Nuclear Engineering and Technology

Korean Nuclear Society (한국원자력학회)
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Enhanced thermal conductivity of spark plasma-sintered thorium dioxide-silicon carbide composite fuel pellets

  • Linu Malakkal (Computational Mechanics and Materials, Idaho National Laboratory) ;
  • Anil Prasad (Advanced Fuels and Reactor Physics, Canadian Nuclear Laboratories) ;
  • Jayangani Ranasinghe (Department of Physics and Engineering Physics, University of Saskatchewan) ;
  • Ericmoore Jossou (Nuclear Science and Technology Department, Brookhaven National Laboratory) ;
  • Lukas Bichler (School of Engineering, University of British Columbia-Okanagan) ;
  • Jerzy Szpunar (Department of Mechanical Engineering, University of Saskatchewan)
  • Received : 2023.01.12
  • Accepted : 2023.06.21
  • Published : 2023.10.25
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Abstract

Thorium dioxide (ThO2)-silicon carbide (SiC) composite fuel pellets were fabricated via the spark plasma-sintering (SPS) method to investigate the role of the addition of SiC in enhancing the thermal conductivity of ThO2 fuel. SiC particles with an average size of 1㎛ in 10 and 15 vol% were used to manufacture the composite pellets. The changes in the composites' densification, microstructure and thermal conductivity were explored by comparing them with pure ThO2 pellets. The structural and microstructural characterization of the composite pellets has revealed that SPS could manufacture high-quality composite pellets without having any reaction products or intermetallic. The density measurement by the Archimedes principles and the grain size from the electron back-scattered diffraction (EBSD) analysis has indicated that the composites have higher densities and smaller grain sizes than the pellets without SiC addition. Finally, thermal conductivity as a function of temperature has revealed that sintered ThO2-SiC composites showed an increase of up to 56% in thermal conductivity compared to pristine ThO2 pellets.

Keywords

Acknowledgement

The authors gratefully acknowledge the financial support of Natural Sciences and Engineering Research Council (NSERC) Canada. In addition, this manuscript has been authored by Battelle Energy Alliance, LLC under Contract No. DE-AC07- 05ID14517 with the U.S. Department of Energy. The U.S. Government retains and the publisher, by accepting the article for publication, acknowledges that the U.S. Government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for U.S. Government purposes. Appreciate the valuable suggestions by Dr. Jijin Raj Ayanath Kuttiyatveetil.

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