Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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The Study for Synthesis and Characteristic of ${\alpha},{\beta}$-tetra(phenoxy, 2-naphthoxy, 4-tritylphenoxy) Oxovanadium Phthalocyanine Derivatives

${\alpha},{\beta}$-tetra(phenoxy, 2-naphthoxy, 4-tritylphenoxy) Oxovanadium 프탈로시아닌 유도체의 합성 및 특성에 관한 연구

  • Son, Dae-Hee (CFC Teramate Co. Ltd.) ;
  • Heo, Jin (CFC Teramate Co. Ltd.) ;
  • Kim, Song-Hyuk (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Lee, Seung-Ho (Composite Materials Center, Korea Institute of Ceramic Eng. & Tech.) ;
  • Lee, Gun-Dae (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Hong, Seong-Soo (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Park, Seong-Soo (Division of Applied Chemical Engineering, Pukyong National University)
  • 손대희 ((주) CFC Teramate) ;
  • 허진 ((주) CFC Teramate) ;
  • 김송혁 (부경대학교 응용화학공학부) ;
  • 이승호 (한국세라믹기술원 복합재료센타) ;
  • 이근대 (부경대학교 응용화학공학부) ;
  • 홍성수 (부경대학교 응용화학공학부) ;
  • 박성수 (부경대학교 응용화학공학부)
  • Received : 2010.07.29
  • Accepted : 2010.09.27
  • Published : 2010.12.10
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Abstract

After phthalonitrile derivatives were synthesized by the introduction of phenoxy, 2-naphthoxy or 4-trityl phenoxy group on ${\alpha}$- and ${\beta}$-position, oxovanadyl phthalocyanine (VOPc) derivatives containing electron-rich substituent group at different position were synthesized successfully in this investigation. The chemical structure of samples was determined by the means of $^1H$-NMR, MALDI-TOF mass spectroscopy, and FT-IR spectrometer. Also, optical and chemical properties were determined by the means of UV-Vis spectrometer, X-ray diffractometry, and thermo gravimetry. It was found that the maximum absorbing wavelength of VOPc derivatives ranged from 684 to 726 nm. Also, their solubility and Q-band were enhanced and shifted by the introduction of substitute group, respectively.

본 연구에서는 벤젠고리의 ${\alpha}$와 ${\beta}$-위치에 phenoxy, 2-naphthoxy 또는 4-trityl phenoxy 치환기가 도입된 프탈로니트릴 유도체들을 합성하였고, 이들 중간체들을 이용하여 전자 주게 특성을 가지는 치환기가 도입된 oxovanadium phthalocyanine (VOPc) 유도체들을 성공적으로 합성하였다. 시료들의 구조 특성 및 분자량은 $^1H$-NMR, FT-IR 및 MALDI-TOF형 질량분석기를 이용하여 측정 분석하였고, 광학적 및 화학적 특성은 UV-Vis 분광기, X-ray 회절기 및 열분석기를 이용하여 측정 분석하였다. 합성된 VOPc 유도체들의 최대흡수파장 값은 약 684~726 nm이었으며, 치환기의 도입으로 말미암아 용해도가 향상되거나 Q 밴드가 이동하였다.

Keywords

References

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