Removal of VOC compounds in the vent of a pharmaceutical plant using a pilot-scale biofilter

Pilot-scale 바이오필터를 이용한 제약공정 배출가스의 처리

  • Ryu, Hee-Wook (Department of Chemical and Environmental Engineering, Soongsil University) ;
  • Lee, Tae-Ho (Research Institute of Biological and Environmental Technology, Biosaint Co.) ;
  • Park, Chang-Ho (Industrial Liaison Research Institute, Green Energy Center and College of Environment and Applied Chemistry, Kyung Hee University)
  • 류희욱 (숭실대학교 환경화학공학과) ;
  • 이태호 ((주)바이오세인트) ;
  • 박창호 (경희대학교 환경응용화학대학, 그린에너지센터, 산학협력기술연구원)
  • Published : 2008.12.31

Abstract

A pilot-plant biofilter ($1750\;m\;W{\times}2750\;mm\;L{\times}2000\;mm\;H$) packed with polyurethane foam ($20\;m\;W{\times}20\;mm\;L{\times}20\;mm\;H$) was installed in an pharmaceutical plant emitting gas streams containing n-hexane and alcohols. The biofilter was successfully operated for 74 days under highly fluctuating incoming concentrations at a residence time of 12.8-24.8 sec. Alcohols and n-hexane were removed by more than 90% from 5 and 20 days after start up, respectively. Malodor was also removed more than 95% from 20 days after start up.

본 연구는 폴리우레탄을 담체로 사용하고 자동교반장치가 장착된 pilot-scale의 바이오필터 (1$1750\;m\;W{\times}2750\;mm\;L{\times}2000\;mm\;H$)를 제약공정 현장에 설치하여 74일간 막힘현상 등 제반 문제없이 성공적으로 가동하였으며 제약공정에서 발생하는 가스에 함유된 핵산과 알코올류로 구성된 휘발성 유기 물질 (VOC)과 악취를 효율적으로 제거하였다. VOC 유입농도의 변화가 비교적 심한 조건임에도 불구하고 체류시간 $12.8{\sim}24.8$초의 가스공급조건에서 알코올류는 가동 5일후부터 90% 이상 100%에 근접하는 제거율을 보였고, n-핵산은 16일정도의 적응기를 지나서 평균 89%가 제거되었고 그 후 더욱 제거율이 증가하였다. 악취 또한 20일 이후부터는 95% 전후한 높은 제거효율을 나타내었다. 향후 적응기간 단축 등의 내용을 다소 보완하여 현장에 실규모 (full scale)로 적응이 가능할 것으로 사료된다.

Keywords

References

  1. Devinny, J. S., M. A. Deshusses, and T. S. Webster (1999), Biofiltration for Air Pollution Control. Lewis Publishers, FL, USA
  2. Swanson, W. J. and Raymond, C. L. (1997) Biofiltration: fundamentals, design and operations principles, and applications, J. Environ. Eng. 54, 538-546
  3. Jung, I.-G. and C.-H. Park (2005), Characteristics of styrene degradation by Rhodococcus pyridinovorans isolated from a biofilter, Chemosphere 61, 451-456 https://doi.org/10.1016/j.chemosphere.2005.03.007
  4. Ryu, H. W., Y. H. Joo, Y. J. An, and K. S. Cho (2006), Isolation and characterization of psychrotropic and halotolerant Rhodococcus sp. YHLT-2, J. Microbiol. Biotechnol. 16, 605-612
  5. Jung, S. J., K.-H. Jang, E.-H. Sihn, S.-K. Park, and C.-H. Park (2005), Characteristics of sulfur oxidation by a newly isolated, Burkholderia spp. J. Microbiol. Biotechnol. 15, 716-721
  6. Kam, S. K., K. H. Kang, and M. G. Lee (2005), Removal characteristics of ethyl acetate and 2-butanol by a biofilter packed with Jeju scoria, J. Microbiol. Biotechnol. 15, 977-983
  7. Kwon, H. H., E. Y. Lee, K. S. Cho, and H. W. Ryu (2003), Benzene biodegradation using the polyurethane biofilter immobilized with Stenotrophomonas maltophilia T3-c. J. Microbiol. Biotechnol. 13, 70-76
  8. Singh, R. S., S. S. Agnihotri, and S. N. Upadhyay (2006), Removal of toluene vapour using agro-waste as biofilter media, Bioresour. Technol. 97, 2296-2301 https://doi.org/10.1016/j.biortech.2005.10.036
  9. Jung, I.-G. I.-H. Lee, S.-J. Choung, C. N. Kim, Y.-M. Koo, E. K. Kim, and C.-H. Park (2006), Biodegradation of toluene and dimethyl sulfide in a cocultured biofilter, KJChE 23, 34-37
  10. Yoon, I.-K. and C.-H. Park (2002), Effects of gas flow rate, inlet concentration and temperature on biofiltration of volatile organic compounds in a peat-packed biofilter, J. of Biosci. Bioeng. 93, 165-169 https://doi.org/10.1263/jbb.93.165
  11. Jorio, H., K. Kiared, R. Brezezinski, A. Leroux, G. Viel, and M. Heitz (1998), Treatment of air polluted with high concentrations of toluene and xylene in a pilot-scale biofilter, J. Chem. Technol. Biotechnol. 73, 183-196 https://doi.org/10.1002/(SICI)1097-4660(1998110)73:3<183::AID-JCTB943>3.0.CO;2-7
  12. Lipski, Q., Droegoe, A., Reichart, K., and Altendorf, K. H. (1997), Detection and diversity of styrene degrading microorganism from biofilters, in Biological Waste Gas Cleaning, Proceedings of an International Symposium, Prins, W. L. and van Ham, J., Eds., VDI Verlag GmbH, Dusseldorf, Germany, p265