Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Synthesis of Gold Nanoparticles Using Fullerene Oxide and Their Catalytic Activity for Reduction of 4-Nitroaniline

  • Park, Geun Wook (Department of Convergence Science, Graduate School, Sahmyook University) ;
  • Ko, Jeong Won (Nanomaterials Research Institute, Sahmyook University) ;
  • Ko, Weon Bae (Department of Convergence Science, Graduate School, Sahmyook University)
  • Received : 2019.04.04
  • Accepted : 2019.05.02
  • Published : 2019.06.30
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Abstract

Gold nanoparticles were synthesized by reacting potassium tetrachloroaurate ($KAuCl_4$), potassium carbonate ($K_2CO_3$), and isopropyl alcohol in the presence of fullerene oxide [$C_{60}(O)_n$, $n{\geq}1$], which was, in turn, prepared from [$C_{60}$] fullerene and m-chloroperoxybenzoic acid under refluxing conditions. The crystallinity and morphology of the prepared gold nanoparticles were confirmed by UV-vis spectroscopy, X-ray diffraction, and scanning electron microscopy. The activity of the gold nanoparticles in the reduction of 4-nitroaniline was measured in order to determine its capability as a catalyst.

Keywords

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Figure 1. UV-vis spectrum of synthesized gold nanoparticles using fullerene oxide [C60 (O)n, n ≥ 1].

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Figure 2. XRD patterns of synthesized gold nanoparticles using fullerene oxide [C60 (O)n, n ≥ 1].

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Figure 3. SEM image of synthesized gold nanoparticles using fullerene oxide [C60 (O)n, n ≥ 1].

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Figure 4. UV-vis spectra of 4-nitroaniline reduction with gold nanoparticles as catalyst in the presence of NaBH4.

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Figure 5. Kinetics of 4-nitroaniline reduction using synthesized gold nanoparticles as catalyst.

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