• Title/Summary/Keyword: $\delta^{15}N$

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Mesothermal Gold Vein Mineralization of the Seolhwa Mine: Fluid Inclusion and Sulfur Isotope Studies (설화 광산의 중열수 금광화작용: 유체포유물 및 황동위원소 연구)

  • Yun, Seong-Taek;So, Chil-Sup;Choi, Seon-Gyu;Choi, Sang-Hoon;Heo, Chul-Heo
    • Journal of the Korean earth science society
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    • v.22 no.4
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    • pp.278-291
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    • 2001
  • Mesothermal gold vein minerals of the Seolhwa mine were deposited in a single stage of massive quartz veins which filled the mainly NE-trending fault shear zones exclusively in the granitoid of the Gyeonggi Massif. The Seolhwa mesothermal gold mineralization is spatially associated with the Jurassic granitoid of 161 Ma. The vein quartz contains three main types of fluid inclusions at 25$^{\circ}$C: 1) low-salinity (< 5 wt.% NaCl), liquid CO$_{2}$-bearing, type IV inclusion; 2) gas-rich (> 70 vol.%), aqueous type II inclusions; 3) aqueous type I inclusions (0${\sim}$15 wt.% NaCl) containing small amounts of CO$_{2}$. The H$_{2}$O-CO$_{2}-CH$_{4}$-N$_{2}$-NaCl inclusions represent immiscible fluids trapped earlier along the solvurs curve at temperatures from 430$^{\circ}$ to 250$^{\circ}$C and pressures of 1 kbars. Detailed fluid inclusion chronologies may suggest a progressive decrease in pressure during the auriferous mineralization. The aqueous inclusion fluids represent either later fluids evelved through extensive fluid unmixing (CO$_{2}-CH$_{4}$ effervescence) from a homogeneous H$_{2}$O-CO$_{2}-CH$_{4}$-N$_{2}$-NaCl fluid due to decreases in temperature and pressure, or the influence of deep circulated meteoric waters possibly related to uplift and unloading of the mineralizing suites. The initial fluids were homogeneous containing H$_{2}$O-CO$_{2}-CH$_{4}$-N$_{2}$-NaCl components and the following properties: the initital temperature of >250$^{\circ}$ to 430$^{\circ}$C, X$_{CO}\;_{2}$ of 0.16 to 0.62, 5 to 14 mole% CH$_{4}$, 0.06 to 0.3 mole% N$_{2}$ and salinities of 0.4 to 4.9 wt.% NaCl. The T-X data for the Seolhwa gold mine may suggest that the Seolhwa auriferous hydrothermal system has been probably originated from adjacent granitic melt which facilitated the CH$_{4}$ formation and resulted in a reduced fluid state evidenced by the predominance of pyrrhotite. The dominance of negative ${\delta}\;^{34}$S values of sulfides (-0.6 to 1.4$%_o$o) are consistent with their deep igneous source.

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Genetics and Breeding for Modified Fatty Acid Profile in Soybean Seed Oil

  • Lee, Jeong-Dong;Bilyeu, Kristin D.;Shannon, James Grover
    • Journal of Crop Science and Biotechnology
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    • v.10 no.4
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    • pp.201-210
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    • 2007
  • Soybean [Glycine max(L.) Merr.] oil is versatile and used in many products. Modifying the fatty acid profile would make soy oil more functional in food and other products. The ideal oil with the most end uses would have saturates(palmitic + stearic acids) reduced from 15 to < 7%, oleic acid increased from 23 to > 55%, and linolenic acid reduced from 8 to < 3%. Reduced palmitic acid(16:0) is conditioned by three or more recessive alleles at the Fap locus. QTLs for reduced palmitic acid have mapped to linkage groups(LGs) A1, A2, B2, H, J, and L. Genes at the Fad locus control oleic acid content(18:1). Six QTLs($R^2$=4-25%) for increased 18:1 in N00-3350(50 to 60% 18:1) explained four to 25% of the phenotypic variation. M23, a Japanese mutant line with 40 to 50% 18:1 is controlled by a single recessive gene, ol. A candidate gene for FAD2-1A can be used in marker-assisted breeding for high 18:1 from M23. Low linolenic acid(18:3) is desirable in soy oil to reduce hydrogenation and trans-fat accumulation. Three independent recessive genes affecting omega-3 fatty acid desaturase enzyme activity are responsible for the lower 18:3 content in soybeans. Linolenic acid can be reduced from 8 to about 4, 2, and 1% from copies of one, two, or three genes, respectively. Using a candidate gene approach perfect markers for three microsomal omega-3 desaturase genes have been characterized and can readily be used in for marker assisted selection in breeding for low 18:3.

