Journal of the Mineralogical Society of Korea (한국광물학회지)

The Mineralogical Society of Korea (한국광물학회)
권호 표지
DOI QR코드

DOI QR Code

High Pressure Behavior Study of the Apophyllite (KF)

고압 하에서 어안석(KF)의 거동 연구

  • Kim, Young-Ho (Department of Geology and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Choi, Jinwon (Department of Geology and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Heo, Sohee (Department of Geology and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Jeong, Nangyeong (Department of Geology and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Hwang, Gil Chan (Department of Earth System Sciences, Yonsei University)
  • 김영호 (경상대학교 지질과학과 및 기초과학연구소) ;
  • 최진원 (경상대학교 지질과학과 및 기초과학연구소) ;
  • 허소희 (경상대학교 지질과학과 및 기초과학연구소) ;
  • 정난경 (경상대학교 지질과학과 및 기초과학연구소) ;
  • 황길찬 (연세대학교 지구시스템과학과)
  • Received : 2015.12.04
  • Accepted : 2015.12.23
  • Published : 2015.12.30
Download PDF
⟨ Previous Next ⟩

Abstract

Apophyllite (KF)($K_{0.84}Ca_{3.99}Si_{7.70}O_{20}F_{0.72}{\cdot}8H_2O$), one of the sheet silicates, was compressed up to 7.7 GPa at ambient temperature and 15 high pressure data were obtained. Lattice parameters of the starting specimen were as follows: $a_0=8.954(2)\;{\AA}$, $c_0=15.795(2)\;{\AA}$, $V_0=1266.4(4)\;{\AA}^3$. Symmetrical diamond anvil cell was employed with synchrotron radiation in the mode of angular dispersive X-ray diffraction. Bulk modulus was determined to be 59(4) GPa when ${K_0}^{\prime}$ is 4. No clear first order phase transition symptom was observed in the series of XRD pattern. However, second-order phase transition cannot be ruled out from the correlation between normalized pressure and strain.

층상규산염광물인 천연산 어안석(KF)($K_{0.84}Ca_{3.99}Si_{7.70}O_{20}F_{0.72}{\cdot}8H_2O$)에 대한 고압실험을 상온에서 시행하였다. 출발시료의 격자상수 값은 다음과 같다: $a_0=8.954(2)\;{\AA}$, $c_0=15.795(2)\;{\AA}$, $V_0=1266.4(4)\;{\AA}^3$. 방사광과 대칭형 다이아몬드앤빌기기 및 각분산 X-선회절법을 이용하여 상온에서 7.7 GPa까지 15개의 고압 X-선회절데이터를 획득하였다. 어안석(KF)의 체적탄성률은 ${K_0}^{\prime}$을 4로 고정하였을 때 59(4) GPa로 계산되었다. 압력구간에서 1차상변이를 지시하는 근거는 관찰되지 않았으나, 2차 상변이에 대한 징후는 정규화압력 및 정규화응력변형 분석결과로부터 배제할 수 없다.

