DOI QR코드

DOI QR Code

Role of HCl in Atomic Layer Deposition of TiO2 Thin Films from Titanium Tetrachloride and Water

  • Leem, Jina (Department of Chemical Engineering, Konkuk University) ;
  • Park, Inhye (Department of Chemical Engineering, Konkuk University) ;
  • Li, Yinshi (Department of Chemical Engineering, Konkuk University) ;
  • Zhou, Wenhao (Department of Chemical Engineering, Konkuk University) ;
  • Jin, Zhenyu (Department of Chemical Engineering, Konkuk University) ;
  • Shin, Seokhee (Department of Chemical Engineering, Konkuk University) ;
  • Min, Yo-Sep (Department of Chemical Engineering, Konkuk University)
  • Received : 2014.01.28
  • Accepted : 2014.02.05
  • Published : 2014.04.20

Abstract

Atomic layer deposition (ALD) of $TiO_2$ thin film from $TiCl_4$ and $H_2O$ has been intensively studied since the invention of ALD method to grow thin films via chemical adsorptions of two precursors. However the role of HCl which is a gaseous byproduct in ALD chemistry for $TiO_2$ growth is still intriguing in terms of the growth mechanism. In order to investigate the role of HCl in $TiO_2$ ALD, HCl pulse and its purging steps are inserted in a typical sequence of $TiCl_4$ pulse-purge-$H_2O$ pulse-purge. When they are inserted after the first-half reaction (chemisorption of $TiCl_4$), the grown thickness of $TiO_2$ becomes thinner or thicker at lower or higher growth temperatures than $300^{\circ}C$, respectively. However the insertion after the second-half reaction (chemisorption of $H_2O$) results in severely reduced thicknesses in all growth temperatures. By using the result, we explain the growth mechanism and the role of HCl in $TiO_2$ ALD.

Keywords

Introduction

Atomic layer deposition (ALD) is a special modification of chemical vapor deposition (CVD) to grow various thin films via self-limiting chemisorption.1-3 While in CVD an appropriate precursor vapor and a reaction gas are simult-aneously supplied to a substrate, in ALD they are alternately exposed onto the substrate of which temperature is main-tained to be low enough in order to avoid thermal decom-position of the precursor. The ALD reactor is purged with an inert gas between the exposures of the precursor vapor and the reaction gas. Each cycle of ALD process generally con-sists of precursor exposure - purge - reaction gas exposure - purge. Therefore, the film grows through chemisorption bet-ween the gaseous molecules (i.e., precursor vapor or reactant gas) and reactive functional groups on the surface (i.e., hydr-oxyl groups or chemisorbed organometallic groups). Once vacant adsorption sites are saturated by adsorbate molecules to form one monolayer (practically sub-monolayer is formed due to the bulkiness of adsorbate molecules), the precursor or reactant in excess do not chemically adsorb on the mono-layer. Consequently the film grows via the self-limiting mechanism.

For an ideal ALD process, several characteristics are required in ALD chemistry: (1) the chemisorption should be highly exothermic with a high activation of desorption (Ed) in order to guarantee 100% sticking coefficient in the chemi-sorption, (2) byproducts should not chemically re-adsorb on the vacant sites after the chemisorption, and (3) the by-product should not etch the growing film through a series of reverse reactions of the growth. In terms of these require-ments, the chemistry for ALD of Al2O3 from trimethyl-aluminum (TMA) and water is nearly ideal. It shows ex-tremely extremely high reaction enthalpies of chemisorption with high Ed values for both the first- and second-half reactions. For the first half-reaction between Al−OH and TMA, the enthalpy change is around −1.70 eV (Ed = 1.61 eV), and for the second-half reaction between Al−(CH3)2 and H2O, it is around −1.48 eV (Ed = 1.61 eV).4 Furthermore methane (the byproduct in the first- and second-half reactions) does not chemically re-adsorb on the surface and is not able to etch the growing film. However many precursors for ALD rather show deviation from the ideal ALD chemistry.

