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The Effects of Ar-ion Bombardment and Annealing of D2O/Zircaloy-4 Surfaces Using XPS and UPS

  • Published : 2007.08.20

Abstract

The surface chemistry of D2O dosed Zircaloy-4 (Zry-4) surface followed by Ar-ion bombardment and annealing was studied by means of X-ray photoelectron spectroscopy (XPS) and Ultraviolet photoelectron spectroscopy (UPS). In the XPS study, Ar-ion bombardment caused decrease of the oxygen on the surface region of Zry-4 and therefore led to change the oxidation states of the zirconium from oxide to metallic form. In addition, oxidation states of zirconium were changed to lower oxidation states of zirconium due to depopulation of oxygen on the surface region by annealing. Up to about 787 K, the bulk oxygen diffused out to the subsurface region and after this temperature, the oxygen on the surface of Zry-4 was depopulated. UPS study showed that the valence band spectrum of the D2O exposed Zry-4 exhibited a dominant peak at around 13 eV and no clear Fermi edge was detected. After stepwise Ar+ sputtering processes, the decrease of the oxygen on the surface of Zry-4 led to suppress the dominant peak around 13 eV, the peak around 9 eV and develop a new peak of the metallic Zr 4d state (20.5-21.0 eV) at the Fermi level.

Keywords

References

  1. Wan, Q.; Bai, X.; Zhang, X. Mater. Res. Bull. 2006, 41, 387 https://doi.org/10.1016/j.materresbull.2005.08.007
  2. Kim, W.; Jung, K. S.; Choi, B. H.; Kwon, H. S.; Lee, S. J.; Han, J. G.; Guseva, M. I.; Atamanov, M. V. Surf. Coat. Technol. 1995, 76, 595
  3. Chen, X. W.; Bai, X. D.; Deng, P. Y.; Peng, D. Q.; Chen, B. S. Nucl. Instr. and Meth. B 2003, 211, 512 https://doi.org/10.1016/S0168-583X(03)01518-0
  4. Liu, X.; Bai, X.; Zhou, C.; Wei, L. Surf. Coat. Technol. 2004, 182, 138 https://doi.org/10.1016/j.surfcoat.2003.07.008
  5. Bai, X. D.; Wang, S. G.; Xu, J.; Bao, J.; Chen, H. M.; Fan, Y. D. J. Nucl. Mater. 1998, 254, 266 https://doi.org/10.1016/S0022-3115(97)00346-2
  6. Li, J.; Bai, X.; Zhang, D.; Li, H. Appl. Surf. Sci. 2006, 252, 7436 https://doi.org/10.1016/j.apsusc.2005.08.091
  7. Stojilovic, N.; Ramsier, R. D. J. Nucl. Mater. 2006, 350, 163 https://doi.org/10.1016/j.jnucmat.2005.12.003
  8. Berger, P.; El Tahhann, R.; Moulin, G.; Viennot, M. Nucl. Instr. and Meth. B 2003, 210, 519 https://doi.org/10.1016/S0168-583X(03)01089-9
  9. Meyer, G.; Kobrinsky, M.; Abriata, J. P.; Bolcich, J. C. J. Nucl. Mater. 1996, 229, 48 https://doi.org/10.1016/0022-3115(95)00228-6
  10. Gumez, M. P.; Domizzi, G.; Lupez Pumarega, M. I.; Ruzzante, J. E. J. Nucl. Mater. 2006, 353, 167 https://doi.org/10.1016/j.jnucmat.2006.01.024