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Gold and Silver Mineralization in the Yonghwa Mine (용화광산(龍化鑛山)의 금은광화작용(金銀鑛化作用))

  • Youn, Seok-Tai;Park, Hee-In
    • Economic and Environmental Geology
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    • v.24 no.2
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    • pp.107-129
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    • 1991
  • The Yonghwa gold-silver deposits are emplaced along $N15^{\circ}{\sim}25^{\circ}W$ trending fissures in middle Cretaceous porphyritic granite or Precambrian Sobaegsan gneiss complex. The results of paragenetic studies suggest that vein filling can be subdivided into four identifiable stages; state I: the main sulfide stage, characterized by base-metal sulfide minerals, iron oxides and minor electrum, stage II: electrum stage, stage III: electrum and silver-bearing sulfosalts stage, stage IV: post ore stage of carbonates and quartz. The ore mineralogy suggests that depositional temperature of the formation of the gold and silver minerals are estimated as 200 to $250^{\circ}C$ and 140 to $180^{\circ}C$, respectively. Sulfur fugacity of the formation of the gold and silver minerals are estimated as $10^{-14.0}$ to $10^{-12.2}$ atm and $10^{-18.5}$ to $10^{-17.2}$ atm, respectively. A consideration of the pressure regime during ore deposition bases on the fluid inclusion evidence of boiling suggests lithostatic pressure of less than 180 bars. This range of pressure indicate that vein system lay at depth of 700m below the surface at the time during mineralization. Salinities of ore-bearing fluids range from 0.4 to 6.9 wt.% equivalent NaCl. The sulfur and carbon isotopic data reveal that these elements were probably derived from a deep-seated source. The ${\delta}^{18}O$ of the hydrothermal fluid was determined from ${\delta}^{18}O$ values of quartz and calcite. Oxygen and hydrogen isotopic studies reveal that meteoric water dominate over ore-bearing fluid.

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Determination of the Origin of Particulate Organic Matter at the Estuary of Youngsan River using Stable Isotope Ratios (${\delta}^{13}C$, ${\delta}^{15}N$) (탄소 및 질소 안정동위원소 비를 이용한 영산강하구역 유기물 기원 추정 연구)

  • Lee, Yeon-Jung;Jeong, Byung-Kwan;Shin, Yong-Sik;Kim, Sung-Hwan;Shin, Kyung-Hoon
    • Korean Journal of Ecology and Environment
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    • v.46 no.2
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    • pp.175-184
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    • 2013
  • Organic carbon and total nitrogen stable isotope ratios of suspended materials were determined at 3 stations (from Mongtan Bridge to Youngsan river estuary barrage) (n=6, each) from November 2008 to August 2009, in order to understand the origin of particulate organic matter at the Estuary of Youngsan River. Allochthonous organic matter, ammonia-N and silicate were increased after heavy rain (in August). Carbon isotope ratios were significantly different between stations in November and August, and it was possible to determine the origin of organic matter. The heavier nitrogen isotope ratios, as well as higher phosphate concentrations, were found in November than other sampling times. Livestock wastewater and farmland input was likely the main causes of these high values. In addition, YS3 station, the nearest site to estuary barrage, appears to be affected by a substantial amount of livestock wastewater and farmland input, considering that nitrogen isotope ratios were heavier than those at the upper sites. These results suggest that the analysis of stable isotope ratios is a simple but useful tool for the determination of organic matter origin in aquatic environments.