TiO2 ALD from titanium tetrachloride (TiCl4) and water is an example for the non-ideal ALD. Several groups had theoretically or experimentally studied the chemistry of TiO2 ALD.5-13 In the generally accepted mechanism of TiO2 growth, TiCl4 mainly reacts with the surface OH groups releasing HCl in the first-half reaction:

where (s) denotes surface. The adsorbed chlorotitanium (TiClx) species may react with water releasing HCl again in the second-half reaction, which results in the recovery of the surface OH groups for the next cycle:

Because the growth of TiO2 is mainly contributed from the surface exchange reactions (Eqs. 1 and 2), the surface OH groups play a key role in the ALD sequence. There are two kinds of OH groups on the surface of oxides: isolated OH and adjacent hydrogen-bonded OH (H-boned OH) groups. The H-bonded OH groups are dominant at low temperatures, but they are condensed at high temperatures by dehydrox-ylation to form oxygen bridges liberating H2O:

The oxygen bridges, formed by Eq. (3), may also contri-bute to the first-half reaction of TiO2 ALD at high temper-atures though the dissociative chemisorption of TiCl4:

In Eqs. (1) and (2), when n = 1 and n = 2, the reactions are monofunctional and bifunctional, respectively. The mono-functional and bifunctional reactions produce gaseous HCl as a byproduct. However HCl is not released in the dis-sociative chemisorption (Eq. 4).

Although ALD of TiO2 from TiCl4 and water has been intensively investigated since the invention of the ALD method,14-27 the role of HCl is not clear yet. Here we investi-gate the role of HCl which may be one of origins for the non-ideality in TiO2 ALD.

 

Experimental

All thin films were grown on boron doped p-type (100) Si wafers, of which resistivity is 5-20 Ω-cm, by using a laminar flow type ALD reactor (ATOMIC-CLASSIC 2nd edition, CN-1 Co., Ltd.). Although our reactor could process a 6 in. wafer, five square specimens (2 × 2 cm2) were loaded on the center, left, right, top and bottom positions of the 6 in. substrate holder in order to evaluate non-uniformity in the 6 in. wafer. The specimens were used without removing the native oxide. TiCl4 (UP Chemical Co., Ltd) and water were vaporized from external canisters at room temperature and led into the reactor through solenoid valves without any carrier gas. The doses of TiCl4 and water were ~2.9 × 10−6 and ~7.2 × 10−5 mol/s, respectively. HCl gas was vaporized at room temperature from a hydrogen chloride solution (2.0 M) in diethyl ether of which dose was ~2.6 × 10−4 mol/s. For purging the reactor, high purity N2 gas (99.999%) was used with a flow rate of 400 sccm. All delivery lines were maintained at 120 °C. The specimen temperature was calib-rated with a thermocouple-implanted 6 in. wafer in the temperature range of 50-400 °C. The base pressure of the reactor was less than 10 mTorr and ALD was pr℃essed at a working pressure range of 200-600 mTorr.

All thicknesses of the grown films were measured by a spectroscopic ellipsometer (SE, MG-1000, NanoView). The incident angle of the polarized light in the SE was fixed at around 70°, and the incident light has a spectral range of 1.5~5.0 eV. In order to determine an initial value of the thick-ness for fitting the measured data, it was firstly fitted with TiO2 reference values of the real and imaginary parts of the complex dielectric function supplied by NanoView.28 Sub-sequently the measured data were fitted with the Tauc-Lorentz dispersion function for all films.29 Refractive index of the films was determined at 1.96 eV from the fitted para-meters of the dispersion function.

By using five thicknesses obtained at center, top, bottom, left and right positions of the 6 in. substrate holder, non-uniformity of the grown film was evaluated by dividing the standard deviation of the thicknesses by the mean value.

X-ray diffraction (XRD) measurements were carried out in θ/2θ scan mode using a Philips X’pert Pro MRD X-ray diffractometer with Cu Kα emission.

