Bulletin of the Korean Chemical Society

  • 제29권2호
  • /
  • Pages.352-356
  • /
  • 2008
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Rapid Determination of Chlorostyrenes in Fish by Freezing-Lipid Filtration, Solid-Phase Extraction and Gas Chromatography-Mass Spectrometry

  • Kim, Min-Sun (College of Pharmacy, Kyung Hee University) ;
  • Park, Kwang-Sik (College of Pharmacy, Dongduk University) ;
  • Pyo, Hee-Soo (Bioanalysis and Biotransformation Research Center, Korea Institute of Science and Technology) ;
  • Hong, Jong-Ki (College of Pharmacy, Kyung Hee University)
  • 발행 : 2008.02.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

An analytical method has been developed for measuring chlorostyrenes in fish tissue sample. Extraction of chlorostyrenes from fish tissue was carried out by ultrasonication using acetone/n-hexane (5:2, v/v) mixture. Most of the lipids in the extract were eliminated by freezing-lipid filtration, prior to solid-phase extraction (SPE) cleanup. During freezing-lipid filtration, about 90% of the lipids extracted from the fish samples were easily removed without any significant losses of chlorostyrenes. For purification, SPE using Florisil was used for the rapid and effective cleanup. Quantification was performed using gas chromatography-mass spectrometry in the selected ion monitoring mode. Spiking experiments were carried out to determine the recovery, precision, and limits of detection (LODs) of the method. The overall recovery was above 80% in the spiked fish tissue sample at 10 and 100 ng/g levels, respectively. The detection limits for chlorostyrenes were ranged from 0.05 to 0.1 ng/g. This developed method is demonstrated to give efficient recoveries and LODs for detecting chlorostyrenes spiked into fish tissue with high lipid content.

