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Effects of O2 Plasma Treatment on the Hydrophilic/hydrophobic Contrast of Film Substrates

O2 플라즈마 처리에 따른 필름기질의 친수 및 소수화 상반효과

  • Kang, In-Sook (Department of Clothing & Textiles, Changwon National University)
  • 강인숙 (창원대학교 자연과학대학 의류학과)
  • Received : 2013.05.20
  • Accepted : 2013.08.13
  • Published : 2013.08.31

Abstract

We studied the effects of $O_2$ plasma on the hydrophilic/hydrophobic contrast of film substrates. PET (polyethylene terephthalate) and FEP (fluorinated ethylene propylene) films were treated by $O_2$ plasma, and the surface of the films was investigated using atomic force microscopy(AFM), X-ray photoelectron spectroscopy (XPS), and contact-angle and surface energy measurements. Surface energies were calculated from the measured contact angles between several solutions and the films based on the geometric mean and Lewis acid-base method. The contact angle of PET films treated by $O_2$ plasma decreased with increasing treatment time in water and surfactant solution, and surface energy increased with increasing polar component of surface tension of the film. In contrast, the contact angle of the $O_2$ plasma-treated FEP film decreased, and surface energy decreased with decreasing nonpolar component of surface tension of the film.

Keywords

References

  1. C. C. Chen, J. S. Lin, E. W. Diau, and T. F. Liu, "Self-cleaning Characteristics on a Thin-film Surface with Nanotube Arrays of Anodic Titanium Oxide", Appl Phys A, 2008, 92(3), 615-620. https://doi.org/10.1007/s00339-008-4546-7
  2. Q. H. Lu, M. Li, J. Yin, Z. K. Zhu, and Z. G. Wang, "Polyimide Surface Modification by Pulsed Ultraviolet Laser Irradiation with Low Fluence", J Appl Polym Sci, 2001, 82(11), 2739-2743. https://doi.org/10.1002/app.2126
  3. J. R. Chen and T. Wakida, "Studies on the Surface Free Energy and Surface Structure of PTFE Film Treated with Low Temperature Plasma", J Appl Polym Sci, 1996, 63(13), 1733-1739.
  4. T. M. Ko and S. L. Cooper, "Surface Properties and Platelet Adhesion Characteristics of Acrylic Acid Allylamin Plasmatreated Polyethylene", J Appl Polym Sci, 1993, 47, 1601-1619. https://doi.org/10.1002/app.1993.070470908
  5. D. Popovici, A. Barzic, and I. Stoica, "Plasma Modification of Surface Wettability and Morphology for Optimization of the Interactions Involved in Blood Constituents Spreading on Some Novel Copolyimide Films", Plasma Chem Plasma Processing, 2012, 32(4), 781-799. https://doi.org/10.1007/s11090-012-9376-x
  6. E. D. Seo, "Comparative Studies on Morphology of Low Temperature Ar-Plasma-Treated Polymer Surfaces", J Korean Soc Dyers Finishers, 2004, 16(5), 35-41.
  7. Y. S. Lin, H. M. Liu, and C. L. Chen, "Plasma Surface Modification of Polyimide Films by Air Glow Discharge for Copper Metallization on Microelectronic Flex Substrates", Surf Coat Technol, 2006, 200(12-13), 3775-3785. https://doi.org/10.1016/j.surfcoat.2004.11.031
  8. J. J. Rha, S. C. Kwon, and Y. S. Jeong, "The Effects of Surface Energy and Roughness on Adhesion Force", The Korean Soc Mech Eng, 2006, 30(11), 1335-1347. https://doi.org/10.3795/KSME-A.2006.30.11.1335
  9. B. Beake, J. Ling, and G. Leggett, "Scanning Force Microscopy Investigation of Poly(ethylene terephthalate) Modified by Argon Plasma Treatment", J Mater Chem, 1998, 8(8), 1735-1742. https://doi.org/10.1039/a801194j
  10. Y. Da, J. G. Hans, W. H. Albert, and S. Robert, "Surface Modification of Poly(tetrafluoroethylene) by Gas Plasma Treatment", Polymer, 1991, 32(6), 1126-1130. https://doi.org/10.1016/0032-3861(91)90602-F
  11. J. J. Rha, Y. S. Jeong, and W. D. Kim, "Fabrication of Super Water Repellent Surfaces by Vacuum Plasma", J Mech Sci Technol, 2008, 32(2), 143-147. https://doi.org/10.3795/KSME-A.2008.32.2.143
  12. Y. J. Hwang and B. C. Kang, "Surface Modification of Poly (ethylene terephthalate) and Poly(trimethylene terephthalate) Fabrics Treated by Oxygen Atmospheric Pressure Plasma", J Korean Fiber Soc, 2004, 41(3), 210-216.
  13. H. H. Chien, K. Ma, and C. H. Kuo, "Effects of Plasma Power and Reaction Gases on the Surface Properties of ePTFE Materials during a Plasma Modification Process", Surf Coat Technol, 2013, 228(suppl.1), S477-S481. https://doi.org/10.1016/j.surfcoat.2012.05.014

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