• Title/Summary/Keyword: $^7Li$

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Integrated-Optic Electric-Field Sensor Utilizing a Ti:LiNbO3 Y-fed Balanced-Bridge Mach-Zehnder Interferometric Modulator With a Segmented Dipole Antenna

  • Jung, Hongsik
    • Journal of the Optical Society of Korea
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    • v.18 no.6
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    • pp.739-745
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    • 2014
  • We have demonstrated a $Ti:LiNbO_3$ electro-optic electric-field sensor utilizing a $1{\times}2$ Y-fed balanced-bridge Mach-Zehnder interferometric (YBB-MZI) modulator, which uses a 3-dB directional coupler at the output and has two complementary output waveguides. A dc switching voltage of ~25 V and an extinction ratio of ~12.5 dB are observed at a wavelength of $1.3{\mu}m$. For a 20 dBm rf input power, the minimum detectable electric fields are ~8.21, 7.24, and ~13.3 V/m, corresponding to dynamic ranges of ~10, ~12, and ~7 dB at frequencies of 10, 30, and 50 MHz respectively. The sensors exhibit almost linear response for an applied electric-field intensity from 0.29 V/m to 29.8 V/m.

Solidification Structure of Al-2.7wt%Li Alloys by Cooling Rate Controlled (냉각속도에 따른 Al-2.7wt%Li 합금계의 응고조직)

  • Shim, Deung-Seub;Choe, Jeong-Cheol;Cho, Hyung-Ho;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.11 no.5
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    • pp.398-405
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    • 1991
  • Al-Li alloy has a high strength with low density. Practically this alloy should use by the material which made from the rapid solidification. Therefore we examine the solidification structures of alloy with cooling rate. According to cooling rate increased, grain size and secondary dendrite arm spacing were smaller. Also grain size was further smaller by Zr added. To obtain more fine solidification structure, rapid solidification by single roll melt spinning was performed. According to higher wheel speed, cooling rate increased and cell size was smaller. Because of locally different cooling rate, different cell size was obtained in same specimen. More than cooling rate $10^6^{\circ}C$ /sec, zone A(insensible zone to corrosion)was obtained.

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Tunable properties and low temperature sintering of BST thick films added ${Li_2}{CO_3}$ (${Li_2}{CO_3}$첨가에 의한 $BaSr(TiO_3)$의 저온 소결과 가변유전 특성)

  • Kim, In-Sung;Min, Bok-Ki;Jeong, Soon-Jong;Song, Jae-Sung;Jeon, So-Hyun
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.7-9
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    • 2006
  • $(BaSr)TiO_3$ thick films were prepared by tape casting method using $BaTiO_3$ and $SrTiO_3$ powder slurry in order to investigate dielectric properties and low temperature sintering. Sintering density was $5.7\;g/cm^3$ and the BST sample exhibited the maximum dielectric constant, tunability at temperatures near phase transition point. The dielectric constant was increased and curie temperature was shifted to higher temperature with increasing of annealing temperature.

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Effects of Li$^+$ and Ag$^+$ Ions on the Rotational Barrier in Acetamide and propionamide System

  • Kwon, Dae-Keun;Choi, Young-Sang;Yoon, Chang-Ju
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.1-5
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    • 1986
  • The influences of $LiNO_3\;and\;AgNO_3$ on the N-C(O) rotational barrier of N,N-dimethylacetamide and N,N-dimethylpropionamide have been investigated. The rotational activation free energy $({\Delta}G^{\neq})\;for\;Li^{+}$-amide complexes is found to increase with increasing salt concentration. On the other hand, that for $Ag^+$-amide complexes increases in the presence of $Ag^+$ ion up to 0.25 M ion concentration and then decreases as the concentration of $Ag^+$ ion is further increased. Such an unusual behavior of $Ag^+$-amide complexes has been interpreted in terms of ion-pairing and diluent effect on the amides. However, $^{13}C$ nmr chemical shift data for the amides have shown that both of these ions interact primarily with the carbonyl group in amides.

