Journal of Sensor Science and Technology (센서학회지)

The Korean Sensors Society (한국센서학회)
권호 표지
DOI QR코드

DOI QR Code

Liquid electrochemical sensors using carbon nanotube film

Carbon Nanotube Film을 이용한 액체 전기화학 센서

  • Noh, Jaeha (Major of Electronic Materials Engineering, Korea and Maritime Ocean University) ;
  • An, Sangsu (Major of Electronic Materials Engineering, Korea and Maritime Ocean University) ;
  • Lee, Changhan (Major of Electronic Materials Engineering, Korea and Maritime Ocean University) ;
  • Lee, Sangtae (Department of offshore plant management, Korea and Maritime Ocean University) ;
  • Lee, Moonjin (Maritime Safety and Environmental Research Division, KRISO) ;
  • Seo, Dongmin (Maritime Safety and Environmental Research Division, KRISO) ;
  • Chang, Jiho (Major of Electronic Materials Engineering, Korea and Maritime Ocean University)
  • 노재하 (한국해양대학교 전자소재공학과) ;
  • 안상수 (한국해양대학교 전자소재공학과) ;
  • 이창한 (한국해양대학교 전자소재공학과) ;
  • 이상태 (한국해양대학교 해양플랜트 운영학과) ;
  • 이문진 (선박해양플랜트연구소 해양안전환경연구본부) ;
  • 서동민 (선박해양플랜트연구소 해양안전환경연구본부) ;
  • 장지호 (한국해양대학교 전자소재공학과)
  • Received : 2021.07.10
  • Accepted : 2021.07.27
  • Published : 2021.07.31
Download PDF
⟨ Previous Next ⟩

Abstract

We studied electrochemical sensors using printed carbon nanotube (CNT) film on a polyethylene terephthalate (PET) substrate. Multiwalled CNT films were printed on a PET substrate to study its feasibility as hazardous and noxious substances (HNS) detection sensor. The printed CNT film (PCF) with a 50 ㎛ thickness exhibited a specific resistance of 230 ohm. To determine the optimum sensor structure, a resistance-type PCF sensor (R-type PCF sensor) and a conductive-type PCF sensor (C-type PCF sensor) were fabricated and compared using diluted NH3 droplets with various concentrations. The response magnitude, response time, sensitivity, linearity, and limit of detection (LOD) were compared, and it was concluded that the C-type PCF sensor exhibited superior performance. By applying a C-Type PCF sensor, we confirmed the detection performance of 12 types of floating HNS and the response of the sensor with selectivity according to the degree of polarity.

Keywords

Acknowledgement

이 논문은 2021년 해양수산부 재원으로 해양수산과학기술진흥원의 지원을 받아 수행된 연구(위험유해물질(HNS)사고 관리기술개발)이다. (D11502119H480000120)