Keywords

References

  1. Angel, R.J., Gonzalez-Platas, J., and Alvaro, M. (2014) EosFit7c and a Fortran module (library) for equation of state calculations. Zeischrift fur Kristallographie, 229, 405-419.
  2. Bell, P.M., Xu, J., and Mao, H.K. (1986) Static compression of gold and copper and calibration of the ruby pressure scale to 1.8 Megabars, in Shock Waves in Condensed Matter, Gupta, Y.M. (eds), Plenum Pub. Co., New York, 125-130.
  3. Chijioke, A.D., Nellis, W.J., Soldatov, A., and Silvera, I.F. (2005) The ruby pressure standard to 150 GPa. Journal of Applied Physics, 98, 1149051-1149059.
  4. Colville, A.A., Anderson, C.P., and Black, P.M. (1971) Refinement of the crystal structure of apophyllite: I. X-ray diffraction and physical properties. American Mineralogist, 56, 1222-1233.
  5. Comodi, P., Gata, G.D., and Zanaazi, P.F. (2001) High-pressure structural behaviour of heulandite. European Journal of Mineralogy, 13(3), 497-506. https://doi.org/10.1127/0935-1221/2001/0013-0497
  6. Comodi, P, Gata, G.D., and Zanaazi, P.F. (2002) High-pressure structural behaviour of scolecite. European Journal of Mineralogy, 14(3), 567-574. https://doi.org/10.1127/0935-1221/2002/0014-0567
  7. Dunn, P.J., Rouse, R.C. and Norberg, J.A. (1978) Hydroxyapophyllite, a new mineral, and a redefinition of the apophyllite group, I. Description, occurrences, and nomenclature. American Mineralogist, 63, 196-202.
  8. Fan, D.W., Wei, S.Y., and Xie, H.S. (2013) An in situ high-pressure X-ray diffraction experiment on hydroxyapophyllite. Chinese Physics B, 22(1), 010702(1)-010702(4). https://doi.org/10.1088/1674-1056/22/1/010702
  9. Fleming, T.H., Foland, K.A., and Elliot, D.H. (1999) Apophyllite $^{40}Ar/^{39}Ar$ and Rb-Sr geochronology: Potential utility and application to the timing if secondary mineralization of the Kirkpatrick Basalt, Antarctica. Journal of Geophysical Research, 104(B9), 10, 20081-20095. https://doi.org/10.1029/1999JB900138
  10. Gatta, G.D., Comodi, P., Zanazzi, P.F., and Ballaran, T.B. (2005) Anomalous elastic behavior and high-pressure structural evolution of zeolite levyne. American Mineralogist, 90, 645-652. https://doi.org/10.2138/am.2005.1768
  11. Goryainov, S.V., Krylov, A.S., Pan, Y., Madyukov, I.A., Smirnov, M.B., and Vtyurin, A.N. (2012) Raman investigation of hydrostatic and nonhydrostatic compression of OH- and F-apophyllites up to 8 GPa. Journal of Raman Spectroscopy, 43, 439-447. https://doi.org/10.1002/jrs.3049
  12. Hriljac, J.A. (2006) High-pressure synchrotron X-ray powder diffraction studies of zeolites. Crystallogrphy Reviews, 12, 181-193. https://doi.org/10.1080/08893110600772032
  13. Jeanloz, R. (1981) Finite-strain equation of state for high-pressure phases. Geophysical Research Letters, 8(12), 1219-1222. https://doi.org/10.1029/GL008i012p01219
  14. Jeanloz, R. and Hazen, R.M. (1991) Finite-strain analysis of relative compressibilities: Application to the high-pressure wadsleyite phase as an illustration. American Mineralogist, 76, 1765-1768.
  15. Kim, Y.H., Hwang, G.C., and Kim, S.O. (2009) Compression study on a synthetic geothite. Journal of Mineralogical Society of Korea, 22(4), 325-330 (in Korean with English abstract).
  16. Liu, L.G. and Bassett, W.A. (1986) Elements, Oxides and Silicates, High-pressure phases with implications for the Earth's interior, Oxford University Press, New York, p. 250.
  17. Mao, H.K., Xu, J., and Bell, P.M. (1986) Calibration of the ruby pressure guage to 800 kbar under quasi-hydristatic conditions. Journal of Geophysical Research, 91, 4673-4676. https://doi.org/10.1029/JB091iB05p04673
  18. Matsueda, H., Miura Y., and Rucklidge, J. (1981) Natroapophyllite, a new orthorhombic sodium analog of apophyllite I. description, occurrence, and nomenclature. American Mineralogist, 66, 410-423.
  19. Marriner, G.F., Tarney, J., and Langford, J.J. (1990) Appophyllite group: dffects of chemical substitutions on dehydration behaviour, recrystallization products and cell parameters. Mineralogical Magazine, 54, 567-577. https://doi.org/10.1180/minmag.1990.054.377.06
  20. Ming, L.C., Jayaraman, A., Shieh, S.R. and Kim, Y.H. (1995) In situ high-pressure x-ray diffraction study of $TlReO_4$ to 14.5 GPa: Pressure-induced phase transformations and the equation of state. Physical Review B, 51(18), 12100-12106. https://doi.org/10.1103/PhysRevB.51.12100
  21. Stahl, K. (1993) A neutron powder diffraction study of partially dehydrated fluorapophyllite, $KCa_4Si_8O_{20}F_0{\cdot}_6.9H_2O$. European Journal of Mineralogy, 5, 845-849. https://doi.org/10.1127/ejm/5/5/0845

Cited by

  1. Compressibility Study of Pyromorphite at High Pressure vol.29, pp.4, 2016, https://doi.org/10.9727/jmsk.2016.29.4.191
  2. High Pressure Behavior Study of Azurite vol.31, pp.4, 2018, https://doi.org/10.9727/jmsk.2018.31.4.277
  3. 고압 하에서 TiO2 복합체의 거동에 대한 연구 vol.30, pp.3, 2015, https://doi.org/10.9727/jmsk.2017.30.3.127