• Journal of the Korean Chemical Society
• /
• v.28 no.6
• /
• pp.418-424
• /
• 1984

Rate constants for the hydrolysis of cinnamonitrile in the concentration range of 1 ∼ 5M of perchloric acid at 25$^{\circ}$C have been determined by UV spectrophotometry and from the Bunnett equations, hydration parameters (${\omega}$ = 9.8, ${\omega}^*$ = 0.42 & ${\phi}$=1.6) were obtained. CNDO/2 MO calculations were performed to determine relative stability, net charges, and overlap population of various conformational isomers. The results show that the (E)-planar is more stable than the (Z)-planar and protonation is favored on the nitrogen atom. On the basis of above findings, the acid hydrolysis is initiated by the protonation of the nitrogen atom of cinnamonitrile and then water molecule acting as nucleophile and as a proton transfer agent in the rate determining step. In the transition state of the acid hydrolysis, nucleophilic addition of water molecule occurs by sigma approach to the positively charged $C_7({\alpha}$) atom of the conjugate acid. As the results, we may conclude that the hydrolysis of cinnamonitrile in the strong acidic media proceeds through the A-2 type mechanism.

• Communications of the Korean Mathematical Society
• /
• v.37 no.4
• /
• pp.1249-1258
• /
• 2022

In this study, we show that the strong exponential limit shadowing property (SELmSP, for short), which has been recently introduced, exists on a neighborhood of a hyperbolic set of a diffeomorphism. We also prove that Ω-stable diffeomorphisms and 𝓛-hyperbolic homeomorphisms have this type of shadowing property. By giving examples, it is shown that this type of shadowing is different from the other shadowings, and the chain transitivity and chain mixing are not necessary for it. Furthermore, we extend this type of shadowing property to positively expansive maps with the shadowing property.

• Nonlinear Functional Analysis and Applications
• /
• v.28 no.2
• /
• pp.521-535
• /
• 2023

In this work, some various types of Dissipativity in random dynamical systems are introduced and studied: point, compact, local, bounded and weak. Moreover, the notion of random Levinson center for compactly dissipative random dynamical systems presented and prove some essential results related with this notion.

• Transactions on Electrical and Electronic Materials
• /
• v.14 no.1
• /
• pp.9-11
• /
• 2013

The AZO/Ag/AZO multilayer films were deposited on polyethersulfone (PES) substrate by using facing target sputtering methods at room temperature. The AZO/Ag/AZO multilayer films with polymer substrate had advantages, such as low sheet resistance, high optical transmittance in visible range and stable mechanical properties. From the results, the AZO/Ag/AZO multilayer films (50/12/50 nm) demonstrated a sheet resistance of 11 ${\Omega}/{\square}$ and average transmittance of 87% in visible range (wavelength of 380-770 nm). Moreover, the multilayer showed stable mechanical properties compared to the single-layered AZO sample during the bending test due to the existence of the ductile Ag metal layer.

• Proceedings of the IEEK Conference
• /
• 2001.06e
• /
• pp.131-134
• /
• 2001

This paper proposes a stable control rule for nonlinear unicycle-type mobile robot. The control method uses a local error coordinate system, velocity and distance constants $\kappa$$\_$x/, $\kappa$$\_$y/, and he. Stability of control rule is proved Liapunov function. System input to the mobile robot is reference posture ($\chi$$\_$r/, y$\_$r/, $\theta$$\_$r/)/sup/ $\tau$/ and reference e velocity (ν$\_$r/,$\omega$$\_$r/)$\^$$\tau$/. System output of the mobi-le robot is velocity of driving wheels. We introduce limit velocity for preventing high initial speed. From simulation results, we can see the proposed control rule is stable.

• Journal of Korean Society of Environmental Engineers
• /
• v.33 no.3
• /
• pp.167-173
• /
• 2011

The Effects of external resistance on electrical properties such as current density, power density and coulombic efficiency were investigated in two-chamber type MFCs using a ferricyanide as reducing agent. A stable electricity was produced when a constant time elapsed after innoculation of mixed cultures into the anode compartment; voltages from 0.13 to 0.16 V was measured at $50{\Omega}$ of external resistance. When the external resistance was increased, the current density decreased and the power density rapidly increased and then slowly decreased. Big variation of electrical properties was observed in high-current density region due to the concentration loss related with substrate consumption in repeated experiments changing the external resistance. The maximum power density ($175.8mW/m^2$) and coulombic efficiency (46.1%) were obtained at $100{\Omega}$ of the external resistance which is nearest with the internal resistance ($134{\Omega}$) of MFC system.

