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Effect of Inorganic Nanomater ials on the Morphology and Thermal Proper ties of PVA Nanocomposite Nanowebs

  • Choi, Jae-Young (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University) ;
  • Yeum, Jeong-Hyun (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University)
  • 투고 : 2011.04.26
  • 심사 : 2011.06.20
  • 발행 : 2011.06.27

초록

Poly(vinyl alcohol) (PVA), PVA/Montmorillonite (MMT), PVA/Silver (Ag), and PVA/MMT/Ag nanocomposite nanowebs were prepared by electrospinning technique in aqueous solution. In order to investigate the effect of inorganic materials on the morphology and thermal properties of PVA based nanocomposite nanowebs, experiments were performed with 5 wt.% of MMT and Ag. Field emission type scanning electron microscopy, transmission electron microscopy (TEM), reflection type X-ray diffraction (XRD), and thermal gravimetric analyzer were utilized to characterize nanocomposite nanowebs. TEM and XRD results show MMT and Ag were well dispersed in PVA nanowebs. Those inorganic nanoparticles enhanced thermal property of the nanocomposite nanowebs.

키워드

참고문헌

  1. J. L. Luna-Xavier, E. Bourgeat-Lami, and A. Guyot, The Role of Initiation in the Synthesis of Silica/poly(methyl methacrylate) Nanocomposite Latex Particles through Emulsion Polymerization, Colloid Polym. Sci., 279(10), 947-958(2001). https://doi.org/10.1007/s003960100520
  2. J. Lee and M. Senna, Preparation of Monodispersed Polystyrene Microspheres Uniformly Coated by Magnetite via Heterogeneous Polymerization, Colloid Polym. Sci., 273(1), 76-82(1995). https://doi.org/10.1007/BF00655677
  3. M. S. Fleming, T. K. Mandal, and D. R. Walt, Nanosphere-microsphere Assembly: Methods for Core-shell Materials Preparation, Chem. Mater ., 13(6), 2210-2216(2001). https://doi.org/10.1021/cm010168z
  4. F. Tiarks, K. Landfester, and M. Antonietti, Silica Nanoparticles as Surfactants and Fillers for Latexes made by Miniemulsion Polymerization, Langmuir , 17(19), 5775-5780(2001). https://doi.org/10.1021/la010445g
  5. B. Erdem, E. D. Sudol, V. L. Dimonie, and M. El-Aasser, Encapsulation of Inorganic Particles via Miniemulsion Polymerization. I. Dispersion of Titanium Dioxide Particles in Organic Media using OLOA 370 as Stabilizer, J. Polym. Sci. Pol. Chem., 38(24), 4419-4430(2000). https://doi.org/10.1002/1099-0518(20001215)38:24<4419::AID-POLA110>3.0.CO;2-X
  6. L. Li, L. M. Bellan, H. G. Craighead, and M. W. Frey, Formation and Properties of Nylon-6 and Nylon-6/montmorillonite Composite Nanofibers, Polymer , 47(17), 6208-6217(2006). https://doi.org/10.1016/j.polymer.2006.06.049
  7. S. S. Feng, L. Mei, P. Anitha, C. W. Gan, and W. Zhou, Poly(lactide)-vitamin E Derivative/Montmorillonite Nanoparticle Formulations for the Oral Delivery of Docetaxel, Biomaterials, 30(19), 3297-3306(2009). https://doi.org/10.1016/j.biomaterials.2009.02.045
  8. S. Y. Kwon, E. H. Cho, and S. S. Kim, Preparation and Characterization of Bone Cements Incorporated with Montmorillonite, J. Biomed. Mater. Res. Part B: Appl. Biomater , 83(1), 276-284(2007).
  9. T. Sun and K. Seff, Silver Clusters and Chemistry in Zeolites, Chem. Rev., 94(4), 857-870(1994). https://doi.org/10.1021/cr00028a001
  10. S. Glaus, G. Calzaferri, and R. Hoffmann, Electronic Properties of the Silver-silver Chloride Cluster Interface, Chem. Eur. J., 8(8), 1785-1794(2002). https://doi.org/10.1002/1521-3765(20020415)8:8<1785::AID-CHEM1785>3.0.CO;2-X
  11. Q. B. Yang, D. M. Li, Y. L. Hong, Z. Y. Li, C. Wang, S. L. Qiu, and Y. Wei, Preparation and Characterization of a PAN Nanofibre Containing Ag Nanoparticles via Electro-spinning, Synth. Met., 137(1-3), 973-974(2003). https://doi.org/10.1016/S0379-6779(02)00963-3
  12. H. W. Lee, M. R. Karim, H. M. Ji, J. H. Choi, H. D. Ghim, S. M. Park, W. Oh, and J. H. Yeum, Electrospinning Fabrication and Characterization of Poly(vinyl alcohol)/montmorillonite Nanofiber Mats, J. Appl. Polym. Sci., 113(3), 1860-1867 (2009). https://doi.org/10.1002/app.30165
  13. A. G. Dong, Y. J. Wang, and Y. Tang, Fabrication of Compact Silver Nanoshells on Polystyrene Spheres through Electrostatic Attraction, Chem. Commun., 4, 350-351(2002).

피인용 문헌

  1. Electrospinning Fabrication of Poly(vinyl alcohol)/TiO2Nanofibers vol.25, pp.2, 2013, https://doi.org/10.5764/TCF.2013.25.2.118
  2. Photocatalytic Activity of Electrospun PAN/TiO2Nanofibers in Dye Photodecomposition vol.25, pp.2, 2013, https://doi.org/10.5764/TCF.2013.25.2.94