In order to examine the electrical insulating properties of TiO2 films, a capacitor structure of Au/TiO2/native SiO2 (2 nm)/p-Si(100) was fabricated by depositing 50 nm-thick Au films by thermal evaporation through a metal shadow mask for the top electrodes. The area of the Au electrode was ~1.26 × 10−3 cm2. Leakage current -voltage characteristics of TiO2 thin films was measured with a semiconductor para-meter analyzer (HP 4145B).

 

Results and Discussion

Determination of Exposure and Purge Times. In order to determine the exposure time of TiCl4 for the self-limiting growth, TiO2 ALD was performed at 150 °C for 100 cycles with a sequence of TiCl4 exposure – N2 purging (30s) – H2O exposure (1s) – N2 purging (30s). The exposure time of water was fixed to be 1s of which the exposure time is generally enough for oxide films. As shown in Figure 1(a), the TiO2 growth initially increases with the exposure time of TiCl4, but saturates over 1s. By contrast, the poor non-uniformity at insufficient exposure times is dramatically improved by increasing the exposure time. Therefore the exposure time of TiCl4 was determined to be 1s for the self-limiting growth.

The purging time for excess TiCl4 and byproduct (e.g., HCl) was also investigated in Figure 1(b) in which the ALD sequence of TiCl4 exposure (1s) – N2 purging – H2O expo-sure (1s) – N2 purging (30s) was repeated for 100 cycles at 150 °C. There is no severe variation in the TiO2 thickness and non-uniformity even with shorter purging times than 1s. However we chose 5s as the purging time for the first-half reaction. Similarly, ALD experiments to determine the purg-ing time for H2O were performed at 150 °C for 100 cycles with a sequence of TiCl4 exposure (1s) – N2 purging (30s) – H2O exposure (1s) – N2 purging. Figure 1(c) shows that it takes much longer time in the second-half reaction than in the first-half reaction. We chose 20s to purge the excess water vapor and byproduct (e.g., HCl). As a result, the optimized ALD sequence for TiO2 was TiCl4 exposure (1s) – N2 purg-ing (5s) – H2O exposure (1s) – N2 purging (20s).

Anomalous Effect of Growth Temperature on Growth-per-cycle and Crystallinity of TiO2 Thin Films. Growth-per-cycle (GPC) of TiO2 ALD was investigated in a temper-ature range of 100-400 °C as shown in Figure 2. The values of GPC were determined from the slopes in the plots of thickness versus number of cycles (100-400 cycles) at each growth temperature (data not shown). While typical ALD processes show a plateau of the GPC in an ALD temperature window, the GPC of our TiO2 ALD from TiCl4 and H2O shows a large fluctuation in which a maximum (0.75 Å/cycle) and a minimum (0.42 Å/cycle) appear at 200 and 300 °C, respectively. The GPC increases by a factor of 1.8 when the growth temperature is raised from 200 to 300 °C. Aarik, et al. also observed the anomalous increase in the GPC in a temperature range of 175-225 °C in ALD of thick TiO2 films for which the number of cycles was 3000 cycles.23 They proposed that crystallization of TiO2 results in surface roughening and increase in surface area. Larger amounts of precursors are adsorbed on the surface, and consequently an additional increase in the GPC is obtained. However they reported that no similar behavior was observed in thinner films than 20 nm because the crystal structure was not developed yet for small number of cycles at the low growth temperatures.

Figure 1.Thickness (circles) and non-uniformity (squares) vari-ations as a function of TiCl4 exposure time (a), TiCl4 purge time (b), and H2O purge time (c) in TiO2 ALD at 150 °C for 100 cycles. The error bars in the circles denote the standard deviations of TiO2 thicknesses grown at top, bottom, left, right and center positions in a 6 in. wafer.

Figure 2.GPC (circles) and non-uniformity (squares) variations as a function of growth temperature. The error bars in the circles denote the standard errors in the linear fitting of the grown thicknesses with respect to the number of cycles. The error bars in the squares denote the standard deviations of the non-uniformity.

Figure 3.XRD patterns of TiO2 films grown at 250-400 °C, of which thicknesses are ranged in 20-24 nm. The peaks were identified as those of the anatase (A) phase.

