Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Efficient Hydrogenation Catalysts of Ni or Pd on Nanoporous Carbon Workable in an Acidic Condition

  • Lee, Dong-Hwan (Department of Chemistry, Inha University) ;
  • Kim, Hong-Gon (Korea Institute of Science and Technology, Reaction Media Research Center, Environment & Process Technology Division) ;
  • Kang, Min (Department of Chemistry, Sungkyunkwan University) ;
  • Kim, Ji-Man (Department of Chemistry, Sungkyunkwan University) ;
  • Lee, Ik-Mo (Department of Chemistry, Inha University)
  • Published : 2007.11.20
Download PDF
⟨ Previous Next ⟩

Abstract

Efficient catalytic systems, where Ni or Pd is introduced in a supporting material of nanoporous carbon, have been developed for a liquid-phase hydrogenation of carboxylic acids and ketones at room temperature. It has been found that the catalysts reliably show high activities and selectivities for the hydrogenation to alcohols even in acidic conditions, and the catalytic activities depend on the preparative method of catalysts, the hydrogen pressure, the agitation rate, and the catalytic species. The hydrogenation of carboxylic acids and ketones clearly shows that the reaction rate is affected by the electronic and the steric effects, and a plausible reaction mechanism using metal hydrides as catalytic species is proposed.

Keywords

References

  1. Hucul, D. A.; Hahn, S. F. Adv. Mater. 2000, 12, 1855-1858 https://doi.org/10.1002/1521-4095(200012)12:23<1855::AID-ADMA1855>3.0.CO;2-P
  2. Feng, M.; Puddephatt, R. J. Chem. Mater. 2003, 15, 2696-2698 https://doi.org/10.1021/cm034170x
  3. Thomas, J. M. Angew. Chem. Int. Ed. 1999, 38, 3588-3628 https://doi.org/10.1002/(SICI)1521-3773(19991216)38:24<3588::AID-ANIE3588>3.0.CO;2-4
  4. Heck, R. M.; Farrauto, R. J. In Catalytic Air Pollution Control, Commercial Technology; Van Nostrand Reinhold: New York, 1995; pp 71-112
  5. Kim, S. W.; Kim, M.; Lee, W. Y.; Hyeon, T. H. J. Am. Chem. Soc. 2002, 124, 7642 https://doi.org/10.1021/ja026032z
  6. Moreno-Manas, M.; Pleixats, R. Acc. Chem. Res. 2003, 36, 638-643 https://doi.org/10.1021/ar020267y
  7. Ying, J. Y. AIChE J. 2000, 46(10), 1902-1906 https://doi.org/10.1002/aic.690461002
  8. Jun, S.; Joo, S. H.; Ryoo, R.; Kruk, M.; Jaroniec, M.; Liu, Z.; Ohsuna, T.; Terasaki, O. J. Am. Chem. Soc. 2000, 122, 10712-10713 https://doi.org/10.1021/ja002261e
  9. Park, S. Y.; Choi, B. H.; Kang, M.; Kim, J. M.; Lee, I. M. J. Mol. Catal. A: Chem. 2007, 265, 323-329 https://doi.org/10.1016/j.molcata.2007.01.020
  10. Park, S. Y.; Kang, M.; Yie, J. E.; Kim, J. M.; Lee, I. M. Tetrahedron Lett. 2005, 46, 2849-2852 https://doi.org/10.1016/j.tetlet.2005.02.114
  11. Neyestanaki, A. K.; Maki-Arvela, P.; Backman, H.; Karhu, H.; Salmi, T.; Vayrynen, J.; Murzin, D. Y. J. Catal. 2003, 218, 267-279 https://doi.org/10.1016/S0021-9517(03)00070-8
  12. Vitulli, G.; Evangelisti, C.; Pertici, P.; Caporusso, A. M.; Panziera, N.; Salvadori, P.; Faga, M. G.; Manfredotti, C.; Martra, G.; Coluccia, S.; Balerna, A.; Colonna, S.; Mobilio, S. J. Organomet. Chem. 2003, 681, 37-50 https://doi.org/10.1016/S0022-328X(03)00529-1
  13. Jung, S. M.; Godard, E.; Jung, S. Y.; Park, K. C.; Choi, J. U. J. Mol. Catal. A: Chemical 2003, 391, 1-6
  14. Thomas, J. M.; Johnson, B. F. G.; Raja, R.; Sankar, G.; Midgley, P. A. Acc. Chem. Res. 2003, 36, 20-30 https://doi.org/10.1021/ar990017q
  15. Hansch, C.; Leo, A.; Taft, R. W. Chem. Rev. 1991, 91, 165-195 https://doi.org/10.1021/cr00002a004

Cited by

  1. Synthesis of Reduced Graphene Oxide-Carbon Nanotubes (rGO–CNT) Composite and Its Use As a Novel Catalyst Support for Hydro-Purification of Crude Terephthalic Acid vol.54, pp.31, 2015, https://doi.org/10.1021/acs.iecr.5b01574
  2. Diels-Alder Cycloaddition of Cyclopentadiene with Ethylacrylate Catalyzed by Mesoporous Al-MCM-48 and Al-MCM-41 Catalysts vol.29, pp.10, 2007, https://doi.org/10.5012/bkcs.2008.29.10.1993
  3. Effects of Catalyst Promotion on the Selective Hydrogenation of Biphenol Using Various Pd/C Catalysts vol.29, pp.12, 2008, https://doi.org/10.5012/bkcs.2008.29.12.2434
  4. Development of Gold Phosphorus Supported Carbon Nanocomposites vol.35, pp.2, 2007, https://doi.org/10.5012/bkcs.2014.35.2.401
  5. 희토류가 수소화 촉매에 미치는 영향 vol.35, pp.1, 2007, https://doi.org/10.12925/jkocs.2018.35.1.151
  6. Semi-batch 반응기에서의 트리글리세라이드 접촉 수소화 반응 vol.25, pp.2, 2007, https://doi.org/10.7464/ksct.2019.25.2.099