the process conditions are suitably chosen, the film growth proceeds by alternate saturative surface reactions and is thus self-limiting. This makes it possible to cover even complex shaped objects with a uniform film. It is also possible to control the film thickness accurately simply by controlling the number of pulsing cycles repeated. We have investigated the ALD of TiO2 at 100$^{\circ}C$ using precursors titanium tetra-isopropoxide (TTIP) and H2O on -O, -OH terminated Si surface by in situ X-ray photoemission spectroscopy. ALD reactions with TTIP were performed on the H2O-dosed Si substrate at 100$^{\circ}C$, where one cycle was completed. The number of ALD cycles was increased by repeated deposition of H2O and TTIP at 100$^{\circ}C$. After precursor exposure, the samples were transferred under vacuum from the reaction chamber to the UHV chamber at room temperature for in situ XPS analysis. The XPS instrument included a hemispherical analyzer (ALPHA 110) and a monochromatic X-ray source generated by exciting Al K${\alpha}$ radiation (h${\nu}$=1486.6 eV).

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Monitoring of Gamma-ray Bright AGN : The Multi-Frequency Polarization of the Flaring Blazar 3C 279

  • Kang, Sincheol;Lee, Sang-Sung;Byun, Do-Young
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.65.1-65.1
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    • 2016
  • We present results of long-term multi-wavelength polarization observations of the powerful blazar 3C 279 after its ${\gamma}$-ray flare on 2013 December 20. We followed up this flare by means of single-dish polarization observations with two 21-m telescopes of the Korean VLBI Network, carried out weekly from 2013 December 25 to January 11, and at 22, 43, and 86 GHz, simultaneously. These observations were part of the Monitoring Of GAmma-ray Bright AGNs (MOGABA) program. We Measured 3C 279 total flux densities at 22, 43, and 86 GHz, showing a mild variability of a factor of ${\leq}50%$ over the period of our observations. The spectral index ranged from -0.13 to -0.36 at between 22 and 86 GHz. The degree of linear polarization was in the range of 6 ~ 12 %, and slightly decreased with time at all frequencies. We found Faraday rotation measures (RM) of -300 to $-1200rad\;m^{-2}$ between 22 and 43 GHz, and -800 to $-5100rad\;m^{-2}$ between 43 and 86 GHz. The RM values follow a power law ${\mid}RM{\mid}{\propto}{\nu}^{\alpha}$, with a mean ${\alpha}$ of 2.2, implying that the polarized emission at these frequencies travels through a Faraday screen in or near the jet. We conclude that the regions emitting polarized radio emission may be different from the region responsible for the 2013 December ${\gamma}$-ray flare, and that these regions are maintained by the dominant magnetic field perpendicular to the direction of the radio jet at milliarcsecond scales.

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A Composite DorsoPlantar Axial X-ray Projection Study on the Bones of the Whole Infant's Foot (유아 발 전체의 뼈에 대한 합성 전후축방향 엑스선촬영법 연구)

  • Park, Yun;Ahn, Byung-Ju
    • Journal of the Korean Society of Radiology
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    • v.15 no.7
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    • pp.1007-1013
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    • 2021
  • A Study that Cronbach Alpha values were Significantly higher at 0.813 in the Composite AP axial Radiography Signal to Noise Ratio(SNR) for Evaluating uniform Density and Advanced Images of the Entire Foot without overlap with the legs. The Subjective Evaluation ROC also scored a high score of 18 on Foot Calcaneus bone 10° from the Foot Metatarsal bone, and 18 on the Examination by tilting the Sharpness X-ray Tube 20° from the Foot Calcaneus bone. Results show uniform Density and images at 10° rearward of Foot Metatarsal bone and 20° forward of Foot Calcaneus bone during the Composite AP axial Radiography X-ray Examination of Infants.

The electrical properties study with specific of phase transition of Lead Monoxide by PIB(Particle In Binder) (PIB(Particle In Binder) 방법으로 제조된 산화납의 특이상전이에 따른 전기적 특성 평가)

  • Kim, Sung-Hyun;Kim, Young-Bin;Jung, Suk-Hee;Kim, Min-Woo;Oh, Kyung-Min;Park, Ji-Gun
    • Journal of the Korean Society of Radiology
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    • v.2 no.3
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    • pp.19-25
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    • 2008
  • Commercial analog x-ray detectors based on film cassettes have been showing problems such as with image storage and image transmission. Recently direct conversion material, photoconductor whit flat panel have been researched which generate the electron hole-pair (EHP). In this paper, we researched the electrical properties of the PbO and Lead(II) oxide PbO. film which fabricated by Particle-In-Binder(PIB) method. We compared tetragonal ${\alpha}$-PbO with orthorhombic ${\beta}$-PbO physical property. Tetragonal material was more than orthorhombic material in other paper. The solution was Poly Vinyl Butyral(PVB) in the PIB. We discussed about the sample of x-ray sensitivity, leakage current, Signal to Noise Rate and investigated SEM for the physical property of sample. We need to think more research ${\alpha}$-PbO material fabrication.