References

  1. S. Hong, Y. Hong, Y. Jeong, G. Jung, W. Shin, J. Park, and J. H. Lee, "Improved CO gas detection of Si MOSFET gas sensor with catalytic Pt decoration and pre-bias effect", Sens. Actuator B-Chem., Vol. 300, p.127040, 2019. https://doi.org/10.1016/j.snb.2019.127040
  2. W. Chen, P. Yang, W. Shen, C. Zhu, D. Lv, R. Tan, and W. Song, "Flexible room temperature ammonia gas sensor based on in suit polymerized PANI/PVDF porous composite film", J. Mater. Sci.: Mater. Electron., Vol. 31, pp. 11870-11877, 2020. https://doi.org/10.1007/s10854-020-03741-9
  3. M. Tonezzer, "Selective gas sensor based on one single SnO2 nanowire", Sens. Actuators B Chem., Vol. 288, pp, 53-59, 2019. https://doi.org/10.1016/j.snb.2019.02.096
  4. J. Y. Zhou, J. L. Bai, H. Zhao, Z. Y. Yang, X. Y. Gu, B. Y. Huang, and E. Q. Xie, "Gas sensing enhancing mechanism via doping-induced oxygen vacancies for gas sensors based on indium tin oxide nanotubes", Sens. Actuators B-Chem., Vol. 265, pp. 273-284, 2018. https://doi.org/10.1016/j.snb.2018.03.008
  5. J. Kong, N. R. Franklin, C. Zhou, M. G. Chapline, S. Peng, K. Cho, and H. Dai, "Nanotube Molecular Wires as Chemical Sensors", Science., Vol. 287, No. 5453, pp. 622-625, 2000. https://doi.org/10.1126/science.287.5453.622
  6. V. Schroeder, S. Savagatrup, M. He, S. Lin, and T. M. Swager, "Carbon Nanotube Chemical Sensors", Chem. Rev., Vol. 119, No. 1, pp. 599-663, 2018. https://doi.org/10.1021/acs.chemrev.8b00340
  7. A. D. Rushi, K. P. Datta, P. S. Ghosh, A. Mulchandani, and M. D. Shirsat, "Selective Discrimination among Benzene, Toluene, and Xylene: Probing Metalloporphyrin-Functionalized Single-Walled Carbon Nanotube-Based Field Effect Transistors", J. Phys. Chem. C., Vol. 118, No. 41, pp. 24034-24041, 2014. https://doi.org/10.1021/jp504657c
  8. P. Li, C. M. Martin, K. K. Yeung, and W. Xue, "Dielectrophoresis Aligned Single-Walled Carbon Nanotubes as pH Sensors", Biosensors, Vol. 1, No. 1, pp. 23-35, 2011. https://doi.org/10.3390/bios1010023
  9. M. B. Gumpu, S. Sethuraman, U. M. Krishnan, and J. B. B. Rayappan, "A review on detection of heavy metal ions in water - An electrochemical approach", Sens. Actuator B-Chem., Vol. 213, pp. 515-533, 2015. https://doi.org/10.1016/j.snb.2015.02.122
  10. Y. R. Kim, T. W. Kim, M. H. Son, S. W. Oh, and M. J. Lee, "A study on prioritization of HNS management in Korean waters", J. Korean Soc. Mar., Vol. 21, No. 6, pp. 672-678, 2015.
  11. M. I. Bodnarchuk, M. V. Kovalenko, S. Pichler, G. Fritz-Popovski, G. Hesser, and W. Heiss, "Large-Area Ordered Superlattices from Magnetic Wustite/Cobalt Ferrite Core/Shell Nanocrystals by Doctor Blade Casting", ACS Nano, Vol. 4, No. 1, pp. 423-431, 2010. https://doi.org/10.1021/nn901284f
  12. P. P. Prosini, C. Cento, M. Carewska, and A. Masci, "Electrochemical performance of Li-ion batteries assembled with water-processable electrodes", Solid State Ion., Vol. 274, pp. 34-39, 2015. https://doi.org/10.1016/j.ssi.2015.02.012
  13. S. W. Lee, K. K. Kim, Y. Cui, S. C. Lim, Y. W. Cho, S. M. Kim, and Y. H. Lee, "Adhesion Test of Carbon Nanotube Film Coated onto Transparent Conducting Substrates", Nano, Vol. 05, No. 03, pp. 133-138, 2010. https://doi.org/10.1142/S1793292010002025
  14. Y. R. Kim, M. Lee, J. Y. Jung, T. W. Kim, and D. Kim, "Initial environmental risk assessment of hazardous and noxious substances (HNS) spill accidents to mitigate its damages", Mar., Vol. 139, pp. 205-213, 2019.