키워드

참고문헌

  1. Lahaniatis, E.; Clausen, E.; Fytianos, K.; Bieniek, D. Neturwiss. 1998, 75, 93
  2. Selden, A.; Nygren, Y.; Westberg, H.; Bodin, L. Occp. Environ. Med. 1997, 54, 613 https://doi.org/10.1136/oem.54.8.613
  3. Lommel, A.; Kruse, H.; Muller, E.; Wassermann, O. Arch. Environ. Contam. Toxicol. 1992, 22, 14 https://doi.org/10.1007/BF00213296
  4. Tarkpea, M.; Hagen, I.; Carlberg, G.; Kolsaker, P.; Storflor, H. Bull. Enviorn. Contam. Toxicol. 1985, 35, 525 https://doi.org/10.1007/BF01636549
  5. Database of Octachlorostyrene, Compilation prepared by Environmental Protection Agency (EPA), http://www.epa.gov/pbt/pubs/octaaction.htm#ref
  6. Chu, S.; Covaci, A.; Voorspeols, S.; Schepens, P. J. Environ. Monit. 2003, 5, 619 https://doi.org/10.1039/b304364a
  7. Kaminsky, R.; Hltes, R. Environ. Sci. Technol. 1984, 18, 275 https://doi.org/10.1021/es00122a013
  8. Bester, K.; Biselli, S.; Ellerichmann, T.; Huhnerfuss, H.; Moller, K.; Rimkus, G.; Wolf, M. Chemosphere 1998, 37, 2459 https://doi.org/10.1016/S0045-6535(98)00302-6
  9. Boer, J.; Valk, F.; Kerkhoff, M.; Hagel, P. Environ. Sci. Technol. 1994, 28, 2242 https://doi.org/10.1021/es00062a007
  10. Kuehl, D.; Haebler, R. Arch. Environ. Contam. Toxicol. 1995, 28, 494
  11. Samdau, C.; Meerts, I.; Letecher, R.; Mcalees, A.; Chittim, B.; Brouwer, A.; Norstorm, R. Environ. Sci. Technol. 2000, 34, 3871 https://doi.org/10.1021/es001134f
  12. Boer, J.; Zande, T.; Pieters, H.; Ariese, F.; Schipper, C.; Brummelen, T.; Vethaak, D. J. Environ. Monit. 2001, 3, 386 https://doi.org/10.1039/b103814c
  13. Selden, A.; Westberg, H. Arch. Environ. Health 1999, 54, 248 https://doi.org/10.1080/00039899909602482
  14. Kuehl, D.; Kopperman, H.; Veith, G.; Glass, G. Bull. Environ. Contam. Toxicol. 1976, 16, 127 https://doi.org/10.1007/BF01685217
  15. Green, N.; Knutzen, J. Mar. Pollut. Bull. 2003, 46, 362 https://doi.org/10.1016/S0025-326X(02)00515-5
  16. Fisk, A.; Holst, M.; Hobson, K.; Duffe, J.; Moisey, J.; Norstorm, R. Arch. Environ. Contam. Toxicol. 2002, 42, 118 https://doi.org/10.1007/s002440010299
  17. Coelhan, M.; Reil, I.; Rimkus, G.; Parlar, H. Environ. Sci. Technol. 2000, 34, 4695 https://doi.org/10.1021/es0011820
  18. Hong, J.; Kim, H.; Kim, D.; Seo, J.; Kim, K. J. Chromatogr. A 2004, 1038, 27 https://doi.org/10.1016/j.chroma.2004.03.003
  19. Castro, J.; Sanchez-Brunete, C.; Tadeo, J. J. Chromatogr. A 2001, 918, 371 https://doi.org/10.1016/S0021-9673(01)00751-8
  20. Richter, B.; Jones, B.; Ezzell, J.; Porter, N.; Avdalovic, N.; Pohl, C. Anal. Chem. 1996, 68, 1033 https://doi.org/10.1021/ac9508199
  21. Ramos, L.; Kristenson, E.; Brinkman, U. J. Chromatogr. A 2002, 975, 3 https://doi.org/10.1016/S0021-9673(02)01336-5
  22. Eskilsson, C.; Bjorklund, E. J. Chromatogr. A 2002, 902, 227 https://doi.org/10.1016/S0021-9673(00)00921-3
  23. Zuloaga, O.; Etxebarria, N.; Fernandez, L.; Madariaga, J. Talanta 1999, 50, 345 https://doi.org/10.1016/S0039-9140(99)00028-4
  24. Turner, C.; Eskilsson, C.; Bjorklund, E. J. Chromatogr. A 2002, 947, 1 https://doi.org/10.1016/S0021-9673(01)01592-8
  25. Kitamura, K.; Takazawa, Y.; Hashimoto, S.; Choi, J.; Ito, H.; Morita, M. Anal. Chim. Acta 2004, 512, 27 https://doi.org/10.1016/j.aca.2004.02.040
  26. Smith, L.; Stalling, D.; Johnson, J. Anal. Chem. 1984, 56, 1830 https://doi.org/10.1021/ac00275a018
  27. Ryan, J.; Pilon, J.; Conacher, H.; Firestone, P. J. Assoc. Off. Anal. Chem. 1983, 66, 700
  28. Ahn, Y.; Seo, J.; Shin, J.; Khim, J.; Hong, J. Anal. Chim. Acta 2006, 576, 31 https://doi.org/10.1016/j.aca.2006.03.010
  29. Seo, J.; Kim, H.; Chung, B.; Hong, J. J. Chromatogr. A 2005, 1067, 303 https://doi.org/10.1016/j.chroma.2004.12.063
  30. Tor, A.; Aydin, M.; Ozcan, S. Anal. Chim. Acta 2006, 559, 173 https://doi.org/10.1016/j.aca.2005.11.078
  31. Cejas, J.; Almansa, E.; Villamandos, J.; Badia, P.; Boalnos, A.; Lorenzo, A. Aquaculture 2003, 216, 299 https://doi.org/10.1016/S0044-8486(02)00525-2
  32. Almansa, E.; Perez, M.; Cejas, J.; Badia, P.; Villamandos, J.; Lorenzo, A. Aquaculture 1999, 170, 323 https://doi.org/10.1016/S0044-8486(98)00415-3

피인용 문헌

  1. Analysis of estrogens and estrogen mimics in edible matrices-A review vol.37, pp.8, 2014, https://doi.org/10.1002/jssc.201301234
  2. Determination of pharmaceuticals in bivalves using QuEChERS extraction and liquid chromatography-tandem mass spectrometry vol.407, pp.13, 2015, https://doi.org/10.1007/s00216-015-8617-2
  3. Current literature in mass spectrometry vol.43, pp.10, 2008, https://doi.org/10.1002/jms.1307
  4. Simultaneous determination of bisphenol A and alkylphenol in plant oil by gel permeation chromatography and isotopic dilution liquid chromatography-tandem mass spectrometry vol.1218, pp.31, 2008, https://doi.org/10.1016/j.chroma.2011.06.005