Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Novel Linking Ligand Containing Sulfur-Donor Atoms and Its Compounds of Palladium and Silver

  • Lee, Hee-K. (Department of Chemistry (BK21), Institute of Basic Science, Sungkyunkwan University) ;
  • Lee, Soon-W. (Department of Chemistry (BK21), Institute of Basic Science, Sungkyunkwan University)
  • Published : 2007.03.20
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Abstract

A linking ligand containing sulfur donor atoms in the terminal thiophene rings, 1,2-bis(thiophen-2-ylmethylene) hydrazine (L), was prepared by Schiff-base condensation. Ligand L reacted with [PdCl2(NCPh)2] to produce a molecular Pd compound [PdL2Cl2] (1). On the other hand, it reacted with AgNO3 and AgClO4 to produce a 2-D network [AgL0.5(NO3)] (2) and a 1-D polymer [AgL]ClO4 (3), respectively, whose structures are based on secondary intermolecular forces such as H-bonding, van der Waals interaction, and π-π stacking. Polymer 2 exhibited photoluminescence at room temperature in the solid state.

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References

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