Classification by Zooplankton Inhabit Character and Freshwater Microbial Food Web: Importance of Epiphytic Zooplankton as Energy Source for High-Level Predator (동물플랑크톤의 서식 특성에 따른 분류와 먹이망: 상위포식자의 에너지원으로서 부착성 동물플랑크톤의 중요성)

  • Choi, Jong-Yun;La, Geung-Hwan;Jeong, Kwang-Seuk;Kim, Seong-Ki;Chang, Kwang-Hyeon;Joo, Gea-Jae
    • Korean Journal of Ecology and Environment
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    • v.45 no.4
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    • pp.444-452
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    • 2012
  • We conducted a comprehensive monitoring for freshwater food web in a wetland system (Jangcheok Lake), from May to October, 2011. Monthly sampling for zooplankton, fish as well as organic matters, was implemented. In order to understand the food web structure and energy flow, we applied stable isotope analysis to the collected samples, based on ${\delta}^{13}C$ and ${\delta}^{15}N$ values of epiphytic particulate organic matter(EPOM) and particulate organic matter (POM), epiphytic and planktonic zooplankton, fish (Lepomis macrochirus). In the study site, epiphytic and planktonic zooplankton was 24 and 30 species, respectively, and coincidence species between epiphytic and planktonic zooplankton were 20 species. Epiphytic zooplankton were more abundant during the spring and early summer (May to July); however, planktonic zooplankton were more abundant during the autumn (September to October) season. Stable isotope analysis revealed that fish and epiphytic zooplankton had seasonal variations on their food sources. EPOM largely contributed epiphytic zooplankton in spring (May), but increasing contribution of POM in autumn (September) was detected. However, planktonic zooplankton depended on only POM in both seasons. Fish utilized both epiphytic and planktonic zooplankton, but small sized (1~3 cm), fish preferred epiphytic zooplankton, where as larger sized (4~7 cm) fish tended to consume planktonic zooplankton, and epiphytic zooplankton had important role in energy transfer. This pattern was clear when results of spring and autumn stable isotope analysis were compared. From the results of this study, we confirmed that wetlands ecosystem supported various epiphytic and planktonic zooplankton species, they depend on other food items, respectively. L. macrochirus also showed a difference of food source according to the body size, they depend on seasonal density change of zooplankton. In particular, epiphytic zooplankton was very important for growth and development of young fish in the spring.

Optical Long-slit Spectroscopy of Parsec-scale Jets from DG Tauri

  • Oh, Heeyoung;Pyo, Tae-Soo;Yuk, In-Soo;Park, Byeong-Gon
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.1
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    • pp.69.1-69.1
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    • 2015
  • Classical T Tauri star DG Tau is suggested as the driving source of parsec-scale jet which expands up to 650" (0.4 pc). To investigate the kinematics and physical properties of the jet, we have obtained the optical emission lines of $H{\alpha}$, [O I] ${\lambda}{\lambda}$6300, 6363, [N II] ${\lambda}{\lambda}$6548,6584, and [S II] ${\lambda}{\lambda}$6716, 6731 from HH 158 ad HH 702. The radial velocity of HH 158 is in the range of -50 to $-250km\;s^{-1}$. For HH 702, located at 650" from the source, it shows ~ $-80km\;s^{-1}$. In HH 158, the electron density ($n_e$) close to the star is ${\sim}10^4cm^{-3}$ and it decreases to ${\sim}10^2cm^{-3}$ at 14" away from the star. Electron temperature ($T_e$) is decreasing from >15,000 K to ~5,000 K with distance. Ionization fraction ($x_e$) is increasing from almost zero to > 0.4 along the distance. In HH 702, the values of $n_e$, $T_e$, and $x_e$ are similar to those estimated at 14" from source, where knot C of HH 158 is located. This may imply that the physical properties of the knot could persist through such a long distance in the space, and the gas could be re-excited by the shock during propagation of the jet. On the other hand, we cannot avoid the possibility that HH 702 is driven by another source rather than DG Tau because HH 158 and HH 702 show somewhat large difference in their inclination angles (${\Delta}i=21-35^{\circ}$).