Figure 3 shows XRD diffraction patterns for TiO2 films of which thicknesses are ranged from 20 to 24 nm. The film grown at 250 °C was amorphous due to the thin thickness while, in the Aarik's reports,23,25 the crystalline anatase peaks was observed even at 150 °C from thick TiO2 (3000 cycles). The GPC value (0.53 Å/cycle) at 250 °C is significantly larger than that (0.42 Å/cycle) at 200 °C even though both films are amorphous. Thus the anomalous increase in GPC at 200-300 °C cannot be explained only by the increase of the surface area due to the crystallization. The other factors for the anomalous tendency of the GPC will be explained in the following section.

One more concern in the XRD pattern is that the intensity of the anatase peak (101) is unusually attenuated at higher growth temperatures. Figure 4 shows refractive index of TiO2 films deposited at each growth temperature. Consider-ing the refractive index of thin films is directly related to density of them, it should be noted that the density increases from 150 to 250 °C, but unusually decreases from 250 to 400 °C. Because the films grown at 150-250 °C are amorphous, they may become denser at higher temperatures. However the decrease in the density at 250-400 °C is abnormal, which may be related to the degree of crystallization in the TiO2 films. Electrical insulating properties of TiO2 films shown in Figure 5 also support the results of XRD and refractive index. The amorphous film grown at 150 °C shows the lowest leakage current density due to the absence of a leakage path through grain boundaries. The grown film at 300 °C shows poorer insulating characteristics than the film at 400 °C, because the film at 300 °C is more crystallized than that at 400 °C as shown in Figure 3.

Figure 4.Refractive index variation as a function of growth temperature. The error bars denote the standard deviations of the refractive indices obtained at top, bottom, left, right, and center positions in a 6 in. wafer.

Generally the GPC of ALD is not constant with respect to the ALD cycles, but it can be varied with the number of cycles. In an initial stage of ALD cycles, the underlying substrate (e.g., SiO2/Si) is generally dissimilar to the grow-ing layer (e.g., TiO2). Therefore the GPC is also different between the early and late stages of ALD cycles. In addition, if the growing layer can be crystallized as deposited, the GPC of the early stage will be smaller than that of the late stage because TiO2 grown at the early stage is amorphous. The GPC of the Figure 2 was obtained from the slope of a plot of the grown thickness versus the number of cycles in a range of 100-400 cycles. Therefore the GPC in Figure 2 may represent the growth behavior at the later stage than at the early stage.

Figure 5.Electrical insulating properties of TiO2 films grown at 150, 300 and 400 °C.

Figure 6.Δ thickness as a function of growth temperature: the Δ thickness is defined as a thickness difference by subtracting the thickness grown for 100 cycles (i.e., circles in Fig. 7) from the thickness calculated by the GPC in Figure 2.

Figure 6 shows the difference (Δ thickness) between the calculated thicknesses with the GPC in Figure 2 and the experimental thicknesses (shown with open circles in Fig. 7) for 100 cycles. Below 200 °C, there is no significant differ-ence between the calculated and experimental values. This reveals no significant change in the growth behavior bet-ween the early and late stages of ALD cycles. However the Δ thickness shows a clear parabolic variation at higher temperatures than 200 °C. The positive value of Δ thickness means that the thickness grown for 100 cycles at the early stage of ALD process are thinner than the thickness grown for 100 cycles at the later stage.

As Aarik, et al. explained the abnormal increase of the GPC with crystallization,23 the variation of Δ thickness can be explained with progress of crystallization which results in an increase of the surface area (i.e., adsorption sites). Below 200 °C, TiO2 is amorphous. Thus Δ thickness is negligible, since TiO2 is not crystalized in both early and later stages. The decreasing tendency of the GPC (below 200 °C in Fig. 2) in the amorphous TiO2 growth is typical and similar to that in the Al2O3 ALD in which the phase is also amorphous. On the other hand, the anatase structure of TiO2 is well developed at 300 °C and Δ thickness shows its highest value. Furthermore, as the anatase peak becomes smaller (above 300 °C in Fig. 3), Δ thickness also decreases. This strongly supports that the GPC is severely influenced by the crystal-lization. However, the anomalous increase of the GPC and Δ thickness at 200-300 °C cannot be explained by only crystal-lization, because TiO2 grown at 250 °C is still amorphous according to the XRD pattern.