  15. A. P. P. Alves, J. P. C. Trigueiro, H. D. R. Calado, and G. G. Silva, "Poly(3-hexylthiophene)-multi-walled carbon nanotube (1:1) hybrids: Structure and electrochemical properties", Electrochim. Acta., No. 209, pp. 111-120, 2016. https://doi.org/10.1016/j.electacta.2016.04.187
  16. M. A. Riheen, T. K. Saha, and P. K. Sekhar, "Inkjet Printing on PET Substrate", J. Electrochem. Soc., Vol. 166, No. 9, pp. B3036-B3039, 2019.
  17. N. aran, K. arikh, D. S. Suh, E. Munoz, H. Kolla, and S. K. Manohar, "Fabrication and Characterization of Thin Films of Single-Walled Carbon Nanotube Bundles on Flexible Plastic Substrates", J. Am. Chem. Soc., Vol. 126, No. 14, pp. 4462-4463, 2004. https://doi.org/10.1021/ja037273p
  18. P. R. Chalker, S. J. Bull, and D. S. Rickerby, "A review of the methods for the evaluation of coating-substrate adhesion", Mater. Sci. Eng. A., No. 140, pp. 583-592, 1991. https://doi.org/10.1016/0921-5093(91)90482-3
  19. S. Petit, P. Laurens, M. G. Barthes-Labrousse, J. Amouroux, and F. Arefi-Khonsari, "Al/PET adhesion: role of an excimer laser pretreatment of PET prior to aluminum thermal evaporation", J. Adhes. Sci. Technol., Vol. 17, No. 3, pp. 353-368, 2003. https://doi.org/10.1163/156856103762864660
  20. Y. Zhang, Z. Kang, and T. Bessho, "Two-component spincoated Ag/CNT composite films based on a silver heterogeneous nucleation mechanism adhesion-enhanced by mechanical interlocking and chemical grafting", Nanotechnology, Vol. 28, No. 10, pp. 105607, 2017. https://doi.org/10.1088/0957-4484/28/10/105607
  21. N. A. Bohari, S. Siddiquee, S. Saallah, M. Misson, and S. E. Arshad, "Optimization and Analytical Behavior of Electrochemical Sensors Based on the Modification of Indium Tin Oxide (ITO) Using PANI/MWCNTs/AuNPs for Mercury Detection", Sensors, Vol. 20, No. 22, pp. 6502, 2020. https://doi.org/10.3390/s20226502
  22. N. H. Quang, M. Van Trinh, B. H. Lee, and J. S. Huh, "Effect of NH3 gas on the electrical properties of single-walled carbon nanotube bundles", Sens. Actuator B-Chem., Vol. 113, No. 1, pp. 341-346, 2006. https://doi.org/10.1016/j.snb.2005.03.089
  23. K. A. Mirica, J. G. Weis, J. M. Schnorr, B. Esser, and T. M. Swager, "Mechanical Drawing of Gas Sensors on Paper", Angew. Chem., Vol. 124, No. 43, pp. 10898-10903, 2012. https://doi.org/10.1002/ange.201206069
  24. S. G. Wang, Q. Zhang, D. J. Yang, P. J. Sellin, and G. F. Zhong, "Multi-walled carbon nanotube-based gas sensors for NH3 detection", Diam. Relat. Mater., Vol. 13, No. 4-8, pp. 1327-1332, 2004. https://doi.org/10.1016/j.diamond.2003.11.070
  25. T. Zhang, S. Mubeen, N. V. Myung, and M. A. Deshusses, "Recent progress in carbon nanotube-based gas sensors." Nanotechnology, Vol. 19, No. 33, p. 33200, 2008
  26. A. Yamada, Y. Kato, T. Yoshikuni, Y. Tanaka, and N. Tanaka, "Computer-assisted measurement of ion-diffusion coefficients by use of the cottrell equation", Anal. Chim. Acta., Vol. 112, No. 1, pp. 55-63, 1979. https://doi.org/10.1016/S0003-2670(01)93029-6
  27. Y. R. Kim, J. Y. Choi, M. H. Son, S. W. Oh, M. J. Lee, and S. J. Lee, "Prioritizing noxious liquid substances (NLS) for preparedness against potential spill incidents in Korean coastal waters", J. Korean Soc. Mar., Vol. 22, pp. 846-853, 2016.