Electrochemical Properties of LixCoyNi1-yO2 Prepared by Citrate Sol0Gel Method

  • 장순호;강성구;장기호
    • Bulletin of the Korean Chemical Society
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    • v.18 no.1
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    • pp.61-65
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    • 1997
  • The electrochemical properties of LixCoyNi1-yO2 compounds (y=0.1, 0.3, 0.5, 0.7, 1.0) prepared by citrate sol-gel method have been investigated. The LixCoyNi1-yO2 compounds were annealed at 850 ℃ for 20 h after preheating at 650 ℃ for 6 h, in air. The x-ray diffraction (XRD) patterns for LixCoyNi1-yO2 have shown that these compounds have a well developed layered structure (R&bar{3} m). From the scanning electron microscopy of LixCoyNi1-yO2, particle size was estimated less than 5 μm. The Li//LixCoyNi1-yO2 electrochemical cell consists of Li metal anode and 1 M LiClO4-propylene carbonate (PC) solution as the electrolyte. The differences in intercalation rate of the LixCoyNi1-yO2 in the first charge/discharge cycle were less than 0.05 e-. The first discharge capacities of LixCoO2 and LixCo0.3Ni0.7O2 were ∼130 mAh/g and ∼160 mAh/g, respectively.

The Novel Synthetic Route to Li$Co_{y}Ni_{1-y}O_{2}$ as a Cathode Material in Lithium Secondary Batteries

  • Gang, Seong Gu;Ryu, Gwang Seon;Jang, Sun Ho;Park, Sin Jeong
    • Bulletin of the Korean Chemical Society
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    • v.22 no.12
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    • pp.1328-1332
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    • 2001
  • The structure and electrochemical properties of the LixCoyNi1-yO2 (y=0.1, 0.3, 0.5, 0.7, 1.0) system synthesized by solid state reaction with various starting materials have been investigated to optimize the characteristics and synthetic conditions of the LixCoyNi1-yO2. The first discharge capacities of LixCoyNi1-yO2 are 60 mAh/g-180 mAh/g with synthetic conditions. Among them, the LixNi0.7Co0.3O2, which was prepared with LiOH, NiO, and Co3O4 at $850^{\circ}C$, had the best electrochemical properties. The first discharge capacity of the compound was 180 mAh/g.

A New Cycloartane Glycoside from Camptosorus sibiricus Rupr.

  • Ning-Li;Xian-Li;Peng-Zhang;Li, Zhan-Lin;Yang, Shi-Lin;Wang, Jin-Hui
    • Archives of Pharmacal Research
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    • v.27 no.7
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    • pp.727-729
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    • 2004
  • A new cycloartane glycoside was isolated from the dried whole herbs of Camptosorus sibiricus Rupr By means of chemical (hydrolysis) and spectroscopic methods (IR, 1D, and 2D NMR, ESI-MS), the structure was established as $3{\beta}$, $7{\beta}$, $24{\beta}$, 25, 30-pentahydroxycycloartane-3-O-${\beta}$-D-glucopyranoside-24-O-${\beta}$-D-glucopyranoside (1).

Shielding analyses supporting the Lithium loop design and safety assessments in IFMIF-DONES

  • Gediminas Stankunas ;Yuefeng Qiu ;Francesco Saverio Nitti ;Juan Carlos Marugan
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1210-1217
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    • 2023
  • The assessment of radiation fields in the lithium loop pipes and dump tank during the operation were performed for International Fusion Materials Irradiation Facility - DEMO-Oriented NEutron Source (IFMIF-DONES) in order to obtain the radiation dose-rate maps in the component surroundings. Variance reduction techniques such as weight window mesh (produced with the ADVANTG code) were applied to bring the statistical uncertainty down to a reasonable level. The biological dose was given in the study, and potential shielding optimization is suggested and more thoroughly evaluated. The MCNP Monte Carlo was used to simulate a gamma particle transport for radiation shielding purposes for the current Li Systems' design. In addition, the shielding efficiency was identified for the Impurity Control System components and the dump tank. The analysis reported in this paper takes into account the radiation decay source from and activated corrosion products (ACPs), which is created by d-Li interaction. As a consequence, the radiation (resulting from ACPs and Be-7) shielding calculations have been carried out for safety considerations.