Figure 7.Thicknesses of TiO2 films as a function of growth temperature. The films were grown for 100 cycles by three kinds of ALD processes. Circles (Typical ALD): TiCl4 exposure (1s) – N2 purge (5s) – H2O exposure (1s) – N2 purge (20s); squares (Modified ALD, M’): TiCl4 exposure (1s) – N2 purge (5s) – HCl exposure (1s) – N2 purge (5s) – H2O exposure (1s) – N2 purging (20s); triangles (Modified ALD, M”): TiCl4 exposure (1s) – N2 purge (5s) – H2O exposure (1s) – N2 purge (20s) – HCl exposure (1s) – N2 purge (5s).

Role of HCl in TiO2 ALD. Recently, Matero et al. investi-gated the mechanism of TiO2 ALD from TiCl4 and water by using in-situ quadrupole mass spectrometry (QMS) and quartz crystal microbalance (QCM).8 The ALD growth main-ly proceeds via exchange reactions (Eqs. 1-2) on the surface. When the growth temperature is increased from 150 to 250 °C, the number (n) of –Cl ligands, released during the TiCl4 pulse, decreases from about two to one (from bifunctional to monofunctional adsorption). However, at temperatures higher than 250 °C, less than one –Cl ligand (n < 1) is released, indicating that the dissociative chemisorption of TiCl4 on the oxygen bridges (Eq. 4) also contributes to the first-half reac-tion. The formation of oxygen bridges via the dehydroxyl-ation (Eq. 3) of OH groups is generally more preferred at higher temperatures. Thus the dissociative chemisorption may more contribute to the first-half reaction of TiO2 ALD at higher temperatures. Therefore we may infer a relation between the GPC and the dissociative chemisorption of TiCl4.

In recent, Turner et al. reported density functional theory (DFT) calculations of the initial surface reactions of TiO2 ALD on SiO2 substrate.12 According to the DFT calculations, the first half-reaction via monofunctional chemisorption between SiOH and TiCl4 is slightly exothermic with an enthalpy change of around −0.28 eV, which is a much smaller value comparing to the first-half reaction of Al2O3 between AlOH and TMA (−1.70 eV).4 Furthermore the bifunctional chemisorption is rather endothermic with an enthalpy change of ~0.017 eV. Therefore we should consider reverse reactions (i.e., desorption) of chemisorption in order to understand the growth behavior of TiO2. The reverse reac-tion may results in decrease of GPC. In general, each half-reaction of ALD is not in equilibrium due to short pulse times of precursors and purging steps by inert gas. If the gaseous byproduct is efficiently removed by the purging step, the chemisorption may be thermodynamically favored than desorption. However considering the non-equilibrium nature of ALD process, the reverse reactions (desorption of precursors) cannot be excluded in a practical point of view. Therefore the monofunctional and bifunctional adsorption (Eq. 1) in the first-half reaction is non-ideal chemisorption for ALD process, especially under the presence of HCl. Different from the monofunctional or bifunctional chemi-sorption via ligand exchange reaction (Eq. 1), the dissocia-tive chemisorption (Eq. 4) is highly exothermic (−1.21 eV) with a high activation of desorption (Ed = 1.56 eV)12 and it is consequently irreversible and ideal for ALD process.

As a result, there are two ways for TiCl4 chemisorption in the first-half reaction of TiO2 ALD: ideal (irreversible) and non-ideal (reversible) adsorption. As proven by the QMS and QCM experiments,8 as the growth temperature increases, the contribution of dissociative chemisorption of TiCl4 increases but those of monofunctional or bifunctional chemisorption decreases in the growth of TiO2. Therefore the anomalous increase of GPC and Δ thickness in the range of 200-300 °C can be explained by large contribution of the dissociative chemisorption.

