• 한국해양공학회지
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• 제16권3호
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• pp.54-58
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• 2002

This study investigates a relationship between fracture mechanics parameters (Stress Intensity Factor Range: ΔK, Maximum Stress Intensity Factor; Kmax) and X-ray parameters (residual stress:$\sigma$r half-value breadth: B) for SG365 steel at elevated temperature up to 30$0^{\circ}C$. The fatigue crack propagation test were carried out and X-ray diffraction technique according to the direction of crack length was applied to fatigue fractured surface. The residual stress on the fracture surface was found to increase at low ΔK region, to reach a maximum value at a certain value of Kmax or ΔK and then to decrease. Residual stress was independent of stress ratio by arrangement of ΔK and half value breadth were independent of the arrangement of Kmax. The equation of $\sigma$r-ΔK was established by the experimental data. therefore, fracture mechanics parameters could be estimated by the measurement of X-ray parameters.

• Bulletin of the Korean Chemical Society
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• 제32권12호
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• pp.4304-4308
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• 2011

Kinetic studies of the reactions of O,O-dimethyl Z-S-aryl phosphorothioates with X-benzylamines have been carried out in dimethyl sulfoxide at $85.0^{\circ}C$. The Hammett (log $k_2$ vs ${\sigma}_X$) and Br$\ddot{o}$nsted [log $k_2$ vs $pK_a$(X)] plots for substituent X variations in the nucleophiles are discrete with a break region between 4-Me and H, while the Hammett plots (log $k_2$ vs ${\sigma}_Z$) for substituent Z variations in the leaving groups are linear. The sign of the cross-interaction constant (${\rho}_{XZ}$) is positive for both the strongly and weakly basic nucleophiles. Greater magnitude of ${\rho}_{XZ}$ (= 2.54) value is observed with the weakly basic nucleophiles compared to with the strongly basic nucleophiles (${\rho}_{XZ}$ = 0.17). The deuterium kinetic isotope effects ($k_H/k_D$) involving deuterated benzylamines [$XC_6H_4CH_2ND_2$] are primary normal ($k_H/k_D$ > 1). The proposed mechanism is a stepwise with a rate-limiting leaving group expulsion from the intermediate involving a frontside nucleophilic attack with a hydrogen bonded, four-center-type transition state for both the strongly and weakly basic nucleophiles.

• 한국수산과학회지
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• 제11권2호
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• pp.49-54
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• 1978

한국 동해안해역에서 하계에 출현하는 냉수괴의 생성기구를 해양화학적인 측면에서 검토한 결과를 요약하면 다음과 같다. 1. 동해연안의 냉수괴출현해역의 인산염과 용존산계의 특수한 관계를 조사한 결과 동해남부 연안해역인 감포부근 해역에서만 용승현상을 인정할 수 있었으나 그 이북 동해중부해역에서는 용승현상을 인정할 수 없었다. 2. $\sigma_t-O_2$ diagram에 의해 동해연안해역의 구성수괴를 분석하면 T-S diagram 으로는 구별하기 어려운 북한한류계수와 일본해고유냉수를 구별할 수 있었다. 3. 동해남부 연안해역을 제외한 동해중부 연안해역에 출현하는 냉수괴의 기원은 일본해고유냉수의 용승에 의한 것이 아니고, 북한한류가 안안을 따라 남하하는 현상 때문으로 보인다.

• 자원환경지질
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• 제29권2호
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• pp.151-158
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• 1996

