한국염색가공학회지 (Textile Coloration and Finishing)

  • 제23권2호
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  • Pages.76-82
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  • 2011
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  • 1229-0033(pISSN)
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  • 2234-036X(eISSN)
한국염색가공학회 (The Korean Society of Dyers and Finishers)
권호 표지
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Sur face Modification of Ultra High Molecular Weight Polyethylene Films by UV/ozone Ir radiation

  • Yun, Deuk-Won (Dept. of Nano-Bio Textile Engineering, Kumoh National Institute of Technology) ;
  • Jang, Jin-Ho (Dept. of Nano-Bio Textile Engineering, Kumoh National Institute of Technology)
  • 투고 : 2011.05.12
  • 심사 : 2011.06.22
  • 발행 : 2011.06.27
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초록

Ultra High molecular weight polyethylene(UHMWPE) films were photooxidized by UV/ozone irradiation. Reflectance of the irradiated films decreased in the low wavelength regions of visible light, indicating destructive interference of visible light due to roughened surface. The UV treatment developed the nano-scale roughness on the UHMWPE films surface, which increased by two-fold from 82.6 to 156.6nm in terms of peak-valley roughness. The UV irradiation caused the oxygen content of the UHMWPE film surface to increase. Water contact angle decreased from $83.2^{\circ}$ to $72.9^{\circ}$ and surface energy increased from 37.8 to 42.6mJ/$m^2$ with increasing UV energy. The surface energy change was attributed to significant contribution of polar component rather than nonpolar component indicating surface photooxidation of UHMWPE films. The increased dyeability to cationic dyes may be due to the photochemically introduced anionic and dipolar dyeing sites on the film surfaces.

키워드

참고문헌

  1. S. M. Kurtz, "UHMWPE Biomaterials Handbook", Academic Press, London, U.K., pp. 197-200, 2009.
  2. A. Koh, V. Shim, and V. Tan, Dynamic Behavior of UHMWPE Yarns and Addressing Impedance Mismatch Effects of Specimen Clamps, Int. J. Impact Eng., 37, 324-332(2010). https://doi.org/10.1016/j.ijimpeng.2009.10.008
  3. S. Kurtz, O. Muratoglu, M. Evans, and A. Edidin, Advances in the Processing, Sterilization, and Crosslinking of Ultra-high Molecular Weight Polyethylene for Total Joint Arthroplasty, Biomaterials, 20, 1659-1688(1999). https://doi.org/10.1016/S0142-9612(99)00053-8
  4. G. H. Koo and J. Jang, Hydrophilic Modification of Poly(ethylene oxide) by UV Irradiation, Textile Coloration and Finishing, 21, 16-20(2009). https://doi.org/10.5764/TCF.2009.21.5.016
  5. H. S. Lee, Y. K. Jeong, and J. Jang, Surface Modification of Cellulose Acetate using $UV/O_3$ Irradiation, Textile Coloration and Finishing, 18, 281(2006).
  6. G. H. Koo and J. Jang, Surface Modification of Poly(Lactic Acid) by UV/Ozone Irradiation, Fibers and Polymers, 9, 674(2008). https://doi.org/10.1007/s12221-008-0106-1
  7. E. M. Kim and J. Jang, Surface Modification of Meta-aramid Films by UV/Ozone Irradiation, Fibers and Polymers, 11(5), 677-682(2010). https://doi.org/10.1007/s12221-010-0677-5
  8. C. J. van Oss, R. J. Good, and M. K. Chaudhury, Additive and Nonadditive Surfacetension Component and the Interpretation of Contact Angles, Langmuir , 4, 884-891(1988). https://doi.org/10.1021/la00082a018
  9. J. Jang and Y. Jeong, Nano Roughening of PET and PTT Fabrics via Continuous $UV/O_3$ Irradiation, Dyes and Pigments, 69, 137-143(2006). https://doi.org/10.1016/j.dyepig.2005.02.010
  10. X. Wang and R. Salovey, Melting of Ultra High Molecular Weight Polyethylene, J. Polym. Sci., 34, 593-599(1987).
  11. P. Smith, H. D. Chanzy and B. P. Rotzinger, Drawing of Virgin Ultra High Molecular Weight Polyethylene: an Alternative Route to High Strength/high Modulus Materials, Part 2 Influence of Polymerization Temperature, J. Mater. Sci., 22, 523-531(1997).
  12. A. Bellare, H. Schnablegger and R. E. Cohen, The Melt Anisotropy of UHMWPE, J. Polym. Sci., 21, 821-830(2003).

피인용 문헌

  1. Photo-oxidation and Dyeability of Poly Ketone by UV/O3Irradiation vol.25, pp.1, 2013, https://doi.org/10.5764/TCF.2013.25.1.25
  2. Surface Treatment and Dyeability of Poly(phenylene sulfide) Films by UV/O3Irradiation vol.23, pp.4, 2011, https://doi.org/10.5764/TCF.2011.23.4.284
  3. Photooxidation of Poly(butylene succinate) Films by UV/Ozone Irradiation vol.26, pp.3, 2014, https://doi.org/10.5764/TCF.2014.26.3.159
  4. Photooxidation of Poly(vinyl butyral) Films by UV/Ozone Irradiation vol.27, pp.2, 2015, https://doi.org/10.5764/TCF.2015.27.2.113
  5. Surface Modification Effect and Mechanical Property of para-Aramid Fiber by Low-temperature Plasma Treatment vol.24, pp.2, 2012, https://doi.org/10.5764/TCF.2012.24.2.131
  6. The Improvement of Thermal Stability and Tensile Toughness by the Photocrosslinking of Poly(phenylene sulfide) containing Acetophenone vol.24, pp.4, 2012, https://doi.org/10.5764/TCF.2012.24.4.281
  7. Surface Photooxidation of Poly(butylene terephthalate) Films by UV/Ozone Irradiation vol.28, pp.2, 2016, https://doi.org/10.5764/TCF.2016.28.2.63