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The Effect of Initial α' on Low and High Cycle Fatigue Behavior of STS 304 Stainless Steel (STS 304 강의 저주기 및 고주기 피로에 있어 초기 마르텐사이트의 영향)

  • Lee, Hyun-Seung;Sin, Hyung-Ju;Kim, Song-Hee
    • Journal of Industrial Technology
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    • v.21 no.B
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    • pp.331-339
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    • 2001
  • Zero to tension fatigue tests and strain controlled fatigue tests were carried out to find how initial strain induced martensite, ${\alpha}^{\prime}$ affects low and high cycle fatigue behavior and fatigue crack growth mechanisms. Microscopic study and phase analysis were carried out with TEM, SEM, EDAX, Optical Microscope, Ferriscope, and X-ray diffractometry. The amount of Initial ${\alpha}^{\prime}$ was controlled from 0% to 33% by controlling the temperatures for cold working and heat treatment. Lower contents of initial ${\alpha}^{\prime}$ showed higher fatigue resistance in low cycle fatigue but lower fatigue resistance in high cycle fatigue because it is ascribed to the more transformation of ${\alpha}^{\prime}$ martensite during low cycle fatigue and higher ductility. In high cycle fatigue, fatigue life is attributed to the strength and phase transformation of austenite into ${\alpha}^{\prime}$ during fatigue was negligible. ${\gamma}$ boundary, ${\gamma}/twin$ boundary, and ${\gamma}/{\alpha}^{\prime}$ boundary were found to be the preferred site of fatigue crack initiation.

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Influence of Dangling Bonds on Nanotribological Properties of Alpha-beam Irradiated Graphene

  • Hwang, Jinheui;Kim, Jong Hoon;Kwon, Sangku;Hwang, C.C.;Wu, Junqiao;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.265-265
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    • 2013
  • We have investigated the influences of dangling bonds generated by alpha particle irradiation on friction and adhesion properties of graphene. Single layer of graphene grown with chemical vapor deposition on copper foil was irradiated by the alpha beam with the average energy of 3.04 MeV and the irradiation dosing between $1{\times}10^{14}$ and $1{\times}10^{15}$/$cm^3$. Raman spectroscopic showed that the ${\pi}$ electron states below Fermi level arises and the $I_D$/$I_G$ increases as increasing the dosing of alpha particle irradiation. The core level X-ray photoelectron (XPS) revealed that these defects represent the creation of various carbon-related defects and dangling bond. The nanoscale tribological properties were investigated with atomic force microscopy in ultrahigh vacuum. The friction appeared to increase remarkably as increasing the amount of dosing, indicating that the dangling bonds on graphene layers enhances the energy dissipations in friction. This trend can be explained by the additional channel of energy dissipation by dangling bond or O- and H- terminated clusters created by alpha particle irradiation.

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The Study for Synthesis and Characteristic of ${\alpha},{\beta}$-tetra(phenoxy, 2-naphthoxy, 4-tritylphenoxy) Oxovanadium Phthalocyanine Derivatives (${\alpha},{\beta}$-tetra(phenoxy, 2-naphthoxy, 4-tritylphenoxy) Oxovanadium 프탈로시아닌 유도체의 합성 및 특성에 관한 연구)

  • Son, Dae-Hee;Heo, Jin;Kim, Song-Hyuk;Lee, Seung-Ho;Lee, Gun-Dae;Hong, Seong-Soo;Park, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.21 no.6
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    • pp.638-642
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    • 2010
  • After phthalonitrile derivatives were synthesized by the introduction of phenoxy, 2-naphthoxy or 4-trityl phenoxy group on ${\alpha}$- and ${\beta}$-position, oxovanadyl phthalocyanine (VOPc) derivatives containing electron-rich substituent group at different position were synthesized successfully in this investigation. The chemical structure of samples was determined by the means of $^1H$-NMR, MALDI-TOF mass spectroscopy, and FT-IR spectrometer. Also, optical and chemical properties were determined by the means of UV-Vis spectrometer, X-ray diffractometry, and thermo gravimetry. It was found that the maximum absorbing wavelength of VOPc derivatives ranged from 684 to 726 nm. Also, their solubility and Q-band were enhanced and shifted by the introduction of substitute group, respectively.

Comparison of Inclusion Complex Formation Capacity of Cyclodextrins with Various Molecules and Characterization of Cyclodextrin-fatty Acid Complex (Cyclodextrin의 Inclusion Complex 형성능과 Fatty Acid와의 Complex 형성조건과 특성)

  • 이용현;정승환박동찬
    • KSBB Journal
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    • v.10 no.2
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    • pp.149-158
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    • 1995
  • The capacity of inclusion complex formation between ${\alpha}$-, ${\beta}$-, ${\gamma}$-cyclodextrins(CDs) and various compounds, such as pH indicators, biloslalns, glycoside, amino acid, and fatty acids, was compared. Fatty acid was identified as the most suitable ligand for fractionation of CDs in terms of capacity and selectivity. The effects of complex formation conditions, such as, mixing ratio of CD and fatty acid, pH, ionic strength, and temperature, on the capacity of fatty acrid-CD complex was also investigated. The carbon number of fatty acids was identified as the most significant factor determining the capacity and selectivity of inclusion complex formation of CDs. Capric acid(C10) and palmitic acid(C16) showed high specificity for ${\alpha}$- and ${\beta}$-CDs, respectively. Under the optimal conditions, the molar ratio of complex formed was found to be 1.0:2.6 for ${\alpha}$-CD/capric acid and 1.0:1.9 for ${\beta}$-CD/palmitic acid. X-ray diffraction and infrared spectrum of the formed inclusion complex were analyzed. The changes of enthalpy($\Delta$H) of the inclusion complex formation reaction was evaluated by differential scanning calorimetry, showed that the reaction was endothermic.

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