Rb-Sr isochron ages, Sr and Nd isotopic compositions were determined for late Cretaceous granophyre on the Haenam-Wando areas, the southwestern part of the Yeongdong-Kwangju depression in Korea. The granophyre in the Haenam-Wando areas are distributed in the shape of a resurgent cauldron. Five samples of Haenam granophyre give a defined Rb-Sr whole rock isochron age of $75.7{\pm}7.2Ma$ and Sr initial ratio of $0.70826{\pm}0.00020(2{\sigma})$. Plagioclase, orthoclase and whole rock of Haenam granophyre give a defined Rb-Sr whole rock-mineral isochron age of $67.0{\pm}5.8Ma$ and Sr initial ratio of $0.708880{\pm}0.00028(2{\sigma})$. Five samples of Wando granophyre give a defined Rb-Sr whole rock isochron age of $70.6{\pm}3.3Ma$ and Sr initial ratio of $0.70850{\pm}0.00088(2{\sigma})$. Eight samples of Haenam granophyre give a defined Nd isotope ratios of 0.512180~0.512259 and ${\varepsilon}Nd$ (T) values of -6.53~-8.15, ${\varepsilon}Sr$ (T) values of +51.49~+66.48 and model age of 1.28~1.60 Ga. Four samples of Wando granophyre give a defined Nd isotope ratios of 0.512228~0.512289 and ${\varepsilon}Nd$ (T) values of -6.74~-8.00, ${\varepsilon}Sr$ (T) values of +54.88~+78.98 and model age of 1.14~1.42 Ga.

• 천문학회보
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• 제42권2호
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• pp.54.1-54.1
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• 2017

Intrinsic alignments (IA), the coherent alignment of intrinsic galaxy orientations, can be a source of a systematic error of weak lensing surveys. The redshift evolution of IA also contains information about the physics of galaxy formation and evolution. We present the first measurement of IA at high redshift, z~1.4, using the spectroscopic catalog of blue star-forming galaxies of the FastSound redshift survey, with the galaxy shape information from the Canada-Hawaii-France telescope lensing survey. The IA signal is consistent with zero with power-law amplitudes fitted to the projected correlation functions for density-shape and shape-shape correlation components, $A_{\delta+}=-0.0040\pm 0.0754$ and $A_{++}=-0.0159\pm 0.0271$, respectively. These results are consistent with those obtained from blue galaxies at lower redshifts (e.g., $A_{\delta+}=0.0035_{-0.0389}^{+0.0387}$ and $A_{++}=0.0045_{-0.0168}^{+0.0166}$ at z=0.51 from the WiggleZ survey), suggesting no strong redshift evolution of IA. The upper limit of the constrained IA amplitude corresponds to a few percent contamination to the weak-lensing shear power spectrum, resulting in systematic uncertainties on the cosmological parameter estimations by $-0.035<\Delta \sigma_8<0.026$ and $-0.025<\Delta \Omega_{\mathrm m}<0.019$.

• 한국세라믹학회지
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• 제53권3호
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• pp.301-305
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• 2016

We investigate proton conduction in a nonstoichiometric ${\Sigma}3$ $BaZrO_3$ (210)[001] tilt grain boundary using density functional theory (DFT). We employ the space charge layer (SCL) and structural disorder (SD) models with the introduction of protons and oxygen vacancies into the system. The segregation energies of proton and oxygen vacancy are determined as -0.70 and -0.54 eV, respectively. Based on this data, we obtain a Schottky barrier height of 0.52 V and defect concentrations at 600K, in agreement with the reported experimental values. We calculate the energy barrier for proton migration across the grain boundary core as 0.61 eV, from which we derive proton mobility. We also obtain the proton conductivity from the knowledge of proton concentration and mobility. We find that the calculated conductivity of the nonstoichiometric grain boundary is similar to those of the stoichiometric ones in the literature.

• 한국안전학회지
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• 제13권2호
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• pp.54-64
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• 1998

This study was initiated to examine the stress and deformation characteristics of the pipelines which were subjected to various environmental conditions in order to confirm their integrity. As the part of them, this paper presents the analysis results for the effect of ground subsidence combined with main loads on buried natural gas pipelines. The ground subsidence which can occur for buried gas pipeline has been classified to the three cases. Finite element method was used to analyze the effect of ground subsidences on pipeline of 26 inch(0.660 m) and 30 inch(0.762 m) diameter used as high pressure ($70 kg_f/cm^2(6.86 MPa)$) main pipelines of KOGAS. This paper shows the result of stress analysis for the pipelines subjected to those three case ground subsidence. Comparing these results with safety criterion of KOGAS(0.9 $\sigma_y$), maximum allowable settlement and loads have been calculated.

