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Effect of Deposition Parameter and Mixing Process of Raw Materials on the Phase and Structure of Ytterbium Silicate Environmental Barrier Coatings by Suspension Plasma Spray Method

서스펜션 플라즈마 스프레이 코팅법으로 제조된 Ytterbium Silicate 환경차폐코팅의 상형성 및 구조에 미치는 증착인자 및 원료혼합 공정의 영향

  • Ryu, Ho-lim (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Choi, Seon-A (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Lee, Sung-Min (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Han, Yoon-Soo (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Choi, Kyun (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Nahm, Sahn (Department of Materials Science and Engineering, Korea University) ;
  • Oh, Yoon-Suk (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology)
  • 류호림 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 최선아 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 이성민 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 한윤수 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 최균 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 남산 (고려대학교 신소재공학과) ;
  • 오윤석 (한국세라믹기술원 엔지니어링 세라믹 센터)
  • Received : 2017.12.01
  • Accepted : 2017.12.21
  • Published : 2017.12.28

Abstract

SiC-based composite materials with light weight, high durability, and high-temperature stability have been actively studied for use in aerospace and defense applications. Moreover, environmental barrier coating (EBC) technologies using oxide-based ceramic materials have been studied to prevent chemical deterioration at a high temperature of $1300^{\circ}C$ or higher. In this study, an ytterbium silicate material, which has recently been actively studied as an environmental barrier coating because of its high-temperature chemical stability, is fabricated on a sintered SiC substrate. $Yb_2O_3$ and $SiO_2$ are used as the raw starting materials to form ytterbium disilicate ($Yb_2Si_2O_7$). Suspension plasma spraying is applied as the coating method. The effect of the mixing method on the particle size and distribution, which affect the coating formation behavior, is investigated using a scanning electron microscope (SEM), an energy dispersive spectrometer (EDS), and X-ray diffraction (XRD) analysis. It is found that the originally designed compounds are not effectively formed because of the refinement and vaporization of the raw material particles, i.e., $SiO_2$, and the formation of a porous coating structure. By changing the coating parameters such as the deposition distance, it is found that a denser coating structure can be formed at a closer deposition distance.

Keywords

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