• Journal of the Korean Vacuum Society
• /
• v.12 no.4
• /
• pp.218-227
• /
• 2003

Pd/Si/Ti/Pt and Pd/Si/Pd/Ti/Au ohmic contacts to n-type InCaAs were investigated for applications to AlGaAs/GaAs HBT emitter ohmic contacts. In the Pd/Si/Ti/Pt ohmic contact, as-deposited contact showed non-ohmic behavior, and high specific contact resistivity of $5\times10^{-3}\Omega\textrm{cm}^2$ was achieved by rapid thermal annealing at $375^{\circ}C$/10 sec. However, the specific contact resistivity decreased remarkably to $2\times10^{-6}\Omega\textrm{cm}^2$ by annealing at $425^{\circ}C$/10sec. In the Pd/Si/Pd/Ti/Au ohmic contact, minimum specific contact resistivity of $3.9\times10^{-7}\Omega\textrm{cm}^2$ was achieved by annealing at $400^{\circ}C$/20sec. In both ohmic contacts, low contact resistivity and non-spiking planar interface between ohmic materials and InGaAs were maintained. Therefore, these thermally stable ohmic contact systems are promising candidates for compound semiconductor devices. RF performance of the AlGaAs/GaAs HBT was also examined by employing the Pd/Si/Ti/Pt and Pd/Si/Pd/Ti/Au systems as emitter ohmic contacts. Cutoff frequencies were 63.9 ㎓ and 74.4 ㎓, respectively, and maximum oscillation frequencies were 50.1 ㎓ and 52.5 ㎓, respectively. It shows very successful high frequency operations.

• Journal of the Korean institute of surface engineering
• /
• v.25 no.6
• /
• pp.309-317
• /
• 1992

Evaluation of electroplated gold has been carried out to obtain the data base for electrical, mechanical and environmental properties for telecommunication component applications. Gold plating was performed to a various thickness of $0.1\mu\textrm{m}$ to 1.$25\mu\textrm{m}$ after Ni plating of $3\mu\textrm{m}$ on C52100 bronze. Electrical properties were evaluated by measuring contact resistance using 4-wire method under static contact and dynamic contact during wear. Reciprocating wear test was performed to study the wear behavior as well as failure of gold contacts. Environmental characteristics were evaluated by using salt spray testing and SO2 test. Hardness of soft gold film was measured to be 53KHN under 5g load. Friction coefficient was initially obtained to be 0.15 and 0.25 under 100g and 200g loads respectively, and then raised up to 0.8 with increasing reciprocating wear cycles. Static contact resistance was 2 to 3m$\Omega$ regardless of gold film thickness while drastic changes of contact resistance were occured upon stripping of the gold film during wear. The lifetime of contact wear showing stable contact resistance increased up to 6 times for $1\mu\textrm{m}$ thickness compared to that of$ 0.1\mu\textrm{m}$ thickness under 100g load. All gold plating appeared to be stable under salt atmosphere while only the gold plating over 1$\mu\textrm{m}$ was stable under SO2 atmosphere.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.59 no.12
• /
• pp.2268-2272
• /
• 2010

This letter presents that a rectenna can utilize more stable wireless power by using a new design dual band/dual polarization microstrip patch antenna and 2 stage voltage multiplier at 2.4 GHz band and 3.1 GHz band. The proposed antenna is a new microstrip patch antenna design to make impedance matching possible by using slotted capacitive coupling between the patch and $50\Omega$ feed line on a ground plane. Its advantage is that the size of the rectenna can be reduced by using $50\Omega$ feed line on the ground plane, which can be used efficiently. The dual band/dual polarization microstrip patch antenna shows circular polarization at 2.4 GHz band and linear polarization at 3.1 GHz band. Under -10 dB return loss, The dual band/dual polarization microstrip patch antenna obtains 340 MHz bandwidth as 2.23~2.57 GHz and 375 MHz bandwidth as 2.95~3.325 GHz. Also, 2 Stage Voltage multiplier is possible to operate at 2.4 GHz band and 3.1 GHz band. The designed retenna can usually obtain wireless power at both 3.1 GHz band, and 2.4 GHz band applications such as Wi-Fi, Bluetooth, Wireless LAN, etc. So more stable wireless power can be utilized at the same time.

• Journal of the Korean Institute of Telematics and Electronics
• /
• v.13 no.6
• /
• pp.7-11
• /
• 1976

A voltage-stable negative resistance circuit with operational amplifier is proposed, and circuit analysis is given all the input voltage range. The behavior of the v-i characteristics in the nogative resistance region is devided into two causes, and top points in the input v-i characteristics of the circuit is analyzed with them. Experimental results of the v-i characteristics of the proposed circuit has a good linearity in the negative region with negative resistance, -86$\Omega$~-833$\Omega$ for the input voltage, $\pm$ 1~$\pm$ 5 colts. The v-i characteristics of the circuit in all the input voltage range is discussed.