Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
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A Study on the Reduction of Particulate Emission Using Oil Soluble Organometallic Compounds as Combustion Improver for Heavy Fuel Oil

중질유 연소시 유용성 유기금속화합물 연소촉진제의 Dust 저감특성

  • Kim, Dong-Chan (Fossil Energy & Environment Research Department, Korea Institute of Energy Research) ;
  • Nho, Nam-Sun (Fossil Energy & Environment Research Department, Korea Institute of Energy Research) ;
  • Woo, Je-Kyung (Fossil Energy & Environment Research Department, Korea Institute of Energy Research) ;
  • Kim, Jin-Hoon (Fossil Energy & Environment Research Department, Korea Institute of Energy Research) ;
  • Lee, Young-Sea (Techno-bio Co., Ltd.)
  • 김동찬 (한국에너지기술연구원, 화석에너지환경연구부) ;
  • 노남선 (한국에너지기술연구원, 화석에너지환경연구부) ;
  • 우제경 (한국에너지기술연구원, 화석에너지환경연구부) ;
  • 김진훈 (한국에너지기술연구원, 화석에너지환경연구부) ;
  • 이영서 (테크노바이오)
  • Published : 2008.02.29
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Abstract

This study is aimed at substantially reducing the particulate matter (dust) emission during the combustion of heavy fuel in boilers by addition of combustion improver. The combustion improver used were the oil-soluble organometallic compounds that were found to be more effective than the dispersing agents that are generally used for reducing the particulate emission. The dust reduction effect was found to depend on the active materials (metals) as well as on the organic ligand part of organometallic compounds. Acetylacetonoate and naphthenate of Fe and Ca were found to be most effective for dust reduction. Addition of Fe and Ca organometallic compounds as combustion improver in concentration of 30 ppm (metal basis) to heavy fuel oil, caused dust reduction by 50 wt% to 80 wt%.

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References

  1. 김동찬, 노남선, 우제경(2006) 산업용 보일러의 고효율 연소 촉진제 및 중질유 분산제 개발에 의한 미세먼지 저감 기술개발, 한국에너지기술연구원, 차세 대핵심 환경기술개발과제 보고서, 011-031-010
  2. 김영철, 육신홍, 이철호, 홍정진 (1999) 연료유 개질 조연제 조성물, 한국화학연구소, 특허공개번호 특1999- 009206
  3. 김용표 (2006) 서울의 미세먼지에 의한 대기오염, 한국대기환경학회지, 22(5), 535-553
  4. 岡部 平八, 大勝 靖一(2005) 石油製品添加製の開發, 日本 CMC出版
  5. 中井 多喜雄(2002) 燃科工學 Guide, 日本 燃穘社
  6. Danilov, A.M. (1998) New additive for fuels: analysis of publications for 1991-1996, Chemistry and Technology of Fuels and Oils, 34(1), 51-58
  7. Eliot, R.C. (1978) Boiler fuel additives for pollution reduction and energy saving, Noyes Data Corp., U.S.A. 23- 27
  8. Fuel Tech Inc. (2003) Fuel Additive: Smoke-Out, Fuel Chem, Fuel Tech Inc. Cat. U.S.A
  9. Giammar, R.D., A.E. Weller, D.W. Locklin, and H.H. Krause (1977) Experimental evalution of fuel oil additives for reducing emissions and increasing efficiency of boiler, Battelle-Columbus Lab., U.S. EPA Contract No. 68-02-0262
  10. Howard, J.B. and W.J. Kausch (1980) Soot control by fuel additives, Prog. Energy Combust. Sci., 6, 263-276 https://doi.org/10.1016/0360-1285(80)90018-0
  11. Kazuhiko and Kenichi Yuge (2005) Effect of fuel additives on reduction of smoke and particulate matter, and stabilization of cycle-to-cycle variation, J. of Japan Petroleum Institute, 48(4), 229-235 https://doi.org/10.1627/jpi.48.229
  12. Mitchell, J.B. (1991) Smoke reduction from burning crude oil using ferrocene and its derivatives, Combustion and Flame, 86, 179-184 https://doi.org/10.1016/0010-2180(91)90065-J
  13. Poullikkas, A. (2004) Cost-benefit analysis for the use of additives in heavy fuel oil fired boilers, ELSEVIER, Energy Conversion and Management, 45, 1725-1734 https://doi.org/10.1016/j.enconman.2003.09.035
  14. Somasundaram, G. and P.D. Sunavala (1989) Suppression of soot in the combustion of residual furnace oil using organometallic additive, Fuel, 68, 921-927 https://doi.org/10.1016/0016-2361(89)90131-2
  15. Witzel, L., P. Moszkowicz, and G. Clausst (1995) Mechanism of particulate reduction in heavy fuel oil combustion, Fuel, 74(12), 1881-1886 https://doi.org/10.1016/0016-2361(95)80023-B