In order to support the desorption of TiClx species under the presence of HCl, we intentionally inserted HCl pulse after the first-half reaction in the typical sequence of TiO2 ALD. The sequence of this modified ALD process (M’) is TiCl4 exposure (1s) – N2 purge (5s) – HCl exposure (1s) – N2 purge (5s) – H2O exposure (1s) – N2 purging (20s). The process M’ was repeated for 100 cycles. Circles and squares in Figure 7 show the thicknesses of TiO2 films by the typical and modified process M’, respectively. Below 300 °C, the TiO2 thickness by the modified process M’ is thinner than that by the typical process due to the desorption of TiClx by HCl. However the thickness difference between them becomes smaller at higher temperatures and then it interestingly becomes reversed above 300 °C. Because the irreversible dissociative chemisorption of TiCl4 becomes gradually more favorable at higher temperature than 200 °C, the thickness reduction by the HCl pulse should be attenuated as the growth temperature increases. The reversal of the thickness difference above 300 °C in Figure 7 can also be explained as following: under HCl atmosphere, the desorption of TiClx recovers OH groups, and the oxygen bridges become more dominant on the surface by the dehydroxylation of OH groups (Eq. 3). As a result, the larger coverage of the oxygen bridges may cause thicker TiO2 by the irreversible chemi-sorption.

Another modified ALD process (M”) was also performed by inserting the HCl pulse after the second-half reaction in the typical sequence of TiO2 ALD. The sequence of the modified process M” is TiCl4 exposure (1s) – N2 purge (5s) – H2O exposure (1s) – N2 purge (20s) – HCl exposure (1s) – N2 purge (5s). The process M” was also repeated for 100 cycles. As shown in Figure 7 (triangles), the TiO2 thicknesses by the modified process M” are much thinner than those by the typical process or by the process M’ in all temperatures.

Figure 8.Normalized thickness of TiO2 films as a function of etching temperature: the thickness after the etching was normaliz-ed by the initial thickness.

In an ideal case, all TiClx species formed by the first-half reaction should be completely converted to Ti(OH)x or Ti-O-Ti in the second-half reaction. However if the reverse reac-tion (or re-adsorption of HCl) of the second-half reaction is possible, the TiClx species may partially remain. Therefore TiO2 growth will be retarded since the number of adsorption sites (-OH or oxygen bridges) for TiCl4 is reduced in the subsequent first-half reaction. Indeed, according to the DFT calculations,12 the second-half reactions (Eq. 2) are endo-thermic with a low activation of ~0.5 eV on the surface of both monofunctionally- and bifunctionally-chemisorbed TiClx. Therefore if the byproduct HCl is not efficiently removed or HCl is intentionally supplied after the second-half reaction (like the process M”), the TiO2 growth is slower in comparison to the cases of the typical process or the process M’.

On the other hand, the dissociative chemisorption (Eq. 4) of TiCl4 gradually more contributes to the growth of TiO2 at higher temperatures, nevertheless the TiO2 thickness is thin even at the high temperature region in the process M”. This can be explained by the re-adsorption of HCl on the oxygen bridges as below:

By the reaction of Eq. (5), the adsorption sites are con-verted from oxygen bridges to OH groups which may experience the similar chemistry mentioned in the previous paragraph. Therefore the growth of TiO2 is severely retarded under the presence of HCl even at high temperatures.

Final concern for HCl is the possibility of etching of TiO2 by the byproduct HCl during ALD process. In order to directly observe whether the etching by HCl is possible or not, we performed etching experiments (Fig. 8) in which 30 nm-thick TiO2 film was exposed to HCl for 1 sec and then purged for 5 sec. This sequence was repeated for 50 cycles at various temperatures. There is no significant change in thickness before and after the etching experiment in all temperatures. Generally etching is not an one-step reaction but a complex reaction in which many elementary reaction steps are included to form volatile species (e.g. TiCl4). Therefore for the successful etching of TiO2 by HCl, various reactions included in a series of the complex reactions should be favorable thermodynamically and kinetically. Considering the reversible nature of some reactions of the first- and second-half reactions, the etching may be kineti-cally hindered. Therefore the byproduct HCl does not etch the grown TiO2 but simply bring about the reduction of adsorption site on the surface for the subsequent ALD step.

