Journal of Integrative Natural Science (통합자연과학논문집)

The Basic Science Institute Chosun University (조선대학교 기초과학연구원)
권호 표지
DOI QR코드

DOI QR Code

Enhancement of Blue Emission Efficiency of Organometallic Nanoparticle Containing Germanium

게르마늄을 함유하는 유기금속 나노입자의 청색 발광 효율의 증가

  • Received : 2010.12.02
  • Accepted : 2010.12.23
  • Published : 2010.12.31
Download PDF
⟨ Previous Next ⟩

Abstract

Dihydrotetraphenylgermole has been synthesized from the reduction of dichlorotetraphenylgermole with lithiumaluminiumhydride. UV-Vis absorption and photoluminescence was measured by using UV-Vis and fluorescence spectroscopy. Nanoparticles of dihydrotetraphenylsilole were synthesized from the mixture solution of water and THF. Photoluminescence behavior of organogermanium nanoparticle was investigated at various water fractions. Critical fraction of water to form organogermanium nanoparticles was 60%. Photoluminescence intensity of organogermanium nanoparticle was increased as the concentration of organogermanium nanocolloids increased. Photoluminescence efficiency of organogermanium nanoparticle at 90% water fraction increased about 100 times compared to that of molecular state.

Keywords

References

  1. K. Tamao, "Silole Derivatives as Efficient Electron Transporting Materials", J. Am. Chem. Soc., Vol. 118, p. 11974, 1996 https://doi.org/10.1021/ja962829c
  2. J. Dubac, C. Guerin and P. Meunier, "The Chemistry of Organic Silicon Compounds", John Wiley & sons Ltd, England, p. 34, 1998.
  3. K. Tamao, "Organosilicon Chemistry IV. From Molecules to Materials", John Wiley & sons Ltd, England, p. 245, 2000.
  4. K. Tamao, M. Uchida, T. Izumizawa, K. Furukawa and S. Yamaguchi, "Silole Derivatives as Efficient Electron Transporting Materials", J. Am. Chem. Soc., Vol. 118, p. 11974, 1996. https://doi.org/10.1021/ja962829c
  5. S. Yamaguchi, T. Endo, M. Uchida, T. Izumizawa, K. Furukawa and K. Tamao, "Toward new materials for organic electroluminescent devices: synthesis, structures, and properties of a series of 2,5-diaryl-3,4-diphenylsiloles", J. Chem. Eur., Vol. 6, p. 1683, 2000. https://doi.org/10.1002/(SICI)1521-3765(20000502)6:9<1683::AID-CHEM1683>3.3.CO;2-D
  6. T. Sanji, T. Sakai, C. Kabuto, and H. Sakurai, "Silole-Incorporated Polysilanes1a", J. Am. Chem. Soc., Vol. 120, p. 4552, 1998. https://doi.org/10.1021/ja973252h
  7. R. West, H. Sohn, D. R. Powell, T. Muller and Y. Apeloig, "The Dianion of Tetraphenylgermole is Aromatic", Angew. Chem. Int. Ed. Engl., Vol. 35, p. 1002, 1996. https://doi.org/10.1002/anie.199610021
  8. Y. Xu, T. Fujino, H. Naito, T. Dohmary, K. Oka, H. Sohn, and R. West, "Electroluminescent propreties of a Novel ${\sigma}{\ast}-{\pi}{\ast}$ conjugated polymer. poly[1,1-(2,3,4,5-tetraphenylsilole)]", Jpn. J. Appl. Phys., Vol. 38, p. 6915, 1999. https://doi.org/10.1143/JJAP.38.6915
  9. H. Sohn, R. R. Huddleston, D. R. Powell, and R. West, "An electroluminescent polysiole and some dichlorooligo-siloes", J. Am. Chem. Soc., Vol. 121, p. 2935, 1999. https://doi.org/10.1021/ja983350i
  10. H. Sohn, M. J. Sailor, D. Magde, and W. C. Trogler, "Detection of nitroarometaic explosives based on photoiuminescent polymers containing metalloes", J. Am. Chem. Soc., Vol. 125, p. 3821, 2003. https://doi.org/10.1021/ja021214e
  11. Y. Shin, S. Seo, M. Do, J. Shin, J. Park, and H. Kim, "Fabrication of silicon nano-wire MOSFET photodetector for high-sensitivity image sensor", J. of the Korean Sensors Society, Vol. 15, p. 1, 2006
  12. M. Kim, T. Nam, and Y. Lee, "Development of the High Temperature Silicon Pressure Sensor", J. of the Korean Sensors Society, Vol. 13, p. 175, 2004
  13. J. Luo, Z. Xie, J. W. Y. Lam, L. Cheng, H, Chen, C, Qiu, H. S. Kwok, X. Zhan, D. Zhu, and B. Z. Tang, "Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenyl silole", Chem. Commun., p. 1740, 2001.