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Preparation and Properties Measurement of 2-hydroxyethyl methacrylate / Water-dispersed polyurethane composites

  • Lee, Joo-Youb (Department of Fire and Disaster Prevention Engineering, Jungwon University)
  • Received : 2018.11.20
  • Accepted : 2018.12.21
  • Published : 2018.12.31

Abstract

In this study, 2-hedroxyethyl methacrylate (2-HEMA) was graft synthesized on water-dispersed polyurethane using polytetramethylene ether glycoll (PTMG), and then the film of resin was prepared and the physical properties of polyurethane resin were measured. The mechanical properties of the synthesized polyurethane resin were measured by using FT-IR, UTM, adhesion performance measuring instrument. As a result of tensile strength measurement, the tensile strength of HPUD4 with high 2-HEMA content was increased to $5.05kgf/mm^2$, the elongation was measured as 285% of the HPUD1 sample not containing 2-HEMA and adhesive strength of HPUD4 sample was measured at 9.1 sec to 635 psi.

Keywords

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Fig. 1. FT-IR spectra of water dispersion polyurethane.

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Fig. 2. Tensile strength measurement graph of polyurethane dispersion samples containing 2-HEMA.

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Fig. 3. Elongation measurement graph of 2-HEMA grafted polyurethane dispersion samples.

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Fig. 4. Results of measurement of adhesive strength of water-dispersed polyurethane without 2-HEMA.

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Fig. 5. Results of measurement of adhesive strength of water-dispersed polyurethane containing 0.5 mol of 2-HEMA.

Table 1. Polymerization condition of polyurethane dispersion with different 2-HEMA Content

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References

  1. J. Kozakiewicz, "Developments in Aqueous Polyurethane and Polyurethane-acrylic dispersion technology. Part II. Polyurethane-acrylic dispersions and modification of Polyurethane and Polyurethane-acrylic Dispersions (in English)". POLIMERY TWORZYWA WIELKOCZASTECZKOWE, Vol.61 No.2, pp. 81-91, (2016). https://doi.org/10.14314/polimery.2016.081
  2. W. R White, D. T. Durocher, "Recycling of Rigid Polyurethane Articles and Reformulation into a Variety of Polyurethane Applications" J.cellular plastics, Vol.33, No.5, pp.477-86, (1997). https://doi.org/10.1177/0021955X9703300504
  3. C. C. Ma, S.C Sung, F. Y. Wang, L. Y. Chiang, L, Y. Wang, C. L. Chiang, "Thermal, Mechanical, and Morphological Properties of Novolac-Type Phenolic resin blended with Fullerenol Polyurethane and Linear Polyurethane", J. polymer science. Part B, Polymer physics, Vol.39, No.20, pp.2439-2443, (2001).
  4. L. Tofan, "Polyurethane Foams Analytical Applications. I. Untreated Polyurethane Foams", MATERIALE PLASTICE, Vol.31, No.4, pp. 245, (1994).
  5. Y. Ikeda, C. Kobayashi, K. Kaeriyama, "Novel polyurethane Cationomer, Part 1 Polyurethane Cationomer Synthesized from Hydroxy - Terminated Poly (Oxytetramethylene) with Ionic Sites in The end of Segments", J. RUBBER INDUSTRY JAPAN, Vol.72, No.2, pp.96-101, (1999). https://doi.org/10.2324/gomu.72.96
  6. F. Seven, N. Sahiner "Modified macroporous P(2-hydroxyethyl methacrylate) P(HEMA) cryogel composites for H2 production from hydrolysis of NaBH4", Fuel Processing Technology, Vol 128, pp. 394-401, (2014). https://doi.org/10.1016/j.fuproc.2014.08.008
  7. F. Abbaszadeh, O. Moradi, M. Norouzi, O. Sabzevari, "Improvement single-wall carbon nanotubes (SWCNTs) based on functionalizing with monomers 2-hydroxyethylmethacryate (HEMA) and N-vinylpyrrolidone (NVP) for pharmaceutical applications as cancer therapy", J of Industrial and Engineering Chemistry, Vol.20. pp. 2985-2900, (2014).
  8. D. K. Sardar, R. M. Yow, J. B. Gruber, "Optical absorption intensities of trivalent erbium in a 2-hydroxyethyl methacrylate (HEMA) polymeric host" Optical Materials, Vol.30, pp.987-992, (2008), https://doi.org/10.1016/j.optmat.2007.05.029
  9. M. A. Khan, M. M. Hassan, L. T. Drzal, "Effect of 2-hydroxyethyl methacrylate (HEMA) on the mechanical and thermal properties of jute-polycarbonate composite", Composites Part A: Applied Science and Manufacturing, Vol. 36, pp. 71-81, (2005), https://doi.org/10.1016/S1359-835X(04)00178-2
  10. S. Tauscher, J. Angermann, Y. Catel, N. Moszner, "Evaluation of alternative monomers to HEMA for dental applications", Dental Materials, Vol. 33, pp. 857-865, (2017). https://doi.org/10.1016/j.dental.2017.04.023
  11. J. Wang, X. Ying, J. Liu, X. Li, W. Zhang, "Controlled mechanical and swelling properties of urethane acrylate grafted calcium alginate hydrogels", I. J. of Biological Macromolecules, Vol. 81, pp. 11-16, (2015). https://doi.org/10.1016/j.ijbiomac.2015.07.021
  12. J. Majer, M. Paljevac, E. Zagar, S. Kovacic, P. Krajnc, "Functionalization of 2-hydroxyethyl methacrylate-based polyHIPEs: Effect of the leaving group", Reactive and Functional Polymers, Vol. 109, pp. 99-103, (2016), https://doi.org/10.1016/j.reactfunctpolym.2016.10.008
  13. A. M. Abdel Ghaffar, T. E. Youssef, H. H. Mohamed, "Radiation synthesis and characterization of zinc phthalocyanine composite based on 2-hydroxyethyl methacrylate/methyl methacrylate copolymer", Materials Chemistry and Physics, Vol. 178, pp.12-20, (2016). https://doi.org/10.1016/j.matchemphys.2016.04.012
  14. H. B. Ly, R. Poupart, B. Carbonnier, V. Monchiet, ... D. Grande, "Versatile functionalization platform of biporous poly(2-hydroxyethyl methacrylate)-based materials: Application in heterogeneous supported catalysis", Reactive and Functional Polymers, Vol. 121, pp. 91-100, (2017). https://doi.org/10.1016/j.reactfunctpolym.2017.10.024
  15. Y. Hu, G. Gu, S. Z.hou, L. Wu, "Preparation and properties of transparent PMMA/ZrO2 nanocomposites using 2-hydroxyethyl methacrylate as a coupling agent", Polymer, Vol 52, pp. 122-129, (2011). https://doi.org/10.1016/j.polymer.2010.11.020