• Bulletin of the Korean Chemical Society
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• 제33권10호
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• pp.3253-3257
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• 2012

Second-order rate constants for the reactions of phenyl Y-substituted-phenyl carbonates 5a-g with Z-substituted-phenoxides ($k_{Z-PhO^-}$) have been measured spectrophotometrically in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. 4-Nitrophenyl phenyl carbonate (5e) is up to 235 times more reactive than 4-nitrophenyl benzoate (4e). The Br$\o$nsted-type plot for the reactions of 5e with Z-substituted-phenoxides is linear with ${\beta}_{nuc}=0.54$, which is typical for reactions reported previously to proceed through a concerted mechanism. Hammett plots correlated with ${\sigma}^o$ and ${\sigma}^-$ constants for the reactions of 5a-f with 4-chlorophenoxide exhibit highly scattered points. In contrast, the Yukawa-Tsuno plot results in an excellent linear correlation with ${\rho}_Y=1.51$ and r = 0.52, indicating that the leaving-group departure occurs at the rate-determining step (RDS). A stepwise mechanism, in which leaving-group departure occurs at RDS, has been excluded since the incoming 4-$ClPhO^-$ is more basic and a poorer nucleofuge than the leaving Y-substituted-phenoxides. Thus, the reaction has been concluded to proceed through a concerted mechanism. Our study has shown that the modification of the nonleaving group from benzoyl to phenyloxycarbonyl causes a change in the reaction mechanism (i.e., from a stepwise mechanism to a concerted pathway) as well as an increase in the reactivity.

• 천문학회지
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• 제49권6호
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• pp.255-259
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• 2016

We estimate the fractal dimension of the ${\rho}$ Ophiuchus Molecular Cloud Complex, associated with star forming regions. We selected a cube (${\upsilon}$, l, b) database, obtained with J = 1-0 transition lines of $^{12}CO$ and $^{13}CO$ at a resolution of 22" using a multibeam receiver system on the 14-m telescope of the Five College Radio Astronomy Observatory. Using a code developed within IRAF, we identified slice-clouds with two threshold temperatures to estimate the fractal dimension. With threshold temperatures of 2.25 K ($3{\sigma}$) and 3.75 K ($5{\sigma}$), the fractal dimension of the target cloud is estimated to be D = 1.52-1.54, where $P{\propto}A^{D/2}$, which is larger than previous results. We suggest that the sampling rate (spatial resolution) of observed data must be an important parameter when estimating the fractal dimension, and that narrower or wider dispersion around an arbitrary fit line and the intercepts at NP = 100 should be checked whether they relate to firms noise level or characteristic structure of the target cloud. This issue could be investigated by analysing several high resolution databases with different quality (low or moderate sensitivity).

• Asian Pacific Journal of Cancer Prevention
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• 제14권3호
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• pp.1851-1863
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• 2013

Diurnal variation of particulate polycyclic aromatic hydrocarbons (PAHs) was investigated by collecting PM10 at three different sampling altitudes using high buildings in the city center of Chiang-Mai, Thailand, during the relatively cold period in late February 2008. At site-1 (12 m above ground level), B[a]P concentrations ranged from 30.3-1,673 pg $m^{-3}$ with an average of $506{\pm}477\;pg\;m^{-3}$ contributing on average, $8.09{\pm}8.69%$ to ${\Sigma}PAHs$. Ind and B[b]F concentrations varied from 54.6 to 4,579 pg $m^{-3}$ and from 80.7 to 2,292 pg $m^{-3}$ with the highest average of $1,187{\pm}1,058\;pg\;m^{-3}$ and $963{\pm}656\;pg\;m^{-3}$, contributing on average, $19.0{\pm}19.3%$ and $15.4{\pm}12.0%$ to ${\Sigma}PAHs$, respectively. Morning maxima were predominantly detected in all observatory sites, which can be described by typical diurnal variations of traffic flow in Chiang-Mai City, showing a morning peak between 6 AM. and 9 AM. Despite the fact that most monitoring sites might be subjected to specific-site impacts, it could be seen that PAH profiles in Site-1 and Site-2 were astonishingly homogeneous. The lack of differences suggests that the source signatures of several PAHs become less distinct possibly due to the impacts of traffic and cooking emissions from ground level.