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The effect of tooth bleaching agent contained 15% carbamide peroxide on the color, microhardness and surface roughness of tooth-colored restorative materials by using pH cycling model (pH 순환 모형을 이용하여 15% 과산화요소를 함유한 치아미백제가 심미수복재의 색, 미세경도 및 거칠기에 미치는 영향)

  • Park, So-Young;Song, Min-Ji;Jeon, Su-Young;Kim, Sun-Young;Shim, Youn-Soo
    • Journal of Korean society of Dental Hygiene
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    • v.13 no.2
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    • pp.351-360
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    • 2013
  • Objectives : The purpose of this study was to evaluate the effects of tooth bleaching agent contained 15% carbamide peroxide on the color, microhardness and surface roughness of tooth-colored restorative materials by using pH cycling model. Methods : Four types of tooth-colored restorative materials, including a composite resin(Filtek Z350 ; Z350), a flowable composite resin(Filtek P60 : P60), a compomer(Dyract$^{(R)}$ AP ; DY), and a glass-ionomer cement(KetacTM Molar Easymix ; KM). were used in the study. Eighty-eight specimens of each material were fabricated, randomly divided into two groups(n=44): experimental group(15% carbamide peroxide) and control group(distilled water). These groups were then divided into four subgroups(n=11). All groups were bleached 4 hours per day for 14 days using pH cycling model. The authors measured the color, microhardness, and roughness of the specimens before and after bleaching. The data were analyzed with ANOVA and T-test. Results : Z350 and P60 showed a slight color change(${\Delta}E^*$), whereas DY and KM showed significantly color change(p<0.05). Among them, the greatest color change was observed in DY. Percentage microhardness loss(PML) of the distilled water group was 1.8 to 5.1%, and 15% peroxide peroxide group was 5.0 to 25.2%. Microhardness of DY and KM showed a statistically significant decrease(p<0.05). Roughness was increased in all groups after bleaching. Z350 and P60 does not have a significant difference(p>0.05), however DY and KM significantly increased more than the 0.2 ${\mu}m$(p<0.05). Conclusions : The effects of bleaching on restorative materials were material dependent. It is necessary to consider the type of the material before starting the treatment.

About Short-stacking Effect of Illite-smectite Mixed Layers (일라이트-스멕타이트 혼합층광물의 단범위적층효과에 대한 고찰)

  • Kang, Il-Mo
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.71-78
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    • 2012
  • Illite-smectite mixed layers (I-S) occurring authigenically in diagenetic and hydrothermal environments reacts toward more illite-rich phases as temperature and potassium ion concentration increase. For that reason, I-S is often used as geothermometry and/or geochronometry at the field of hydrocarbons or ore minerals exploration. Generally, I-S shows X-ray powder diffraction (XRD) patterns of ultra-thin lamellar structures, which consist of restricted numbers of sillicate layers (normally, 5 ~ 15 layers) stacked in parallel to a-b planes. This ultra-thinness is known to decrease I-S expandability (%S) rather than theoretically expected one (short-stacking effect). We attempt here to quantify the short stacking effect of I-S using the difference of two types of expandability: one type is a maximum expandability ($%S_{Max}$) of infinite stacks of fundamental particles (physically inseparable smallest units), and the other type is an expandability of finite particle stacks normally measured using X-ray powder diffraction (XRD) ($%S_{XRD}$). Eleven I-S samples from the Geumseongsan volcanic complex, Uiseong, Gyeongbuk, have been analyzed for measuring $%S_{XRD}$ and average coherent scattering thickness (CST) after size separation under 1 ${\mu}m$. Average fundamental particle thickness ($N_f$) and $%S_{Max}$ have been determined from $%S_{XRD}$ and CST using inter-parameter relationships of I-S layer structures. The discrepancy between $%S_{Max}$ and $%S_{XRD}$ (${\Delta}%S$) suggests that the maximum short-stacking effect happens approximately at 20 $%S_{XRD}$, of which point represents I-S layer structures consisting of ca. average 3-layered fundamental particles ($N_f{\approx}3$). As a result of inferring the $%S_{XRD}$ range of each Reichweite using the $%S_{XRD}$ vs. $N_f$ diagram of Kang et al. (2002), we can confirms that the fundamental particle thickness is a determinant factor for I-S Reichweite, and also that the short-stacking effect shifts the $%S_{XRD}$ range of each Reichweite toward smaller $%S_{XRD}$ values than those that can be theoretically prospected using junction probability.

