Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Structure of Mixed-Anions Tris(2-pyridylmethyl)amine Mn Complex, TPAMnη2-NO3)(η-CIO4)

  • Shin, Bok-Kyu (Metalloenzyme Research Group, BET Research Institute and Department of Biotechnology, Chung-Ang University) ;
  • Kim, Mi-Hyang (Metalloenzyme Research Group, BET Research Institute and Department of Biotechnology, Chung-Ang University) ;
  • Han, Jae-Hong (Metalloenzyme Research Group, BET Research Institute and Department of Biotechnology, Chung-Ang University)
  • Published : 2007.03.20
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Abstract

Mononuclear mixed-anions Mn complex of TPAMn(η2-NO3)(η-ClO4), where TPA is tris(2-pyridylmethyl)-amine, has been synthesized and characterized. The neutral TPAMn(η2-NO3)(η-ClO4) was obtained from the reaction between Mn(NO3)2·4H2O and [H3TPA](ClO4)3 in MeOH. X-ray crystallographic structure of mononuclear TPAMn(η2-NO3)(η-ClO4) complex showed a seven-coordinated geometry with a tripodal tetradentate TPA, a terminal perchlorate and an η2-bound nitrate.

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References

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