  11. Kim, S. J.; Kim, K. H.; Baek, J. H.; Choi, B. K.; Jeong, Y. H.; Jung, Y. H. J. Nucl. Mater. 1998, 256, 114 https://doi.org/10.1016/S0022-3115(98)00066-X
  12. Fernandez, G. E.; Meyer, G.; Peretti, H. A. J. Alloys & Compd. 2002, 330, 483 https://doi.org/10.1016/S0925-8388(01)01622-X
  13. Stojilovic, N.; Ramsier, R. D. Appl. Surf. Sci. 2006, 252, 5839 https://doi.org/10.1016/j.apsusc.2005.08.006
  14. Park, K. H.; Cho, Y. C.; Kim, Y. G. J. Nucl. Mater. 1999, 270, 154 https://doi.org/10.1016/S0022-3115(98)00903-9
  15. Stojilovic, N.; Ramsier, R. D. Surf. Interface Anal. 2006, 38, 139 https://doi.org/10.1002/sia.2212
  16. Hong, H. S.; Moon, J. S.; Kim, S. J.; Lee, K. S. J. Nucl. Mater. 2001, 297, 113 https://doi.org/10.1016/S0022-3115(01)00601-8
  17. Bai, X.; Xu, J.; He, F.; Fan, Y. Nucl. Instr. and Meth. B 2000, 160, 49 https://doi.org/10.1016/S0168-583X(99)00583-2
  18. Stojilovic, N.; Bender, E. T.; Ramsier, R. D. J. Nucl. Mater. 2006, 348, 79 https://doi.org/10.1016/j.jnucmat.2005.08.022
  19. Li, B.; Griffiths, K.; Zhang, C.-S.; Norton, P. R. Surf. Sci. 1997, 370, 97
  20. Kang, Y. C.; Ramsier, R. D. Surf. Sci. 2002, 519, 229 https://doi.org/10.1016/S0039-6028(02)02210-0
  21. Takagi, I.; Hashizumi, M.; Yamagami, A.; Maehara, K.; Higashi, K. J. Nucl. Mater. 1997, 248, 306 https://doi.org/10.1016/S0022-3115(97)00159-1
  22. Gobrecht, K.; Gutsmiedl, E.; Scheuer, A. Phy. B 2002, 311, 148 https://doi.org/10.1016/S0921-4526(01)01130-9
  23. Charquet, D.; Hahn, R.; Ortlieb, E.; Gros, J. P.; Wadier, J. F. Zirconium in the Nuclear Industry San Diego, 1989; STP 1023, p 405
  24. Kwon, J. H.; Youn, S. W.; Kang, Y. C. Bull. Korean Chem. Soc. 2006, 27, 11 https://doi.org/10.5012/bkcs.2006.27.11.1851
  25. Lyapin, A.; Jeurgens, L. P. H.; Mittemeijer, E. J. Acta Mater. 2005, 53, 2925 https://doi.org/10.1016/j.actamat.2005.03.009
  26. Lyapin, A.; Jeurgens, L. P. H.; Graat, P. C. J.; Mittemeijer, E. J. J. Appl. Phys. 2004, 96, 12 https://doi.org/10.1063/1.1753084
  27. Roustila, A.; Chêne, J.; Severac, C. J. Alloys & Compd. 2003, 356, 330 https://doi.org/10.1016/S0925-8388(03)00356-6
  28. Morant, C.; Sanz, J. M.; Galan, L. Phys. Rev. B 1992, 45, 3
  29. Wiame, H.; Centeno, M. A.; Picard, S.; Bastians, P.; Grange, P. J. Eur. Ceram. Soc. 1998, 18, 1293 https://doi.org/10.1016/S0955-2219(98)00056-9
  30. Song, Z.; Bao, X.; Wild, U.; Muhler, M.; Ertl, G. Appl. Surf. Sci. 1998, 134, 31 https://doi.org/10.1016/S0169-4332(98)00249-9
  31. Sanz, J. M.; Gonzalez-Elipe, A. R.; Fernandez, A.; Leinen, D.; Galan, L.; Stampfl, A.; Bradshaw, A. M. Surf. Sci. 1994, 307, 848
  32. Zafeiratos, S.; Neophytides, S.; Kennou, S. Thin Solid Films 2001, 386, 53 https://doi.org/10.1016/S0040-6090(01)00770-2

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