A 900 MHz Zero-IF RF Transceiver for IEEE 802.15.4g SUN OFDM Systems

  • Kim, Changwan;Lee, Seungsik;Choi, Sangsung
    • ETRI Journal
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    • v.36 no.3
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    • pp.352-360
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    • 2014
  • This paper presents a 900 MHz zero-IF RF transceiver for IEEE 802.15.4g Smart Utility Networks OFDM systems. The proposed RF transceiver comprises an RF front end, a Tx baseband analog circuit, an Rx baseband analog circuit, and a ${\Delta}{\Sigma}$ fractional-N frequency synthesizer. In the RF front end, re-use of a matching network reduces the chip size of the RF transceiver. Since a T/Rx switch is implemented only at the input of the low noise amplifier, the driver amplifier can deliver its output power to an antenna without any signal loss; thus, leading to a low dc power consumption. The proposed current-driven passive mixer in Rx and voltage-mode passive mixer in Tx can mitigate the IQ crosstalk problem, while maintaining 50% duty-cycle in local oscillator clocks. The overall Rx-baseband circuits can provide a voltage gain of 70 dB with a 1 dB gain control step. The proposed RF transceiver is implemented in a $0.18{\mu}$ CMOS technology and consumes 37 mA in Tx mode and 38 mA in Rx mode from a 1.8 V supply voltage. The fabricated chip shows a Tx average power of -2 dBm, a sensitivity level of -103 dBm at 100 Kbps with PER < 1%, an Rx input $P_{1dB}$ of -11 dBm, and an Rx input IP3 of -2.3 dBm.

Expression of peroxisome proliferator activated receptor gamma in the neuronal cells and modulation of their differentiation by PPAR gamma agonists

  • Hong, Jin-Tae
    • Proceedings of the Korea Environmental Mutagen Society Conference
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    • 2002.11a
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    • pp.14-40
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    • 2002
  • 15-Deoxy-${\Delta}^{12, 14}$-prostaglandin $J_2$ (15-deoxy-$PGJ_2$), a naturally occurring ligand activates the peroxisome proliferator-activated $receptor-{\gamma}(PPAR-{\gamma}$). Activation of $PPAR-{\gamma}$ has been found to induce cell differentiation such as adipose cell and macrophage. Here it was investigated whether 15-deoxy-$PGJ_2$ has neuronal cell differentiation and possible underlying molecular mechanisms. Dopaminergic differentiating PC 12 cells treated with 15-deoxy-$PGJ_2$ (0.2 to 1.6 ${\mu}M$) alone showed measurable neurite extension and expression of neurofilament, markers of cell differentiation. However much greater extent of neurite extension and expression of neurofilament was observed in the presence of NGF (50 ng/ml). In parallel with its increasing effect on the neurite extension and expression of neurofilament, 15-deoxy-$PGJ_2$ enhanced NGF-induced p38 MAP kinase expression and its phosphorylation in addition to the activation of transcription factor AP-1 in a dose dependent manner. Moreover, pretreatment of SD 203580, a specific inhibitor of p38 MAP kinase inhibited the promoting effect of 15-deoxy-$PGJ_2$(0.8 ${\mu}M$) on NGF-induced neurite extension. This inhibition correlated well with the ability of SB203580 to inhibit the enhancing effect of 15-deoxy-$PGJ_2$ on the expression of p38 MAP kinase and activation of AP-1, The promoting ability of 15-deoxy-$PGJ_2$ did not occur through $PPAR-{\gamma}$, as synthetic PPAR-${\gamma}$ agonist andantagonist did not change the neurite promoting effect of 15-deoxy-PGJ$_2$. In addition, contrast to other cells (embryonic midbrain and SK-N-MC cells), $PPAR-{\gamma}$ was not expressed in PC-12 cells. Other structure related prostaglandins, PGD$_2$ and $PGE_2$ acting via a cell surface G-protein-coupled receptor (GPCR) did not increase basal or NGF-induced neurite extension. Moreover, GPCR (EP and DP receptor) antagonists did not alter the promoting effect of f 5-deoxy-$PGJ_2$ on neurite extension and activation of p38 MAP kinase, suggesting that the promoting effect of 15-deoxy-$PGJ_2$ may not be mediated GPCR. These data demonstrate that activation of p38 MAP kinase in conjunction with AP-1 single pathway may be important in the promoting activity of 15-deoxy-$PGJ_2$ cells.

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