 

Conclusions

Here we investigated the role of HCl in the ALD of TiO2 from TiCl4 and water. In the first-half reaction of TiO2 ALD, the hydroxyl groups and oxygen bridges on the surface compete for the chemisorption of TiCl4. At low temperatures below 200 °C, the hydroxyl groups mainly play a role of adsorption sites, but the contribution of the oxygen bridge gradually increases as the temperature becomes higher. While the monofunctional or bifunctional chemisorption of TiCl4 on the hydroxyl groups is reversible under the pre-sence of HCl, the dissociative chemisorption on the oxygen bridges is irreversible. Therefore the GPC of TiO2 ALD is severely dependent on the growth temperature. In addition, the second-half reaction of TiO2 ALD is also reversible by the re-adsorption of HCl under the presence of HCl. There-fore, the byproduct HCl should be efficiently and completely removed in the purge steps to avoid a non-ideal ALD.

References

  1. George, S. M. Chem. Rev. 2010, 110, 111. https://doi.org/10.1021/cr900056b
  2. Suntola, T.; Antson, J.; Pakkala, A.; Lindfors, S. SID 80 Dig. 1980, 11, 108.
  3. Suntola, T.; Hyvarinen, J. Ann. Rev. Mater. Sci. 1985, 15, 177. https://doi.org/10.1146/annurev.ms.15.080185.001141
  4. Widjaja, Y.; Musgrave, C. B. Appl. Phys. Lett. 2002, 80, 3304. https://doi.org/10.1063/1.1473237
  5. Haukka, S.; Lakomaa, E. L.; Root, A. J. Phys. Chem. 1993, 97, 5085. https://doi.org/10.1021/j100121a040
  6. Kytokivi, A.; Haukka, S. J. Phys. Chem. B 1997, 101, 10365. https://doi.org/10.1021/jp971822u
  7. Schrijnemakers, K.; Impens, N. R. E. N.; Vansant, E. F. Langmuir 1999, 15, 5807. https://doi.org/10.1021/la9812469
  8. Matero, R.; Rahtu, A.; Ritala, M. Chem. Mater. 2001, 13, 4506. https://doi.org/10.1021/cm011046+
  9. Aarik, J.; Aidla, A.; Mandar, H.; Uustare, T. Appl. Surf. Sci. 2001, 172, 148. https://doi.org/10.1016/S0169-4332(00)00842-4
  10. Schrijnemakers, K.; Cool, P.; Vansant, E. F. J. Phys. Chem. B 2002, 106, 6248. https://doi.org/10.1021/jp014560b
  11. Gu, W.; Tripp, C. P. Langmuir 2005, 21, 211. https://doi.org/10.1021/la047811r
  12. Hu, Z.; Turner, C. H. J. Phys. Chem. B 2006, 110, 8337. https://doi.org/10.1021/jp060367b
  13. Methaapanon, R.; Bent, S. F. J. Phys. Chem. C 2010, 114, 10498. https://doi.org/10.1021/jp1013303
  14. Lakomaa, E. L.; Haukka, S.; Suntola, T. Appl. Surf. Sci. 1992, 60/61, 742. https://doi.org/10.1016/0169-4332(92)90506-S
  15. Haukka, S.; Lakomaa, E. L.; Jylha, O.; vilhunen, J.; Hornytzkyj, S. Langmuir 1993, 9, 3497. https://doi.org/10.1021/la00036a026
  16. Ritala, M.; Leskela, M. Nykanen, E.; Soininen, P.; Niinisto, L. Thin Solid Films 1993, 225, 288. https://doi.org/10.1016/0040-6090(93)90172-L
  17. Ritala, M.; Leskela, M.; Jhansson, L. S.; Niinisto, L. Thin Solid Films 1993, 228, 32. https://doi.org/10.1016/0040-6090(93)90557-6
  18. Ritala, M.; Leskela, M.; Niinisto, L.; Prohaska, T.; Griedbacher, G.; Grasserbauer, M. Thin Solid Films 1994, 249, 155. https://doi.org/10.1016/0040-6090(94)90754-4
  19. Aarik, J. Aidla, A.; Uustare, T.; Sammelselg, V. J. Cryst. Growth 1995, 148, 268. https://doi.org/10.1016/0022-0248(94)00874-4
  20. Aarik, J.; Aidla, A.; Sammelselg, V.; Siimon, H.; Uustare, T. J. Cryst. Growth 1996, 169, 496. https://doi.org/10.1016/S0022-0248(96)00423-X
  21. Siimon, H.; Aarik, J. J. Phys. D: Appl. Phys. 1997, 30, 1725. https://doi.org/10.1088/0022-3727/30/12/006
  22. Sammelselg, V.; Rosental, A.; Tarre, A.; Niinisto, L.; Heiskanen, K.; Ilmonen, K.; Johansson, L. S.; Uustare, T. Appl. Surf. Sci. 1998, 134, 78. https://doi.org/10.1016/S0169-4332(98)00224-4
  23. Aarik, J.; Aidla, A.; Mandar, H.; Sammelselg, V. J. Cryst. Growth 2000, 220, 531. https://doi.org/10.1016/S0022-0248(00)00897-6
  24. Cameron, M. A.; Gartland, I. P.; Smith, J. A.; Diaz, S. F.; George, S. M. Langmuir 2000, 16, 7435. https://doi.org/10.1021/la9916981
  25. Aarik, J.; Aidla, A.; Mander, H.; Uustare, T.; Schuisky, M.; Harsta, A. J. Cryst. Growth 2002, 242, 189. https://doi.org/10.1016/S0022-0248(02)01426-4
  26. Ferguson, J. D., Yoder, A. R.; Weimer, A. W.; George, S. M. Appl. Surf. Sci. 2004, 226, 393. https://doi.org/10.1016/j.apsusc.2003.10.053
  27. Triani, G.; Campbell, J. A.; Evans, P. J.; Davis, J.; Latella, B. A.; Burford, R. P. Thin Solid Films 2010, 518, 3182. https://doi.org/10.1016/j.tsf.2009.09.010
  28. Thomas, M. E.; Tropf, W. J. In Handbook of Optical Constants of Solids; Palik, E. D., Ed.; Academic Press: San Diego, CA, 1998; p 653.
  29. Jellison, G. E., Jr.; Modine, F. A. Appl. Phys. Lett. 1996, 69, 371. https://doi.org/10.1063/1.118064

