Figure 1. Reactor flow diagram
Figure 2. Five EEM distribution regions
Figure 3. FI(fluorescence index) analysis
Figure 4. HIX(humification index) analysis
Figure 5. BIX(biological index) analysis
Figure 6. Result of 3D-EEM(Running time 140 min)
Figure 7. Result of 3D-EEM(Running time 80 min)
Figure 8. Result of 3D-EEM(Running time 60 min)
Figure 9. Result of intensity analysis(Running time 140 min)
Figure 10. Result of intensity analysis(Running time 80 min)
Figure 11. Result of intensity analysis(Running time 60 min)
Figure 12. Average removal efficiency
Table 1. Chemical composition result of the ceramics media(wt%)
Table 2. List of environmental parameters used for the prediction
Table 3. Each reactor measured value
References
- Baker A. 2001. Fluorescence excitation-emission matrix characterization of some sewageimpacted rivers. Environmental Science & Technology. 35(5): 948-953. https://doi.org/10.1021/es000177t
- Birdwell JE, Valsara KT. 2010. Characterization of dissolved organic matter in fogwater by excitation-emission matrix fluorescence spectroscopy. Atmospheric Environment. 44: 3246-3253. https://doi.org/10.1016/j.atmosenv.2010.05.055
- Chen W, Westerhoff P. LeenHeer LA, Booksh K. 2003. Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter. Environmental science & technology. 37(24): 5701-5710. https://doi.org/10.1021/es034354c
- Chen Z, Hu C, Conmy RN, Muller-Karger F, Swarzenski P. 2007. Colored dissolved organic matter in Tampa Bay. Florida. Marine Chemistry. 104: 98-109. https://doi.org/10.1016/j.marchem.2006.12.007
- Choi DH. 2009. A Study on Improvement of Water Quality in Constructed Wetland Based on Various Mechanisms. Doctor's Thesis. Chungnam National University.
- Coble PG. 1996. Characterization of marine and terrestrial DOM in seawater using excitation-emission matrix spectroscopy. Marine chemistry. 51(4): 325-346. https://doi.org/10.1016/0304-4203(95)00062-3
- Hudson N, Baker A, Reynolds D. 2007. Fluorescence analysis of dissolved organic matter in natural waste and polluted waters-a review. River Research and Applications. 23(6): 631-649. https://doi.org/10.1002/rra.1005
- Huguet A, Vacher L, Relexans S, Saubusse S, Froidefond JM, Parlanti E. 2009. Properties of fluorescent dissolved organic matter in the Gironde Estuary. Organic Geochemistry. 40: 706-719. https://doi.org/10.1016/j.orggeochem.2009.03.002
- Hunt JF, Ohno T. 2007. Characterization of fresh and decomposed dissolved organic matter using excitation-emission matrix fluorescence spectroscopy an multiway analysis. Journal of Agricultural and Food Chemistry. 55: 2121-2128. https://doi.org/10.1021/jf063336m
- Hur J, Sin SG, Park SW. 2006. Characterizing Fluorescence Properties of Dissolved Organic Matter for Water Quality Management of Rivers and Lakes. J. of KSEE. 28(9): 940-948.
- Lakowicz JR. 2013. Principles of fluorescence spectroscopy. Springer Science & Business Media.
- Lee DH. 2016. Molecular structural characteristics of soil and sediment humic substances and correlation with phenanthrene sorption parameters. Doctor's Thesis, Seoul National University of Science and Technology.
- Lee EJ, Yoo GY, Jeong Y, Kim KU, Park JH & Oh NH. 2015. Comparison of UV-VIS and FDOM sensors for in situ monitoring of stream DOC concentrations. Bio geosciences. 12(10): 3109-3118.
- Lee KC, Park YJ, Kim YR, Park JY, Lee HG, Jegal BC. 2014. Formation Characteristics and Controls of Disinfection By-products in G Drinking Water Treatment Processes. The report of Seoul Metropolitan Government Institute of Health and Environment. 27: 148-172.
- Lee SK, Park MS, Yeon SJ, Park DH. 2016. Optimization of chemical precipitation for phosphate removal from domestic wastewater. Journal of Korea Society of Water and Wastewater. 30(6): 663-671 https://doi.org/10.11001/jksww.2016.30.6.663
- Malcolm RL. 1985. Geochemistry of Stream Fulvic and Humic Substances. In Humic Substances in soil, sediment, and water: Geochemistry, Isolation, and Characterization, Edited by G. R. aiken, D. M. Mcknight, R. L. Wershaw and P. MacCarthy. New York: John Wiley and sons.
- McKnight DM, Boyer EW, Westerhoff PK, Doran PT, Kulbe T, Andersen DT. 2001. Spectrofluorometric characterization of dissolved organic matter for indication precursor organic material and aromaticity. Limnology and Oceanography. 46: 38-48. https://doi.org/10.4319/lo.2001.46.1.0038
- Ministry of Environment. 2014. Future bureau of Creativity. Ministry of land, Infrastructure and Transport. Multi-server Joint planning report: Safe constant supply from algal bloom.
- National Institute of Environmental Research (NIEF). 2010. The increasing treand of regratory organic matters and the management plans for the han river basin, Hangang Sugye Gwanri Wiwonhoe.
- Park YH. 2017. Study on the characterization of dissolved organic matter in groundwater and surfacewater with fluorescence analysis. Kangwon National University.
- Shim JH, Kim SJ, Gang MG, Lee SI. 2016. Evaluation of Magnetite-Loess Composite as a Flocculant for Phosphorus Removal. KSWST Jour. Wat. Treat. 24(3): 39-48.
- Stedmon CA, Markager S, Bro R. 2003. Tracing dissolved organic matter in aquatic environments using a new approach to fluorescence spectroscopy. Marine Chemistry. 82(3): 239-254. https://doi.org/10.1016/S0304-4203(03)00072-0
- Steinberg G, Muenster V. 1985. Geochemistry and Eco-logical Role of Humic Substances in Lake water. In Humic Substances in soil, sediment, and water: Geochemistry, Isolation, and Characterization, Edited by G. R. aiken, D. M. Mcknight, R. L. Wershaw and P. MacCarthy. New York: John Wiley and sons.
- United Sates Environmental Protection Agency. 1990. Environmental Regulation and Technology: Autothermal Themophilic Aerobic Digestion of Municipal Wastewater Sludge. EPA/625/10-90/007.
- Wen C, Paul W, Jerry A, Leenheer Karl. B. 2003. Fluorescence Excitation-Emission Matrix Regional Integration to Quantify Spectra for Dissolved Organic Matter. Environ. Sci. Technol. 37(24): 5701-5710. https://doi.org/10.1021/es034354c
- Wetzel RG. 2001. Limnology: Lake and River Ecosystems. Elsevier academic press, New York.
- Zsolnay A, Baigar E, Jimenez M, Steinweg B, Saccomandi F. 1999. Differentiating with fluorescence spectroscopy the sources of dissolved organic matter in soil subjected to drying. Chemosphere. 38: 45-50. https://doi.org/10.1016/S0045-6535(98)00166-0