FBW7 Upregulation Enhances Cisplatin Cytotoxicity in Non-small Cell Lung Cancer Cells

  • Yu, Hao-Gang;Wei, Wei;Xia, Li-Hong;Han, Wei-Li;Zhao, Peng;Wu, Sheng-Jun;Li, Wei-Dong;Chen, Wei
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.11
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    • pp.6321-6326
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    • 2013
  • Introduction: Lung cancer is extremely harmful to human health and has one of the highest worldwide incidences of all malignant tumors. Approximately 80% of lung cancers are classified as non-small cell lung cancers (NSCLCs). Cisplatin-based multidrug chemotherapy regimen is standard for such lesions, but drug resistance is an increasing problem. F-box/WD repeat-containing protein 7 (FBW7) is a member of the F-box protein family that regulates cell cycle progression, and cell growth and differentiation. FBW7 also functions as a tumor suppressor. Methods: We used cell viability assays, Western blotting, and immunofluorescence combined with siRNA interference or plasmid transfection to investigate the underlying mechanism of cisplatin resistance in NSCLC cells. Results: We found that FBW7 upregulation significantly increased cisplatin chemosensitivity and that cells expressing low levels of FBW7, such as NCI-H1299 cells, have a mesenchymal phenotype. Furthermore, siRNA-mediated silencing or plasmid-mediated upregulation of FBW7 resulted in altered epithelial-mesenchymal transition (EMT) patterns in NSCLC cells. These data support a role for FBW7 in regulating the EMT in NSCLC cells. Conclusion: FBW7 is a potential drug target for combating drug resistance and regulating the EMT in NSCLC cells.

Electrochemical Characteristics of Transition Metal Pyrophosphate as Negative Electrode Materials through Solid-state Reaction (고상법으로 합성된 리튬이온 이차전지용 음극물질로서 전이금속 피로인산화물의 전기화학적 특성)

  • Hong, Min Young;An, Sang-Jo;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.23 no.4
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    • pp.105-112
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    • 2020
  • Transition metal oxide, which undergoes a conversion reaction in the negative electrode material for a lithium-ion batteries, has a high specific capacity, but still has several critical problems. In this study, manganese pyrophosphate (Mn2P2O7), nickel pyrophosphate (Ni2P2O7), and carbon composite materials with pyrophosphates as novel negative electrode materials instead of transition metal oxide, are synthesized through simple solid-state reaction. The initial reversible capacity of Mn2P2O7 and Ni2P2O7 are 333 and 340 mAh g-1, and when the composite materials are composed with carbon, the reversible capacity increases to 433 and 387 mAh g-1, respectively. The initial Coulombic efficiency is also improved by about 10%. The Mn2P2O7 and carbon composite material has the highest initial capacity and efficiency, and has the best cycle performance. Mn2P2O7 containing polyanion, has a lower specific capacity due to the large mass of polyanion compared to MnO (manganese oxide). However, since Mn2P2O7 shows a voltage curve with a slope, the charging (lithiation) voltage increases from 0.51 to 0.57 V (vs. Li/Li+), and the discharge (delithiation) voltage decreases from 1.15 to 1.01 V (vs. Li/Li+). Therefore, the voltage efficiency of the cell is improved because the voltage difference between charging and discharging is greatly reduced from 0.64 to 0.44 V, and the operating voltage of the full cell increases because the negative electrode potential is lowered during the discharging process.