A variety of metal vacuum systems displays the celebrated 1/t pressure, namely, power-law dependence on time t, with the exponent close to unity, as to the origin of which there has been long-standing controversy. Here we propose a chemisorption model for water adsorbates, based on the argument for 2D fermion behavior of water adsorbed on a metal surface, and obtain analytically the power-law behavior of pressure with an exponent unity. Further, the model predicts that the pressure should depend on the temperature T according to $T^{1.5}$, which is indeed confirmed by our experiment.