Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Effect of [Al(DMSO2)3]3+ Concentration on Al Electrodeposition from AlCl3/Dimethylsulfone Baths

  • Kim, Sangjae (Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University) ;
  • Matsunaga, Naoya (Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University) ;
  • Kuroda, Kensuke (Institute of Materials and Systems for Sustainability, IMaSS, Nagoya University) ;
  • Okido, Masazumi (Institute of Materials and Systems for Sustainability, IMaSS, Nagoya University)
  • Received : 2017.12.27
  • Accepted : 2018.03.07
  • Published : 2018.03.31
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Abstract

Aluminum electrodeposition was carried out in dimethylsulfone ($DMSO_2$) baths containing 6.2-28.3 mol% $AlCl_3$ at 403 K. The electrochemically active species for Al electrodeposition in $DMSO_2$ baths were investigated. Electrochemical behavior of the electrolyte and the deposition mechanism were studied via cyclic voltammetry (CV). Properties of the deposits were assessed by scanning electron microscopy with energy-dispersive X-ray spectroscopy and X-ray diffraction. In addition, structures of the ionic complexes formed with aluminum in the bath were characterized by $^{27}Al$ nuclear magnetic resonance (NMR) spectroscopy. NMR spectra revealed that all baths contained two ionic species: $AlCl_4{^-}$ and $[Al(DMSO_2)_3]^{3+}$. Al electrodeposited when the $[Al(DMSO_2)_3]^{3+}$ concentration was the highest (23.3 mol% $AlCl_3$) exhibited fine grain sizes, relatively smooth surfaces, and high purities.

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