The numerical simulations were conducted to investigate the thermal-fluid phenomena occurred inside the experimental apparatus during a PCCS, used to remove heat released in accidents from a containment of light water nuclear power plant, operation. Numerical simulations of the flow and heat transfer caused by wall condensation inside the containment simulation vessel (CSV), which equipped with 18 vertical heat exchanger tubes, were conducted using the commercial computational fluid dynamics (CFD) software ANSYS-CFX. Shear stress transport (SST) and the wall condensation model were used for turbulence closure and wall condensation, respectively. The simulation using the actual size of the apparatus. However, rather than simulating the whole experimental apparatus in consideration of the experimental cases, calculation resources, and calculation time, the simulation model was prepared only in CSV. Selective simulation was conducted to verify the effects of non-condensable gas(NC gas) concentration, CSV internal pressure, and wall sub-cooling conditions. First, as a result of the internal flow of CSV, it was observed that downward flow due to condensation occurred surface of the vertical tube and upward flow occurred in the distant place. Natural convection occurred actively around the heat exchanger tube. Due to this rising and falling internal flow, natural circulation occurred actively around the heat exchanger tubes. Next, in order to check the performance of built-in condensation model using according to the non-condensable gas concentration, CSV internal flow and wall sub-cooling, the heat flux values were compared with the experimental results. On average, the results were underestimated with and error of about 25%. In addition, the influence of CSV internal pressure and wall sub-cooling was small, but when the condensate was highly generated due to the low non-condensable gas concentration, the error was large compared to the experimental values. This is considered to be due to the nature of the condensation model of the CFX code. However, in spite of the limitations of CFD, it is valid to use the built-in condensation model of CFD for PCCS performance prediction from a conservative perspective.