Cited by

  1. Effect of Process Temperature and Reaction Cycle Number on Atomic Layer Deposition of TiO2 Thin Films Using TiCl4 and H2O Precursors: Correlation Between Material Properties and Process Environment vol.46, pp.1, 2016, https://doi.org/10.1007/s13538-015-0383-2
  2. -coated magnetite nanoparticles vol.10, pp.7, 2019, https://doi.org/10.1039/C8SC04474K
  3. Titanium dioxide thin films by atomic layer deposition: a review vol.32, pp.9, 2017, https://doi.org/10.1088/1361-6641/aa78ce
  4. Chlorine Doping of Amorphous TiO2 for Increased Capacity and Faster Li+-Ion Storage vol.29, pp.23, 2014, https://doi.org/10.1021/acs.chemmater.7b03478
  5. Highly Reactive TiO2 Anatase Single Crystal Domains Grown by Atomic Layer Deposition vol.18, pp.9, 2014, https://doi.org/10.1021/acs.cgd.8b00170
  6. Stability and Degradation Mechanismof Si-based Photocathodes for Water Splitting with Ultrathin TiO2 Protection Layer vol.234, pp.6, 2020, https://doi.org/10.1515/zpch-2019-1481
  7. Bilayer number driven changes in polarizability and optical property in ZnO/TiO2 nanocomposite films prepared by ALD vol.233, pp.None, 2021, https://doi.org/10.1016/j.ijleo.2021.166617